非常规/复杂油藏

页岩生产和水再利用:应用情况和障碍分析

对于当今全球水力压裂革命而言,没有什么比获取淡水更重要,但这种依赖性使用引发了环境问题和运营挑战。

水滴涡流效应
资料来源:Getty Images。

对于当今全球水力压裂革命而言,没有什么比淡水的使用更重要,但这种依赖性使用引发了环境问题和运营挑战。为此,石油和天然气公司越来越多地转向采出水和回流液来提高可持续性。

这一主题一直是行业聚会的焦点,例如最近在休斯顿地区举行的SPE 水力压裂技术会议 (HFTC) 。

在今年的活动中,北达科他大学能源与环境研究中心 (EERC) 的研究人员展示了突出水再利用进展和局限性的研究成果。

他们的研究发现,北达科他州 40% 的运营商将生产水在一定程度上纳入其完井计划,其中 20% 的运营商使用了 EERC 认为的“大量生产水”。

然而,最终分析(详见论文SPE 223512)显示,威利斯顿盆地完井过程中使用的总水量中只有约 5% 来自循环水,其余水均来自淡水供应。相比之下,二叠纪盆地的循环利用率超过 50%。

EERC 分析还显示,估计每天有 85 万 BWPD 的石油被泵入北达科他州的地下,而每天有超过 200 万 BWPD 的石油直接流出。该州几乎所有的采出水都被送入盐水处理井,其中 10% 用于提高石油采收率,只有 5% 被重新利用或用卡车运出州外进行处理。

研究人员指出,虽然再利用在北达科他州越来越受欢迎,但运营商可以加快步伐,将盐水处理注入量减少多达 25%。但他们确实面临障碍,包括采出水盐度高,会引起不必要的化学反应,而缺乏专用输水管道意味着成本更高。

推动更大程度重复使用的努力不仅限于美国。

阿根廷国家石油公司 YPF 也正在其瓦卡穆埃尔塔页岩作业中推进水循环利用工作。该公司面临的一个主要挑战是,只有 20% 至 30% 的注入水会返回地面,其余的则被岩石基质吸收。

尽管如此,YPF 在论文SPE 223566中描述了如何开发一种将未处理的回流水与淡水混合以进行完井的工艺。

该公司发现,它可以加入高达 25% 的再生水,但这取决于测试的压裂液系统。该公司发现,淡水基减阻剂经得住考验,但采出水在泵送时会导致压力变化,这可能是由于流体系统对除淡水以外的任何物质都很敏感。

效果最好的是更可预测和更一致的高盐度聚合物。此外,新的减阻剂降低了 YPF 对聚合物的依赖,这还具有减少可怕的“假熊”效应的额外好处,据信这种效应会堵塞裂缝并导致导电性损失。

另一篇论文强调了美国一些页岩油生产商面临的一个日益严峻的挑战。NexTier Oilfield Solutions 的研究人员撰写的SPE 223549研究了在完井作业中使用用回收采出水清洗的湿砂可能带来的意外后果。

研究发现,经过清洗但未干燥的沙子(作为低成本支撑剂备受追捧)最终会保留高于预期水平的粘土、长石和方解石。当与减摩剂混合时,这些矿物会絮凝或结块,几乎总是会影响流体性能,并被认为会损害油井生产力。

流体的盐度也会影响这些细小颗粒的行为。当盐度从 4,500 ppm 增加到 115,000 ppm 时,一种名为 P-CAT 的化学物质会使细小颗粒更粘在支撑剂表面。同时,流体的 pH 值会改变颗粒聚集的方式——较高的 pH 值有利于 P-CAT,而较低的 pH 值更适合另一种化学物质 P-AN1。

NexTier 还得出结论,改善沙子清洁将进一步降低细颗粒水平,而细颗粒水平正是问题的根源。为了测试这个想法,该公司与德克萨斯州的一家砂矿运营商合作,升级了清洁流程。

第一个调整是将洗涤阶段的循环水使用量从 100% 减少到 50%。接下来,用于细料分离的旋风分离器数量从一台增加到两台。

结果显示,样品中的石英含量有所增加,而迁移粘土含量从 3.5% 减少到 1.3%。这导致浊度降低了 90%,从而提高了整体砂石质量和完井效率。

这些论文强调,水力压裂中的水再利用是一项复杂的挑战,说起来容易做起来难。然而,它们也表明,这一努力可以产生巨大的效益,这进一步表明需要继续投资研究,以提高再利用率。

进一步阅读

SPE 223549避免致命吸引力:如何防止湿砂与刺激液之间发生影响生产的相互作用,作者:S. Kakadjian、J. Kitchen 和 A. Gebrekirstos,NexTier Oilfield Solutions。

SPE 223512巴肯井刺激措施中采出水的最新发展和利用,作者:北达科他州大学能源与环境研究中心的 DD Schmidt;北达科他州矿产资源部的 G. Harms 和 A. Thiel;Arolytics 的 J. Neubeker;以及 ND 能源服务公司的 T. Hopfauf。

SPE 223566 Vaca Muerta:水再利用可持续性发展的技术方法,作者:RD Velo,YPF SA;ML Arias 和 MI Weimann,YPF Tecnología SA;以及 N. Mottes 和 SM P茅rez,YPF SA

原文链接/JPT
Unconventional/complex reservoirs

Shale Production and Water Reuse: A Look at Adoption and Barriers

Few things are more essential to the now global hydraulic fracturing revolution than access to fresh water, yet this dependency use has raised environmental concerns and operational challenges.

