页岩 EOR:已发现石油

致密岩作业者正在测试 EOR 的想法,以便在他们已经打井的地方生产更多的石油。以下是他们的一些发现。

[编者注:这个故事的一个版本出现在《 石油和天然气投资者》 2019 年 12 月版中在这里订阅杂志 。]

也许可以给井下的细菌一些维生素。或者将现场气体泵回井中。用二氧化碳浸泡孔?泡在水里吗?用现场气体追踪器给它一些水?

非常规岩石 EOR 的正确方法仍然难以捉摸。但从巴肯到伊格尔福德再到二叠纪盆地的运营商正在研究所有可以想象的公式。他们从传统岩层似乎喜欢的地方开始。

其中大部分至少能发挥一点作用;其中一些不能持续很长时间。然后,还有这种方法与那种方法的成本,以及它所获得的额外石油的对比。此外,数学计算还必须考虑处理过程中油井离线时的产量损失。

不过,最终,完美的鸡尾酒将使油井的欧元大幅增长,而无需运营商花费额外的 640 英亩、20,000 英尺的管道、数十个压裂塔、数千桶的成本来支付另一个井的费用( bbl)水和数百吨沙子。

现场气体注入,巴肯

2018 年至今年 5 月,Liberty Resources LLC 在巴肯进行了富气吞吐 (HnP) 试点项目“Stomping Horse”。预计明年将进行第二次审判,规模将会更大。

该测试涉及在威廉斯县东部麦格雷戈油田沿内森背斜线的两部分 Liberty 井中注入 11 口井中的 5 口。监测偏移井注入的气体是否离开目标装置。

气体来自井口,主要成分为 60% 甲烷、20% 乙烷和 10% 丙烷,英国热单位含量约为 1,500。

根据 Liberty 9 月份向北达科他州工业委员会提交的后续报告,我们学到了很多东西。研究结果包括:这将需要更多的天然气。

在目标区域,Liberty 运营除北部以外的邻近区域。该井由 Murex 石油公司运营,在 Liberty 进行测试时,该公司提供了有关其单位内四口井的操作情报。这四台 Murex 水平井于 2010 年至 2012 年上线,总计生产了 958,000 桶石油和 12 亿立方英尺 (Bcf) 天然气。

总体而言,试点结果表明“具有在 [HnP] 方案中注入气体、建立压力、在 [装置] 的巴肯/三叉间隔内控制气体以及回收注入气体的能力,”Liberty 副总裁 Gordon Pospisil 表示总裁,负责业务发展,并领导 EOR 项目。

注入的气体留在自由单元内。根据国家文件,2019 年 8 月 Murex 油井的平均产量为每天 43 桶 (bbl/d) 和每天 121,000 立方英尺 (cf/d)。在 Liberty 试点之前,2018 年 6 月的平均产量为 40 桶/天和 111,000 cf/天。

Liberty 在其油井中总共注入了 158 MMcf;到今年 8 月,它已经恢复了 143 MMcf。

Pospisil 表示,范围受到该装置生产并可注入的天然气量的限制,“这限制了枯竭区间内的影响——压力建立,从而限制了石油响应的幅度。” �

油井完工时,装置内的储层压力已超过 6,000 psi;注入时,除了一口井压力约为 1,100 psi 外,压力均低于 1,000 psi。泡点约为 2,500 psi。

PoSpisil 表示,第二个试点将涉及注入更多的天然气,目标井的天然气消耗更少,初始井底压力更高。

五个注入井中每一个注入井的结果:

Leon 2MBH于2016年3月上线,24小时IP为428 bbl。截至今年 8 月份的累计产量为 75,842 桶和 300 MMcf。2018 年 8 月 18 天内注入的压力为 13.8 MMcf。预注入压力约为 1,100 psi。上个月石油平均产量为 48.5 桶/天;注射后一个月,55.6 桶/天。

Leon 3TFH于 2016 年 3 月上线,IP 为 272 桶/天。截至今年 8 月,累计产量为 92,564 桶和 330 MMcf。两组共注射10.8 MMcf:2018年7月12天,2018年9月6天。

当时的压力约为 900 psi。第一次注入前一个月的油量为 33.4 桶/天;两次注射之间的一个月内,43.3 桶/天;第二次注射后的一个月,35桶/天。

2014 年 12 月, Gohrick 5MBH 的IPed 产量为 1,032 桶/天。截至今年 8 月的累计产量为 240,507 桶/天,608 MMcf。2018年第四季度共注射了2组42MMcf:一组持续11天;一组持续12天。另一个是33天。

注射时的压力小于600 psi。治疗前整整一个月的油量为 21.4 桶/天;注射后第一个完整月,45.1桶/天。

Gohrick 4MBH于 2014 年 11 月的产量为 1,191 桶/天。截至今年 8 月的累计产量为 229,557 桶和 563 MMcf。从今年 1 月到 5 月,在 29 天内总共注射了 75 MMcf。当时的 Psi 还不到 1,000。

第一次注射前整月的产量为 17.5 桶/天;最后一次注射后的第一个完整月,17.9 桶/天。

Gohrick 6TFH 2015 年 1 月的产量为 1,067 桶/天。截至今年 8 月的累计产量为 141,367 桶/天,日产量为 455 MMcf。5 月份 15 天内注射量为 17.4 MMcf。当时的 Psi 为 713。注射前一个月的产量为 17.8 桶/天;注射后一个月,33.5桶/天。

所有五口井均于八月恢复生产。《自由报》在后续报道中列举了几个问题:

  • 试点项目的天然气供应仅限于该装置生产的天然气;
  • 所使用的水井已经相当枯竭;静态井底压力远低于 MMP(最小混相压力)约 2,450;
  • 在注入期间关闭期间,油井没有生产的石油累计超过了 Liberty 注入后获得的额外石油。

然而,Liberty 补充道,该项目表明:

  • 注射是可能的,并且可以作为常规操作的一部分进行;
  • 注入的气体可以包含在巴肯和三叉以及装置本身内。此外,它还可以回收、出售或在 EOR 中重新使用;
  • 压力正在增加,因此通过更强烈的注射可能可以实现 MMP;
  • Bakken 井和 Three Forks 井需要大量天然气才能将压力恢复到至少 2,450 psi。但最好一开始就从压力至少为 2,450 psi 的井开始;
  • 最好的办法可能是注入比租赁所生产的更多的天然气。

自由号的下一个飞行员将使用消耗较少的装置,因此在开始喷射时具有更高的 psi。预计这将减少天然气需求量以及油井关闭时间。

巴肯由西向东

北达科他州能源与环境研究中心 (EERC) 助理主任 James Sorenson 和 EERC 首席工程师兼油田运营小组负责人 James Hamling 于 2016 年审查了巴肯 EOR 项目,并在《美国石油》上报告了调查结果&天然气记者。

这些项目的范围从二氧化碳到气田注气再到注水,并从该地区的远西边界到远东观察巴肯河。

页岩

科罗拉多州巴肯远西地区,2009 年。在 Elm Coulee Field,巴肯水平压裂作业于 2000 年开始,三名操作员签约,看看如果在组织者中进行 COHNP 会发生什么情况好吧,燃烧树州 36-2H,位于蒙大拿州里奇兰县。

该井于 2000 年 5 月由运营商 Lyco Energy Corp. 与 Halliburton Co. 作为合作伙伴投入使用。据 Sorensen 报道,2009 年,Continental Resources Inc.、Enerplus Corp. 和 XTO Energy Inc. 开始向其中注入天然气。

页岩
ULTRecovery Corp. 董事长兼首席执行官 Jacob Jin 估计,美国五个主要致密油区现有油井的 EOR 潜力在最低情况下为 549 MMbbl。

此前,该井日产量约为 35 桶。45 天内注入约 45 MMcf 的 CO2;油井被封盖 64 天,让二氧化碳渗透进来。恢复生产后 8 天产量达到峰值 160 桶/天,并在月底前恢复到 30 桶/天。

几个月后,它就不再流动了。索伦森表示,安装抽油机后,注入前的生产速度恢复了。该井已经停产并开始注入二氧化碳一年了。

索伦森补充说,补偿井没有受到租约外二氧化碳迁移的监测;目前还不清楚租赁内是否存在二氧化碳迁移。

乔治·格林斯塔夫 (George Grinestaff),Shale IOR LLC 首席执行官
Shale IOR LLC  首席执行官 George Grinestaff 表示,在 Eagle Ford
石油挥发性窗口中
,试点
EOR 项目
已经
证明是有效的。


截至 2016 年,Elm Coulee 生产了 168 MMbbl 石油,这是蒙大拿州发布年度石油和天然气评论的最后一年。当年,它仍以 8.4 MMbbl 的产油量位居该州第一大油田。

科罗拉多州远东巴肯,2008 年。与此同时,Sorensen 写道,EOG Resources Inc. 从 2008 年底开始在北达科他州 Mountrail 县 Parshall Field 的 Austin 1-02H 进行了 CO2 测试。该井于 2007 年 12 月投入使用,是“内森东部(背斜)”开发项目的一部分,将水力压裂水平成功延伸至威利斯顿盆地的东部边界。

EOG 在内森河以东所做的工作的不同之处在于它使用了分段压裂技术。蒙大拿州燃烧树州立大学的揭幕战是裸洞比赛。

根据州档案,奥斯汀 1-02H 于 2007 年 12 月 13 日产量为 781 桶。截至今年 8 月,累计产量为 602,769 桶。

Sorensen 写道,2008 年 EOR 试点使用了 30 MMcf 的 CO2,但没有有关测试前或测试后油藏条件的数据。“然而,注入 11 天后,在向西 1 英里的偏置井 [Austin 2-03H] 中观察到二氧化碳突破。”(Austin 2-03H 到今年 8 月的累计产量为 667,943 桶。 )

与此同时,距奥斯汀 1-02H 一英里范围内的另外三口井“没有看到突破,这表明了解当地天然裂缝系统是 EOR 规划的关键,”索伦森写道。

远东巴肯,水驱,2012 年。同样在 Parshall 油田,EOG 于 2012 年测试了 Wayzetta 4-16H 水驱,根据州数据,4 月至 5 月注入了 39,177 桶采出水,10 月至 11 月又注入了 45,171 桶采出水,总计 84,348 桶。

根据井文件,Wayzetta 在 2008 年 7 月开采了 667 桶石油。截至今年 8 月累计产量为 499,957 桶。截至 8 月份,累计注入水量为 89,219 桶。

索伦森写道:“再次强调,没有公开测试前或测试后油藏状况的数据。” 由于注水,石油产量没有明显的增量改善。”

州数据显示,注入前一个月该井每天产油 135 桶。在治疗后的第一个月,每天产量为 59 桶。在第二次治疗开始之前,这一数字提高到了 83 桶/天。

第二次带回来时,产量为 50 桶/天。在接下来的几个月里,这一数字提高到了 82 桶/天。

EOG 在油井档案中没有描述,该井因作业而被停运后,于 2014 年 1 月恢复生产,产量为 227 桶/天。今年 8 月,产量为 18 桶/天。

远东巴肯,带气体追逐器的水,2012-2014 年。索伦森描述了帕歇尔机场的第三位 EOG 飞行员。其中,从 2012 年 4 月开始到 2014 年 2 月,向 Parshall 20-03H 注入了 447,471 桶。

根据州数据,该井 2008 年 5 月产量为 1,347 桶。处理前的产量为 60 桶/天。2014 年恢复生产时产量有所减少。

根据州数据,当年夏天 EOG 之后进行了现场气体注入,总计 89 MMcf。该井恢复正常生产,产量为 95 桶/天。

该井总共停工了 26 个月。今年 8 月的产量为 30 桶/天。

索伦森写道,“没有关于测试前或测试后储层条件的数据,井文件中没有任何内容表明操作员认为测试活动是成功的。”

他补充说,“在两口偏置井中观察到流体生产率的变化,这表明井之间的连通可以迅速发生。”

巴肯·赫斯

索伦森在报告中补充道,“重要的是要记住,巴肯油田是一个非常规的致密油区。”

他写道:“从‘传统’角度来看,高度裂缝且基质致密的储层不适合任何传统的 CO 提高采收率方法。” “这就是为什么应该在开拓性努力的背景下看待这些早期的[严格的 EOR] 测试并做出相应的判断。

“研究结果强烈表明,传统的 [HnP] 方法在非常规地层中不会有效。”

赫斯公司巴肯油井工厂总监道吉·麦克迈克尔 (Dougie McMichael) 告诉《勘探与生产》杂志,赫斯公司正在考虑在其威尔利斯顿盆地租赁地 EOR 的何处进行作业Hess 在二叠纪盆地运营常规岩石二氧化碳 EOR,并于 2017 年以 6 亿美元的价格将其出售给西方石油公司 (Occidental Petroleum Corp.)。

麦克迈克尔说,虽然巴肯盆地“结构复杂,具有致密的岩石基质”,但该地层“在整个盆地内变化很大”。

赫斯的前身阿美拉达石油公司 (Amerada Petroleum Corp.) 于 1951 年在北达科他州发现了 C. Iverson 1 号石油发现井。赫斯的名字出现在该州数千份油井档案中。麦克迈克尔说,凭借其在巴肯的大量租赁权,它“可以通过观察整个地层岩石的特征来决定我们认为申请最有可能成功的地方”。

面临的挑战包括 EOR 工作是否会产生足够的额外石油、哪种注入剂在不需要大量注入剂的情况下效果最好(即成本太高)以及如何保持其租赁状态。

美国页岩气区的其他致密岩运营商正在保持其 EOR 情报的严格性——你可以想象这种技术可能具有竞争优势,”麦克迈克尔补充道。

但是,从公开的情况来看,其他页岩油的 EOR 挑战与巴肯运营商的挑战类似,他说。

EOG、伊格尔福特 EOR

操作员尽可能地堵住漏洞,持续尽可能长的时间。例如,当EOG在威利斯顿盆地东部部署分段压裂时,它要求州政府改变保密状态政策,从开工后开始,而不是从IP开始。

EOG 请求称,水力压裂水平井需要很长时间,因此开钻后六个月的规则并不公平。该规则在完成后六个月内改为严格限制结果。

在德克萨斯州,当 EOR 项目显示“积极回应”时,如果运营商希望获得 50% 的遣散费折扣,则必须向铁路委员会 (RRC) 提交 H-13 表格。迄今为止,已有 7 份 H-13 申请据 Shale IOR LLC 称,该项目已获得批准。