Water droplets eddy effect
Source: Getty Images.

Few things are more essential to the now global hydraulic fracturing revolution than access to fresh water, yet this dependency use has raised environmental concerns and operational challenges. In response, oil and gas companies are increasingly turning to produced water and flowback fluids to improve sustainability.

The subject has remained central at industry gatherings such as the recent SPE Hydraulic Fracturing Technology Conference (HFTC) held in the Houston area.

At this year’s event, researchers from the Energy and Environmental Research Center (EERC) at the University of North Dakota presented findings that highlight both progress and limitations in water reuse.

Their study found that 40% of operators in North Dakota incorporate produced water into their completions programs to some extent, with 20% using what EERC considers “significant volumes.”

However, the final analysis—detailed in paper SPE 223512—revealed that only about 5% of the total water used in Williston Basin completions comes from recycled sources, with the rest sourced from fresh supplies. By comparison, the Permian Basin was found to boast a reuse rate exceeding 50%.

The EERC analysis also shows that an estimated 850,000 BWPD is pumped into the subsurface in North Dakota while more than 2 million BWPD flows right back out. Almost all the state’s produced water is sent down a saltwater disposal well, with 10% used for enhanced oil recovery and just 5% reused or trucked out of state for disposal elsewhere.

Researchers noted that while reuse is gaining traction in North Dakota, operators could step it up and reduce saltwater disposal injections by as much as 25%. They do face hurdles, however, including the high salinity of produced water which causes unwanted chemical reactions, and the lack of dedicated water pipelines means costs are higher.

The push for greater reuse extends beyond the US.

Argentina’s national oil company, YPF, is also advancing water recycling efforts in its Vaca Muerta Shale operations. A major challenge it faces is that only 20–30% of injected water returns to the surface—the rest is absorbed into the rock matrix.

Despite this, YPF described in paper SPE 223566 how it developed a process to blend untreated flowback water with fresh water for completions.

The company found it could incorporate up to 25% recycled water, but that this was dependent on which fracturing fluid system it was testing. The company found that fresh water-based friction reducers held up but that the produced water led to pressure variations while pumping, likely due to the fluid system’s sensitivity to anything other than fresh water being introduced.

What worked best was a high-salinity polymer that was more predictable and consistent. More than that, the new friction reducer decreased YPF’s dependency on polymers which had the added benefit of reducing the dreaded “gummy bear” effect which is believed to clog up fractures and lead to conductivity loss.

Another paper highlighted a niche but growing challenge faced by some US shale producers. SPE 223549, authored by researchers at NexTier Oilfield Solutions, examines the unintended consequences of using wet sand cleaned with recycled produced water in completions.

The study found that washed but undried sand—highly sought after as a low-cost proppant—tends to retain higher-than-desired levels of clay, feldspar, and calcite. When mixed with friction reducers, these minerals can flocculate, or clump together, almost always impacting fluid performance and believed to harm well productivity.

The salinity of the fluid also affects how these fine particles behave. As salinity increases from 4,500 to 115,000 ppm, a chemical called P-CAT makes the fine particles stick more to the proppant surfaces. Meanwhile, the fluid’s pH will shift how the particles clump together—higher pH levels favor P-CAT, while lower pH levels work better with a different chemical, P-AN1.

NexTier also concluded that improving sand cleaning would further reduce fine particle levels, which is the root cause of the issue to begin with. To test the idea, the company partnered with a Texas sand mine operator to upgrade the cleaning process.

The first adjustment involved reducing recycled water use from 100 to 50% in the washing stage. Next, the number of cyclones used for fines separation was doubled from one to two.

The results showed an increase in quartz levels and a reduction in migrating clay from 3.5 to 1.3% among the samples. This led to a 90% reduction in turbidity, improving overall sand quality and completions efficiency.

These papers underscore that water reuse in hydraulic fracturing is a complex challenge—one that’s easier said than done. However, they also demonstrate that the effort can yield significant benefits, reinforcing the need for continued investment in research to drive higher reuse rates.

For Further Reading

SPE 223549 Avoiding Fatal Attractions: How To Prevent Production-Killing Interactions Between Wet Sand and Stimulation Fluids by S. Kakadjian, J. Kitchen, and A. Gebrekirstos, NexTier Oilfield Solutions.

SPE 223512 Recent Developments and Utilization of Produced Water in Bakken Well Stimulations by D.D. Schmidt, Energy and Environmental Research Center, University of North Dakota; G. Harms and A. Thiel, North Dakota Department of Mineral Resources; J. Neubeker, Arolytics; and T. Hopfauf, ND Energy Services.

SPE 223566 Vaca Muerta: A Technical Approach to the Path of Sustainability in Water Reuse by R.D. Velo, YPF S.A.; M.L. Arias and M.I. Weimann, YPF Tecnología S.A.; and N. Mottes and S.M. Pérez, YPF S.A.