该公司已汇总了迄今为止 30 个 Eagle Ford EOR 试点和项目的所有公开数据。首席执行官 George Grinestaff 在 9 月份的 Hart Energy DUG Eagle Ford 会议上对与会者表示,从 EOG 和其他 EOR 试点中确实学到的东西是不要在挥发性石油航道上进行“试点”。

相反,“试点已经为你完成了,”他说。因此,“你可能想要进行一个完整的项目。”

如果考虑“低 API 黑油窗口,现在我们需要谈谈,”他说。那里的 EOR 工作还处于起步阶段。“我们必须真正开始做一些设计。但我永远不会说黑油窗口是不行的,因为我们(在这个行业)总是对我们能做的事情感到惊讶。”

页岩 IOR 查看了 30 个 EOR 目标中的井、垫/单元和其他细节。“虽然不太容易找到,但我们已经走遍了所有的[地点],”他说。

页岩
在 EOR 之前,根据当时的产量下降,预测 EOG Resources Inc. 位于德克萨斯州卡恩斯县的 Vincent 八井试验井的最终产量为每口井 1.4 MMbbl。EOR 后结果表明为 2.4 MMbbl。

在巴肯,由于天然裂缝,使储层恢复到泡点或更高是一个挑战。不过,Eagle Ford“可以实现高达 8,000 psi 的表面注入压力,这确实是通过租赁天然气实现高采收率所需要的,”他在 10 月份告诉《投资者》

Grinestaff 估计每年有 2,500 口 Eagle Ford 井正在接近其经济极限。“由于石油质量和/或天然气供应情况,在某些地区 EOR 不会成为候选方案,”他补充道。

与此同时,他表示,在开发租赁权时,应该预计到 EOR,但运营商的资源、钻探和完井都很少,“这就是游戏的名称”。不过,一些 EOR 基础设施可以作为项目的一部分安装。该单位的开发和“并不是非常昂贵。”

开始注气的最佳时间至少是在开泵之前。例如,在二叠纪盆地,运营商无法从伴生气中获得太多(如果有的话),因此回注可能是值得的。

“注气项目中最大的支出之一是购买天然气来填充枯竭的油井。一旦加满,90% 的气体就会被回收利用,”他说。“但是越早开始,加油就越便宜。”

耐心是必不可少的。“开始执行这样的过程通常需要两到四年的时间。它移动得很慢。”

Shale IOR 首席运营官 Chris Barden 表示:“最重要的是它有效。” 现在已经证明了。如果不拥有所有补偿井,那么将天然气流失到邻居的井中“确实是最大的风险。”

DUG Eagle Ford 的 Grine 工作人员表示,最重要的是了解注气 EOR 中的烃相行为。在鹰福特的飞行员身上,“它”真的消失了。天然气本身会调动大量石油,而您正在生产这口井,就像生产凝析气井一样,因此您确实必须关注相行为。”

启动成本可能为1000万美元;与此同时,补充期间现金流量下降。“如果您可以使用自己的天然气和加工,经济就会发生变化。但这是一个稳健的过程。

“石油就在那里,我们相信您每天增加 200 桶就能获得一致、稳健的结果。”

鹰福特 EOR、康菲石油公司

Shale IOR 研究过的 Eagle Ford 项目中,有一些是由康菲石油公司 (ConocoPhillips) 负责的,该公司迄今为止已拥有 1,200 多口井。从 2009 年开始,累计净产量超过 3.75 亿桶油当量 (MMboe)。

康菲石油公司墨西哥湾沿岸业务部副总裁埃里克·艾萨克森 (Erec Isaacson) 在 DUG Eagle Ford 表示,目前的项目是三个注气 HnP,全部位于天然气驱动较低的黑油窗口。

“我们在 EOR 试点期间所做的关键事情之一就是收集数据”,我们可以使用这些数据来推进技术,在我们进行 EOR 流程时进行创新,这样我们就可以了解在 Eagle Ford 油田的各个领域对欧元影响最大的机制。”

这是一项遗产资产,“它”是我们皇冠上的宝石之一。我们面前还有[3]亿桶尚未生产。我们还有数千口井尚未钻探,”他说。

Protégâ Energy III LLC 董事长兼首席执行官 Marty Thalken 告诉与会者,他迄今为止看到的 EOR 项目涉及约 400 口井。“如果他们正在逐步康复,则必须将结果报告给德克萨斯州 RRC(在 H-13 积极响应证书中)。”

他提到了 EOG 在德克萨斯州卡恩斯县的 Vincent 八井 EOR 试点项目。EOR 之前,根据当时的产量下降,预测每井最终产量为 1.4 MMbbl。EOR 后结果表明为 2.4 MMbbl。

他估计 Eagle Ford 注气 EOR 在 55 美元石油价格下的 ROR 为 80% 或更高;以 40 美元的西德克萨斯中质油计算,IRR 超过 40%。

“迄今为止,已向德克萨斯州 RRC 报告的项目仍处于不同阶段;然而,他们指出的增量石油采收率范围在 15 至 31 个月内从 12 万桶到 52 万桶不等。”他说。

CO 2处理,二叠纪

据勘探与生产报告称,Oxy 是一家长期从事常规岩石二氧化碳开采的运营商,其在米德兰和特拉华盆地的致密岩石中正在进行 EOR 试点其目标是最终将 EOR 整合到良好的开发水平。

二叠纪页岩产量主要归因于“溶液气驱采收机制”,并且“产量急剧下降,预期最终采收率较低”,Oxy 油藏工程师刘顺华 (Shunhua Liu) 是该研究的主要作者。 2018 年非常规资源技术会议 (URTeC) 上发表的一篇论文。

Oxy 团队成员与 Core Laboratories NV 一起对从新井采集的 Wolfcamp 岩心样本进行了实验室级实验。将样品引入二氧化碳、甲烷和未经过滤的现场生产的气体中。平均样品的孔隙率为 7%。

在PVT(压力、体积、温度)测试中,三种气体的注入均证明了“在初始储层压力条件下的混溶性,但CO”是最有效的溶剂,首次接触混溶性处于测试的最低水平压力,”吕报告道。

然后,该团队测试了如果在油藏条件下使用直径为 1 英寸、长度为 2 英寸的页岩岩心塞和二氧化碳,会发生什么情况。这些“显示出良好的结果,包括在多达七个连续 [HnP] 循环中良好的石油采收率和二氧化碳利用率。”

油在循环过程中也会发生变化。核磁共振测试显示“油饱和度显着降低”,因此“该过程的提取效率很高”。

最大的石油采收率是第一个 HnP 循环的 0.25 克,这是符合预期的,但随后的 HnP 循环收集了额外的石油,甚至在第 6 个循环中也回收了 0.035 克。第七个循环生产的石油不足以衡量。

Lui 写道,“多周期增量采收——即使是在小岩心塞规模上——也表明了未来 [Wolfcamp] 非常规 EOR 项目设计中多个 HnP EOR 周期的巨大潜力。”

第一个周期生产出最轻的油(低于 C16);较重的油随后出现。

运营商已经在巴肯和伊格尔福特进行了 EOR 测试,进行二氧化碳和采出气注入以及尝试化学注入。但这些系统的岩石和流体特性与二叠纪不同,Lui 补充道。

生物增产,二叠纪盆地

研究人员利用两口二叠纪井,研究了一些(甚至可能是大量)页岩井急剧下降是否是由于完井过程中引起的污染造成的。该测试喂养了井下自然存在的细菌,激活它们吞噬堵塞诱导裂缝的材料,包括每一个几乎看不见的支撑剂颗粒。

主要作者、ULTrecovery Corp. 董事长兼首席执行官 Jacob Jin 在今年夏天的 URTeC 会议上报告了现场级二叠纪页岩“微生物 HnP”EOR 测试的结果。参与这项研究的是俄克拉荷马大学。

Jin 写道,非常规岩石的快速下跌和低欧元的原因有很多。但其中包括来自胶凝剂和部分水解聚丙烯酰胺 (HPAM) 的污染,它们是“滑溜水的主要成分”。

该小组通过“向改造后的储层体积(SRV)注入微生物营养物,使本地有益微生物生长,从而降解残留的压裂液化学物质”来疏通孔隙。所发生的情况是“原本堵塞的流动路径被堵塞了”。重新开放。”

现场测试于2018年7月进行了垂直和水平测试。报告中没有指明这些井的所有者。

米德兰盆地北部的垂直施工已于 2015 年在 Spraberry 和 Wolfcamp A 下部约 9,000 英尺处完成,使用的是交联瓜尔胶基流体。其IP约为110桶/天;截至 2018 年 6 月累计产量约为 13,200 桶。

“由于产液率低,这台井泵无法每天 24 小时运行,”金写道。EOR 试验时的井口压力约为 48 psi,该试验将 500 桶用于本土细菌的维生素泵入井中。

预处理产量为每月 274 桶;几个月后,治疗后峰值为每月 662 桶。2019 年 3 月的日均产量比 2018 年 6 月增加了 113%。“项目回款约四个月,ROR 远远超过 100%,”金写道。

测试的水平线位于佩科斯河以西的特拉华盆地北部。这条 4,500 英尺长的支线于 2014 年在 Wolfcamp A 海拔约 9,900 英尺处用滑溜水完成,共有 20 个赛段。初始压力约为7,000 psi,IP约为630 bbl/d。

截至 2018 年 6 月,产量约为 174,000 桶。井口压力约为 300 psi。其中还注射了 500 桶维生素。

Shale IOR LLC 首席执行官 George Grinestaff 估计,每年有 2,500 口 Eagle Ford 井正在接近其经济极限。同时,在开发租赁权时应预期 EOR。

预处理产量为138.5桶/天;处理后峰值为 2018 年 9 月 303 桶/天。2019 年 1 月,处理后 6 个月,平均日产量比处理前增加 122%,这向研究团队表明细菌仍在井下继续工作。

一次处理的额外费用约为 25,000 桶或约 9%。付款时间约为2.5个月;Jin 报告称,ROR“几乎”超过 100%。

总体而言,在这两项试验中,液体产量在 180 天内提高了 40% 至 127%,“这意味着原本受污染的 SRV 已被受刺激的有益微生物畅通无阻。”

治疗后 8 个月内,垂直产量比治疗前建议的下降率多了 1,500 桶;八个月后,横向产量增加了约 12,000 桶。

“压裂直井和水平井的欧元增量分别为 2,100 桶和 25,000 桶,”金写道。“治疗后欧元增加了 9% 到 12%。

“两种治疗的费用都在两到四个月内。两名飞行员的 ROR 均超过 100%。”

在这两种情况下,“考虑到仅注入了 500 桶微生物营养物,并且营养物并未接触到所有裂缝,未来更大规模的治疗可能会产生更多的欧元增量。”

由于基于细菌的测试表明,直井 EUR 可以提高约 12%,水平井 EUR 可以提高 9%,“美国五个主要页岩油区现有油井的 EOR 总潜力为 549 MMbbl”,小情况。

“如果重复几次 [HnP] 处理,可能会回收更多的石油。”

他指出,生产商不愿意扰乱井下细菌,担心这可能导致“浇水、生物腐蚀、硫化氢、堵塞储层等”。

不过,Jin 写道,ULTRecovery 过程中不含硫酸盐。


[侧边栏故事]

Hess 探索 EOR 进展

为了不断从油藏中提取更多搁浅的碳氢化合物,赫斯公司、陶氏化学公司和美国能源部 (DOE) 合作开展了一项联合计划,资助怀俄明大学 (UW) 对泡沫辅助 EOR 技术的研究。

8 月,美国能源部捐赠了 800 万美元,作为赠款研究和现场试点测试计划的一部分,陶氏化学公司、威斯康星大学和赫斯大学也总共捐赠了 200 万美元。华盛顿大学的研究人员认为,泡沫辅助碳氢化合物气体注入技术可以帮助从非常规油藏中多采收 3% 至 5% 的石油。

“我们的主要驱动力实际上是有能力从非常规油藏中开采更多原油,”赫斯巴肯技术高级经理 Khalid Shaarawi 说。

“目前,很大一部分石油在初次枯竭期间被留下。因此,我们希望找到一种方法,从地下开采更多石油,释放剩余的数十亿桶石油。”

沙拉维表示,如果该技术的最终试验成功,这将成为回收搁浅储量的“改变者”。

Hess 油藏工程负责人 Srini Prasad 表示,威斯康星大学正在进行的研究建立在之前的努力基础上,最初的重点是应用注气作为 EOR 工艺。

“我们发现气体注入在实验室中有效,”他说。“它可以开采石油,但我们面临的问题之一是由于油藏中的天然裂缝和水力裂缝而导致的突破性问题。

“这就是我们开始 EOR 下一阶段的原因,我们将使用泡沫,使用陶氏开发的化学品,在实验室中进行测试,然后进行现场测试,以便能够做得更好提高采收率的工作不仅仅是使用注气。”

普拉萨德表示,巴肯 EOR 的现场测试已经进行了较小规模的测试,但这将是赫斯的第一个大规模试点。

华盛顿大学研究员、怀俄明州石油工程卓越主席穆罕默德·皮里 (Mohammed Piri) 表示,在整个研究项目过程中获得的知识将用于校准计算模拟,以更好地预测现场表现、评估和减轻潜在风险并确保在现场成功实施。

Hess 表示,EOR 研究将在该大学与 Hess 合作建立的高湾研究设施内的先进石油和天然气实验研究设施中进行。在过去六年中,Hess 向威斯康星大学工程与应用科学学院捐赠了 2500 万美元,以增进对巴肯等区域中复杂的岩石与流体相互作用的理解。

Shaarawi 表示:“ESS 与 [威斯康星大学] 进行了战略合作,这确实为 Hess 带来了很多价值,并帮助我们提供解决方案来满足世界不断增长的能源需求。” “我们依赖 [威斯康辛大学] 的突破性研究能力以及他们为我们提供的高端技术服务。” Brian Walzel

原文链接/hartenergy

Shale EOR: Found Oil

Tight-rock operators are testing EOR ideas to produce more oil where they’ve already made hole. Here are some of their findings.

[Editor's note: A version of this story appears in the December 2019 edition of Oil and Gas Investor. Subscribe to the magazine here.]

Maybe give that bacteria that’s downhole some vitamins. Or pump that field gas back into the well. Soak the hole with CO₂? Soak it in water? Give it some water with a field-gas chaser?

The right recipe for unconventional-rock EOR remains elusive. But operators—from the Bakken to the Eagle Ford to the Permian Basin—are looking at all the formulae yet imaginable. They’ve started with what conven­tional-rock formations seem to like.

Most of it works at least a bit; some of it doesn’t work for very long. And, then, there’s the cost of this method vs. that method—and in contrast to what additional oil it nets. In addition, the math has to factor for production lost while the well is offline during treatment.

Ultimately, though, the perfect cocktail will boost wells’ EUR by a worthwhile fraction—without an operator paying for another hole at a cost of another 640 acres, 20,000 feet of pipe, dozens of frack stag­es, thousands of barrels (bbl) of water and hundreds of tons of sand.

Field-gas injection, Bakken

In the Bakken, Liberty Resources LLC did a rich-gas huff-n-puff (HnP) pilot, Stomping Horse, in 2018 through this past May. It anticipates a sec­ond trial next year that will be larger.

The test involved injection in five wells of 11 in a two-section Liberty unit in McGregor Field in eastern Williams County, along the Nesson Anti­cline. Offset wells were monitored for whether the injected gas was leaving the targeted unit.

The gas was wellhead—primarily 60% meth­ane, 20% ethane and 10% propane—with British thermal unit content of about 1,500.

A great deal was learned, according to Liberty’s follow-up report to the North Dakota Industrial Commission in September. Among the findings: This is going to need a lot more gas.

In the target area, Liberty operates adjacent sections except one north. That one is operated by Murex Petroleum Corp., which provided op­erational intel about the four wells in its unit as Liberty conducted the tests. The four Murex hor­izontals came online in 2010 through 2012 and have produced a combined 958,000 bbl of oil and 1.2 billion cubic feet (Bcf) of gas.

Overall, pilot results indicated a “demonstrated ability to inject gas within [an HnP] scheme, build pressure, contain gas within the Bakken/Three Forks intervals of the [unit] and recover injected gas,” said Gordon Pospisil, Liberty vice president, business de­velopment, and lead on the EOR projects.

The injected gas stayed within the Liberty unit. August 2019 production from the Murex wells averaged 43 barrels per day (bbl/d) and 121,000 cubic feet per day (cf/d), according to state files. June 2018 production, prior to the Liberty pilot, averaged 40 bbl/d and 111,000 cf/d.

Liberty injected a total of 158 MMcf in its wells; into this past August it had recovered 143 MMcf.

The scope was limited by the amount of gas produced from the unit and available for injection, Pospisil said, “which restricted the impact—the pressure build—within the depleted intervals and, thus, the magnitude of the oil response.”

Reservoir pressure in the unit had been more than 6,000 psi when the wells were completed; at the time of injection, pressure was less than 1,000 psi except for one well at about 1,100. Bubble point is approximately 2,500 psi.

The second pilot will involve injecting a larger amount of gas “and target wells with less deple­tion and higher initial bottomhole pressures,” Po­spisil said.

The results from each of the five injection wells:

Leon 2MBH had been brought online in March of 2016 with a 24-hour IP of 428 bbl. Cumulative production through this past Au­gust was 75,842 bbl and 300 MMcf. Injected was 13.8 MMcf during 18 days in August of 2018. Pressure pre-injection was about 1,100 psi. Oil the month prior averaged 48.5 bbl/d; the month after injection, 55.6 bbl/d.

Leon 3TFH had been brought online in March of 2016 with an IP of 272 bbl/d. Cu­mulative through this past August was 92,564 bbl and 330 MMcf. Injected was a total of 10.8 MMcf in two sets: 12 days in July of 2018 and six days in September of 2018.

Pressure at the time was about 900 psi. Oil the month prior to the first injection was 33.4 bbl/d; during the month between injections, 43.3 bbl/d; the month after the second injection, 35 bbl/d.

Gohrick 5MBH had IPed 1,032 bbl/d in December of 2014. Cumulative through this past August was 240,507 bbl and 608 MMcf. Injected was a total of 42 MMcf in two sets in the fourth quarter of 2018: one for 11 days; the other, 33 days.

Pressure at the time of injection was less than 600 psi. Oil the full month prior to treatment was 21.4 bbl/d; the first full month after the set of in­jections, 45.1 bbl/d.

Gohrick 4MBH IPed 1,191 bbl/d in No­vember of 2014. Cumulative through this past August was 229,557 bbl and 563 MMcf. In­jected was a total of 75 MMcf over 29 days during this past January into May. Psi at the time was less than 1,000.

Production the full month prior to the first injec­tion was 17.5 bbl/d; the first full month after the last injection, 17.9 bbl/d.

Gohrick 6TFH IPed 1,067 bbl/d in January of 2015. Cumulative through this past August was 141,367 bbl and 455 MMcf. Injected was 17.4 MMcf during 15 days in May. Psi at the time was 713. Production in the month prior to injection was 17.8 bbl/d; in the month after injection, 33.5 bbl/d.

All five of the wells were returned to production in August. Liberty cited several issues in the fol­low-up report:

  • The pilot-project gas supply was limited to what the unit had been producing;
  • The wells used were fairly depleted; static bot­tomhole pressure was well below MMP (mini­mum miscibility pressure) of about 2,450; and
  • The oil the wells didn’t make—while shut-in during injection—was cumulatively more than what additional oil Liberty got post-injection.

However, Liberty added, the project demonstrat­ed:

  • Injection is possible and can be done as part of routine operations;
  • The injected gas can be contained within the Bakken and Three Forks and within the unit itself. Also, it can be recovered—for sale or for re-use in EOR;
  • Pressure was building, thus MMP is likely achievable with more intense injection;
  • A substantial amount of gas is needed to restore pressure to at least 2,450 psi in Bakken and Three Forks wells. But it would be better to start with wells with at least 2,450 psi in the first place; and
  • It’s probably best to inject more gas than just what the lease is producing.

Liberty’s next pilot will use a less-depleted unit, thus having a higher psi at the time of commencing injection. It expects this will reduce how much gas is needed and how long the wells will be shut in.

Bakken west to east

James Sorenson, an assistant director with North Dakota’s Energy & Environmental Research Center (EERC), and James Hamling, EERC principal en­gineer and oilfield operations group lead, reviewed Bakken EOR projects in 2016, reporting the find­ings in American Oil & Gas Reporter.

The projects ranged from CO₂ to field-gas injec­tion to waterflood and looked at the Bakken from the play’s far western boundary to the far east.

shale

Far western Bakken, CO₂, 2009. Over in Elm Coulee Field, where the fracked, horizontal Bak­ken play began in 2000, three operators signed on to see what would happen if doing a CO₂ HnP in the play-maker well, Burning Tree State 36-2H, in Richland County, Mont.

The well had been brought online in May of 2000 by operator Lyco Energy Corp. with Halliburton Co. as a partner. In 2009, Continental Resources Inc., Enerplus Corp. and XTO Energy Inc. began injecting gas into it, Sorensen reported.

shale
The EOR potential of existing wells in the five major U.S. tight-oil plays is 549 MMbbl as the low case, estimates Jacob Jin, ULTRecovery Corp. chairman and CEO.

Prior, the well was producing some 35 bbl/d. Some 45 MMcf of CO₂ was injected in 45 days; the wells were capped for 64 days to let the CO₂ soak in. Production peaked at 160 bbl/d eight days after brought back online and returned to 30 bbl/d before the month’s end.

In a few months, it wasn’t flowing at all. Put on pumpjack, the pre-injection rate of production resumed, according to Sorensen. It was a year since the well had been taken offline to start CO₂ injection.

Sorensen added that offset wells weren’t moni­tored for CO₂ migration off-lease; it’s also unknown whether there was CO₂ migration intra-lease.

George Grinestaff, CEO of Shale IOR LLC
In the volatile-oil
window of the
Eagle Ford, pilot
EOR projects
have already
proven they work,
said George
Grinestaff, CEO of
Shale IOR LLC. 

Elm Coulee made 168 MMbbl of oil through 2016, the last year for which Montana published an annual oil and gas review. In that year, it re­mained the No. 1 oil-producing field in the state with 8.4 MMbbl.

Far eastern Bakken, CO₂, 2008. Meanwhile, EOG Resources Inc. did a CO₂ test on Austin 1-02H in Parshall Field, Mountrail County, N.D., beginning in late 2008, Sorensen wrote. The well had been brought online in December of 2007 and had been a part of the “east of the Nesson (Anti­cline)” play-opener, taking fracked horizontal suc­cess to the eastern boundary of the Williston Basin.

The different aspect of what EOG was doing east of the Nesson was its use of staged fracturing; the play-opener Burning Tree State in Montana had been openhole.

Austin 1-02H had IPed 781 bbl on Dec. 13, 2007, according to state files. Cumulative was 602,769 bbl through this past August.

Sorensen wrote that 30 MMcf of CO₂ was used in the 2008 EOR pilot, but data were not available on pre- or post-test reservoir conditions. “However, af­ter 11 days of injection, CO₂ breakthrough was ob­served in offset well [Austin 2-03H] 1 mile west.” (Austin 2-03H’s cumulative through this August was 667,943 bbl.)

Meanwhile, three other wells within a mile of Austin 1-02H “did not see CO₂ breakthrough, sug­gesting that understanding the local natural fracture system is key to EOR planning,” Sorensen wrote.

Far eastern Bakken, waterflood, 2012. Also in Parshall Field, EOG tested waterflooding Wayzetta 4-16H in 2012, injecting 39,177 bbl of produced water that April through May and another 45,171 bbl in October through November, totaling 84,348 bbl, according to state data.

Wayzetta had IPed 667 bbl of oil in July of 2008, according to the well file. Cumulative through this past August was 499,957 bbl. Cumulative water—deducting for what was injected—through August was 89,219 bbl.

Sorensen wrote, “Again, no data on pre-test or post-test reservoir conditions are publicly available. There was no observable incremental improvement in oil production attributable to water injection.”

State data show the well made 135 bbl/d of oil in the month prior to injection. In the first full month post-treatment, it made 59 bbl/d. That improved to 83 bbl/d before the second treatment began.

When brought back on the second time, it was making 50 bbl/d. That improved to 82 bbl/d in subsequent months.

After taking the well offline for work that EOG didn’t describe in the well file, it came back on with 227 bbl/d in January of 2014. This past Au­gust, it was making 18 bbl/d.

Far eastern Bakken, water with a gas chaser, 2012-2014. Sorenson wrote of a third EOG pilot in Parshall Field. In this, 447,471 bbl were inject­ed into Parshall 20-03H beginning in April 2012 and through February 2014.

The well had IPed 1,347 bbl in May of 2008, ac­cording to state data. Production prior to treatment was 60 bbl/d. Output when brought back online in 2014 was less.

EOG followed with field-gas injection that sum­mer, totaling 89 MMcf, according to state data. The well came back on with 95 bbl/d.

Altogether, the well was offline for 26 months. Production this past August was 30 bbl/d.

Sorensen wrote, “No data on pre- or post-test res­ervoir conditions are available, and there is nothing in the well file to suggest that the testing activities were considered successful by the operator.”

He added that “changes in fluid production rates were observed in two offset wells, demonstrating that communication between wells can occur rapidly.”

Hess, Bakken

Sorensen added in his report that “it is important to keep in mind that the Bakken is an unconvention­al tight oil play.

“When viewed through a ‘conventional’ lens, a reservoir that is highly fractured with a tight matrix is not a good candidate for any conventional CO₂ EOR approach,” he wrote. “That is why these early [tight-rock EOR] tests should be viewed in the con­text of pioneering efforts and judged accordingly.

“The findings strongly suggest that a convention­al [HnP] approach will not be effective in unconventional formations.”

Hess Corp. is looking at where in its Wil­liston Basin leasehold EOR will work, Dou­gie McMichael, Hess director, Bakken well factory, told E&P magazine. Hess operated conventional-rock CO₂ EOR in the Permian, selling it to Occidental Petroleum Corp. for $600 million in 2017.

McMichael said that, while the Bakken “is complex with a dense rock matrix,” the for­mation “is variable across the basin.”

A Hess predecessor, Amerada Petroleum Corp., made the North Dakota oil discovery well, C. Iverson 1, in 1951. Hess’ name is on thousands of the state’s well files. With its large Bakken leasehold, it “can look at the characteristics of the rock across the formation to decide on where we think the application has the best chance of success,” McMichael said.

Challenges include whether the EOR ef­fort will make enough additional oil, what injectant works best without requiring a lot of it—that is, being too costly—and how to keep it on lease.

Other tight-rock operators across U.S. shale plays are keeping their EOR intel tight—“as you can imagine for a technique that might have a competitive advantage,” McMichael added.

But, from what is public, it looks like the EOR challenges in other shales are similar to those of Bakken operators, he said.

EOG, Eagle Ford EOR

Operators tight-hole as much as they can for as long as they can. For example, when EOG de­ployed staged fracturing in the eastern Williston Basin, it asked the state to change the confiden­tial-status policy to begin at IP rather than after spud.

Fracked horizontals take a long time, so the six-month-since-spud rule wasn’t fair, EOG had peti­tioned. The rule was changed to tight-hole results through up to six months after completion.

Over in Texas, operators have to file an H-13 form with the Railroad Commission (RRC) if wanting a 50% discount on severance taxes when an EOR project indicates “positive response.” Seven of the H-13 applications to date have been approved, according to Shale IOR LLC.

The firm has put together all publicly available data for 30 Eagle Ford EOR pilots and projects to date. Something certainly learned from EOG’s and others’ EOR pilots is to not do a “pilot” in the volatile-oil fairway, George Grinestaff, CEO, told attendees at Hart Energy’s DUG Eagle Ford conference in September.

Rather, the “piloting has already been done for you,” he said. So, instead, “you may want to go with a full project.”

If looking at “the low-API black-oil window, now we need to talk,” he said. EOR work there is too nascent. “We have to really start doing some design. But I would never say the black-oil win­dow is a no-go because we [in the industry] al­ways surprise ourselves with what we can do.”

Shale IOR looked at well, pad/unit and other de­tails among the 30 EOR targets. “It’s not so easy to get, but we’ve gone through all of the [locations],” he said.

shale
Prior to EOR, the forecast for EOG Resources Inc.'s Vincent eight-well pilot in Karnes County, Texas, was of eventual production of 1.4 MMbbl per well based on the decline at the time. Post-EOR results suggest 2.4 MMbbl.

In the Bakken, a challenge has been to get the reservoir back up to bubble point or higher, due to natural fractures. The Eagle Ford, though, “can achieve surface injection pressures up to 8,000 psi, and that’s really what you need to achieve high recovery with lease gas,” he told In­vestor in October.

Grinestaff estimates 2,500 Eagle Ford wells per year are approaching their economic limits. “There are areas where EOR will not be a candidate because of oil quality and/or gas availability,” he added.

Meanwhile, EOR should be anticipated when de­veloping the leasehold, he said, but operators have minimal resources and drilling and completion “has been the name of the game.” Still, some EOR infra­structure can be installed as part of the unit’s devel­opment and “it’s not terribly expensive.”

The best time to start gas injection is at least be­fore putting a well on pump. In the Permian, for example, where operators aren’t getting much, if anything, for their associated gas, reinjection may be worthwhile.

“One of the largest expenses in a gas-injection project is buying the gas to fill up depleted wells. Once fill-up is achieved, 90% of the gas is recy­cled,” he said. “But the earlier you start, the less expensive gas fill-up will be.”

Patience is essential. “It typically takes two to four years to start doing a process like this. It moves very slowly.”

Chris Barden, Shale IOR COO, said, “The bot­tom line is it works. It’s been proven now.” Losing the gas to neighbors’ wells, if not owning all of the offset wells, “is really the biggest risk.”

Most important is to understand the hydrocar­bon-phase behavior in gas-injection EOR, Grine­staff said at DUG Eagle Ford. In the Eagle Ford pilots, “it’s really vaporizing. The gas itself is mo­bilizing a lot of oil, and you’re producing the well just like you would a gas-condensate well, so you really have to focus on the phase behavior.”

Start-up may cost $10 million; meanwhile, cash flow declines during refill. “If you can use your own gas and processing, the economics change. But it is a robust process.

“The oil is there, and we believe you can get a consistent, robust result—an incremental 200 bbl/d.”

Eagle Ford EOR, ConocoPhillips

Among the Eagle Ford projects Shale IOR has studied are some by ConocoPhillips, which has more than 1,200 wells in the play to date. Cumu­lative production is more than 375 million barrels of oil equivalent (MMboe), net, beginning in 2009.

Current projects are three gas-injection HnPs, all in the black-oil window where there is lower gas drive, Erec Isaacson, ConocoPhillips vice president, Gulf Coast business unit, said at DUG Eagle Ford.

“One of the key things we’re doing during our EOR pilots, again, is gathering data—data that we can use to advance the technology, to innovate as we’re going through our EOR processes, so we can understand what mechanisms are impacting EUR most for us in the various areas of our Eagle Ford field.”

A legacy asset, “it’s one of our crown jewels. We have [3] billion bbl yet to produce in front of us. We have thousands of wells yet to drill,” he said.

Marty Thalken, chairman and CEO of Protégé Energy III LLC, told conference attendees that the EOR projects he has seen to date involve some 400 wells. “The results have to be reported to the Texas RRC [in an H-13 positive-response certifi­cate] if they’re getting incremental recovery.”

He pointed to EOG’s Vincent eight-well EOR pilot in Karnes County, Texas. Pre-EOR, the fore­cast was of eventual production of 1.4 MMbbl per well based on the decline at the time. Post-EOR results suggest 2.4 MMbbl.

He estimates Eagle Ford gas-injection EOR at $55 oil has an 80% or higher ROR; at $40 West Texas Intermediate, the IRR is more than 40%.

“Those that have reported to the Texas RRC to date remain in various stages; however, the range of incremental oil recovery they are indicating varies from about 120,000 to 520,000 bbl during between 15 and 31 months,” he said.

CO2 treatment, Permian

A longtime CO₂-in-conventional-rock operator, Oxy has EOR pilots underway in tight rock in the Midland and Delaware basins, according to an E&P report. It aims to integrate EOR at the well-develop­ment level eventually.

Permian shale production is largely due to “a solu­tion-gas-drive recovery mechanism” and has “steep production declines and low expected ultimate re­coveries,” Shunhua Liu, an Oxy reservoir engineer, reported as lead author of a paper presented at the Unconventional Resources Technology Conference (URTeC) in 2018.

Oxy team members, along with Core Laborato­ries NV, did a lab-level experiment on Wolfcamp core samples taken from a new well. The samples were introduced to CO₂, methane and unfiltered field-produced gas. The average sample had poros­ity of 7%.

In the PVT (pressure, volume, temperature) test, injection of each of the three gases demonstrated “miscibility at initial reservoir pressure condi­tions, but CO₂ was the most efficient solvent, with first-contact miscibility at the lowest tested pres­sure,” Lui reported.

The team then tested what would happen if us­ing shale core plugs—each 1 inch in diameter and 2 inches in length—with CO₂ at reservoir conditions. These “showed favorable results, including good oil recovery and CO₂ utilization in up to seven con­secutive [HnP] cycles.”

The oil changed during the cycles as well. A nu­clear magnetic resonance test showed “significant oil-saturation reduction,” thus “the extraction effi­ciency of this process.”

The greatest oil recovery—0.25 gram—was from the first HnP cycle “as expected,” but subsequent HnP cycles collected additional oil with 0.035 gram coming “even in Cycle 6.” The oil produced from the seventh cycle wasn’t enough to measure.

“The multicycle incremental recovery—even at the small core-plug scale—suggests the significant potential for multiple HnP EOR cycles for a future [Wolfcamp] unconventional EOR project design,” Lui wrote.

The lightest oil—less than C16—was produced in the first cycle; the heavier oil came later.

EOR tests in the Bakken and Eagle Ford—using CO₂- and produced-gas injection as well as trying chemical injection—have been tried by operators. But the rock and fluid properties of these systems are different than in the Permian, Lui added.

Bio-stimulation, Permian Basin

Using two Permian wells, researchers looked into whether some—or maybe even a lot—of steep shale-well decline is because of contamination in­duced during completion. The test fed bacteria that are naturally occurring downhole, activating them to eat up materials clogging the induced fractures, including each of the nearly invisible grains of proppant.

The findings of the field-level, Permian shale “microbial HnP” EOR test were reported at URTeC this summer by lead author Jacob Jin, ULTRecov­ery Corp. chairman and CEO. Participating in the study was the University of Oklahoma.

The reasons for rapid decline and low EUR from unconventional rock are myriad, Jin wrote. But among them is contamination—such as from gellants and partially hydrolyzed polyacrylamide (HPAM) that “is the main component of slickwa­ter.”

The group unclogged the pores by “injecting mi­crobial nutrients to the stimulated reservoir volume (SRV) to grow the indigenous beneficial microbes to degrade the residual fracturing-fluid chemicals.” What happened was “the otherwise-blocked flow paths are reopened.”

The field tests were done in July of 2018 in a ver­tical and in a horizontal. The wells’ owners weren’t identified in the report.

The vertical—in the northern Midland Ba­sin—was completed in 2015 in lower Spraberry and Wolfcamp A at about 9,000 feet with cross­linked, guar-based fluid. Its IP was about 110 bbl/d; cumulative by June of 2018 was about 13,200 bbl.

“This well pump could not run 24 hours per day due to [the] low liquid-production rate,” Jin wrote. Wellhead pressure at the time of the EOR trial, which pumped 500 bbl of vitamins for the indige­nous bacteria into the hole, was about 48 psi.

Pre-treatment production was 274 bbl per month; post-treatment peak was 662 bbl per month a few months later. Average daily production in March 2019 was 113% more than in June 2018. “The proj­ect payout is about four months, and the ROR is far more than 100%,” Jin wrote.

The tested horizontal is in the northern Del­aware Basin west of the Pecos River. The 4,500-foot lateral was completed with 20 stages in 2014 at about 9,900 feet in Wolfcamp A with slickwater. Initial pressure was about 7,000 psi, and IP was about 630 bbl/d.

By June of 2018, it had produced about 174,000 bbl. Wellhead pressure was some 300 psi. In this one, 500 bbl of vitamins were injected as well.

George Grinestaff, CEO of Shale IOR LLC, estimates 2,500 Eagle Ford wells per year are approaching their economic limits. Meanwhile, EOR should be anticipated when developing the leasehold.

Pre-treatment production was 138.5 bbl/d; post-treatment peak was 303 bbl/d in September 2018. In January 2019, six months after treatment, average daily production was 122% more than pre-treatment, suggesting to the research team that the bacteria were continuing to work downhole.

The additional EUR is about 25,000 bbl or about 9% from one treatment. Payout was about 2.5 months; the ROR, “far more” than 100%, Jin re­ported.

Overall, among the two trials, liquid production improved between 40% and 127% in 180 days, “which means the otherwise-polluted SRV was un­blocked by the stimulated, beneficial microbes.”

In eight months after treatment, the vertical made 1,500 bbl more than the pre-treatment decline rate suggested it should; the horizontal, after eight months, about 12,000 bbl more.

“The incremental of EUR of the fractured verti­cal and horizontal wells was 2,100 bbl and 25,000 bbl, respectively,” Jin wrote. “And the EUR after the treatment is increased by [between] 9% and 12%.

“The payouts for both treatments were [in] two to four months. The ROR for both pilots is more than 100%.”

In both cases, “considering only 500 bbl [of] mi­crobial nutrients were injected and not all the frac­tures were contacted by the nutrients, a larger treat­ment in future might incur more incremental EUR.”

As the bacteria-based tests suggest vertical-well EUR may improve by about 12% and horizontal by 9%, “the total EOR potential of the current existing wells in the five major U.S. shale oil plays is 549 MMbbl” of oil as the low case.

“If the [HnP] treatment is repeated several times, more additional oil might be recovered.”

He noted that producers are reluctant to perturb bacteria downhole, though, with concern that it could result in “souring, biocorrosion, hydrogen sulfide, plugging the reservoir, etc.”

The ULTRecovery process doesn’t contain sul­fate, though, Jin wrote.


[Sidebar story]

Hess Explores For EOR Advances

In the ongoing effort to extract ever more stranded hydrocarbons from reservoirs, Hess Corp., Dow and the U.S. Department of Energy (DOE) have partnered in a joint program to fund research at the University of Wyoming (UW) into foam-assisted EOR technologies.

In August, the DOE contributed $8 million as part of a grant research and field pilot test program for which Dow, UW and Hess also contributed a combined $2 million. Researchers at UW believe foam-assisted hydrocarbon gas injection technology could help recover 3% to 5% more of the oil in place from unconventional reservoirs.

“The main driver for us is really to have the ability to recover more crude oil from unconventional reservoirs,” said Khalid Shaarawi, senior manager for Bakken technology at Hess.

“Right now, a significant portion of oil is left behind during primary depletion. So we want to find a way to get more oil out of the ground, unlocking those billions of barrels left behind.”

Shaarawi said that if an eventual test pilot for the technology is successful, it would be a “game-changer” for recovering stranded reserves.

Srini Prasad, head of reservoir engineering for Hess, said the research being conducted at UW builds upon previous efforts that initially focused on applying gas injection as an EOR process.

“What we have found is that the gas injection works in the lab,” he said. “It can extract oil, but one of the problems we have is breakthrough issues because of the natural and hydraulic fractures in the reservoir.

“That’s the reason we are embarking on this next stage of EOR where we are going to be using foam, using chemicals developed by Dow, where we test it in the lab and then field test it to be able to do a better job of enhancing the recovery than just using gas injection.”

Prasad said that field testing on Bakken EOR has been conducted on a smaller scale, but this venture will be the first large-scale pilot for Hess.

UW researcher and Wyoming excellence chair in petroleum engineering Mohammed Piri said that the knowledge gained throughout the course of the research project will be used to calibrate computational simulations to better predict field performance, assess and mitigate potential risks and ensure successful implementation in the field.

According to Hess, the EOR research will be conducted at an advanced experimental oil and gas research facility housed at the university’s High Bay Research Facility, which was established in partnership with Hess. During the past six years, Hess has contributed $25 million to UW’s College of Engineering and Applied Science to improve the understanding of complex rock-fluid interactions in plays such as the Bakken.

“Hess has a strategic collaboration with [UW] that does deliver a lot of value at Hess, and that helps us provide solutions to meet the world’s growing energy needs,” Shaarawi said. “We rely on [UW] for its groundbreaking research capabilities as well as their high-end technical services they give us.” Brian Walzel