产生结果

油井维护和增产是当今形势下的关键考虑因素。

J. Greg Darby,Rockwater 能源解决方案

该油田的数千口国内油井未达到预期生产潜力。有效的油井维护计划对于提供工程、测试、应用和监控经验至关重要,以解决阻碍油井盈利的无数生产问题。服务公司的科学家、工程师和生产工程师之间需要进行有效的沟通,以识别表现不佳的油井和工程解决方案,并监控处理以验证作业后的处理结果。目标是以可靠和可持续的方式最大限度地提高产量并最大限度地降低总运营成本。

背景
产量低于预期且成本高于预期的原因有多种。这些原因可能包括造成堵塞的残留钻井液或完井液,以及限制流动路径的有机物或矿物沉积物。在规划油井维护作业时,了解要解决的问题非常重要。

表现不佳的油井可能会出现低于预期的石油或天然气产量、机械问题或高含水率。下降曲线比正常下降幅度低 10% 以上可能表明存在问题。运营经理或工程师通常是确定潜在油井问题根本原因的最佳数据来源。生产工程师将拥有详细的数据,例如油井测试、每日生产图和井眼图。井的历史应详细,包括修井和生产历史;对刺激治疗反应良好;产生的流体特性和成分;产出液与增产处理的相互作用;和水库条件。

罗克沃特对井液的审查可以帮助确定井产量下降的原因。应进行油、水和气体分析。油液分析可以确定石蜡、沥青质或乳液是否阻塞了导电路径。对水进行检查可以根据流体化学、温度和压力确定矿物质结垢的可能性。操作员还可以提供历史记录,或许还可以提供过去修复工作(例如修井、擦拭作业或杆和油管拉拔)中的固体和沉积物样本。

油井修复技术方法建立在生产化学进步和专业知识的悠久历史之上。可以设计处理措施来针对生产抢劫流保证问题或提供处理措施以维持资产完整性。

酸化
井酸化是一种增产技术,旨在去除矿物垢和/或去除近井眼皮肤损伤。使用多种酸,包括盐酸、氢氟酸、乙酸和甲酸。可以根据要去除的沉积物类型和井下温度来选择酸。

在许多增产作业中,目标通常是由于矿物垢或地层细粉而导致的近井眼孔隙堵塞。对于沉积物去除和油井增产,15% 的盐酸是常用的酸。通常使用该量,因为它提供了显着的酸强度,同时最大限度地减少了将废酸和溶解的固体流回井外所需的压力。当废酸被溶解的物质饱和时,其粘度会增加。

罗克沃特能源公司

用盐酸溶解的矿物垢包括碳酸钙、硫化铁和其他铁垢,例如碳酸铁和氢氧化铁。盐酸对于石盐堵塞和硫酸钡无效。盐酸对于硫酸钙水垢的效果有限。水是石盐沉积物的有效溶剂。

钡垢和硫酸钙垢特别难以去除,但可以用适当的阻垢剂进行处理以防止沉积。机械去除(例如铣削或钻出水垢)可能是去除阻止化学处理接触固体的管道堵塞的唯一途径。严重的结垢沉积通常需要更换设备。在处理硫酸盐垢时,使用化学阻垢剂进行预防通常是最具成本效益的补救措施。

有机物去除
经验表明,生产井近井筒处的有机沉积物通常是主要的损害机制。有机沉积物的例子是石蜡和沥青质。这些沉积物会产生稳定乳液的第二个问题。有些产品旨在清除近井眼区域的有机沉积物。该产品系列由在溶剂中配制的表面活性剂混合物组成。这些产品将去除有机沉积物并溶解和分散沥青质。它们还含有破乳剂,可以分解稳定的近井眼乳液,而不会对地面设施中的原油脱水产生不利影响。

案例历史
俄克拉荷马州加拿大县伍德福德地层新钻探的井遇到了严重的硫化铁油管沉积问题。未经处理的油井如果发生管道堵塞,每隔几周就需要进行机械和化学干预。最初,将四羟甲基硫酸磷(THPS)(一种硫化铁螯合剂)注入环隙中来控制硫化铁。THPS 的腐蚀性使其无法作为长期解决方案使用。生产商寻求一种非酸性硫化铁控制溶液。

在固体样品上测试了化学添加剂。实验室测试表明,分散和抗聚集硫化铁以防止沉积,而不是溶解它,是一种可行的选择。制备了易于获得的表面活性剂的混合物。对混合物进行了稳定性测试,以确保其适合 76.6 C (170 F) 的井底温度。除了进行稳定性测试外,还进行了腐蚀测试,以确保混合物不会腐蚀井底管材。在使用 76.6°C 的合成现场盐水进行的喷射烧杯腐蚀测试中,硫化铁混合物的腐蚀速率与空白相比降低了 98%。

罗克韦尔能源公司

新混合物的测试数据符合客户规格,并获准进行现场试验。非酸性硫化铁分散剂的现场广泛使用证明它能够成功地保持生产管内没有硫化铁沉积物。使用新产品后,铁和锰的读数降低,咸水处理地点的总可溶性固体含量得到改善。新型硫化铁控制产品的广泛应用证明,它是一种有效的硫化铁控制非酸性溶液。

结论
在开发油井维护或增产项目时应考虑经济性,以便处理计划的成本不超过石油和天然气的市场价格。如果需要修井,总处理成本的预期盈亏平衡点将包括关井时间、租赁设备成本、化学品成本和回收处理液所需的时间。如果需要大量驱替液来驱替油管和套管,则在回收该流体并重新恢复碳氢化合物生产之前可能需要相当长的时间。

有效的油井维护计划需要正确理解油井问题。在适当的时间进行有效的设计和应用可以减少现场费用并缩短井故障间隔时间。运营商依靠其生产化学合作伙伴部署有效的维护和增产计划,以改善油田经济效益并提高资产估值。

原文链接/hartenergy

Producing Results

Well maintenance and stimulation are key considerations in today’s landscape.

J. Greg Darby, Rockwater Energy Solutions

Thousands of domestic wells in the field underperform their projected production potential. An effective well maintenance program is essential to provide the engineering, testing, application and monitoring experience to remedy the myriad production problems that hinder well profitability. Effective communication between service company scientists and engineers and production engineers is required to identify underperforming wells and engineered solutions as well as to monitor treatments to verify treatment results post job. The objective is to maximize production and minimize the total cost of operations in a reliable and sustainable manner.

Background
Lower than expected production and higher than expected costs can occur for a variety of reasons. These reasons can range from residual drilling or completion fluid that creates a blockage to organic or mineral deposits that restrict flow paths. It is important that one understands the problem to be addressed when planning well maintenance operations.

An underperforming well may demonstrate lower than expected oil or gas production, mechanical problems or high water cut. A decline curve of more than 10% below the normal decline may indicate a problem. The operations manager or engineer is usually the best source for data to determine the root cause of a potential well problem. The production engineer will have detailed data such as well tests, daily production plots and a wellbore diagram. The history of the well should be detailed, including well workover and production history; well response to stimulation treatments; produced fluid properties and composition; interaction of produced fluids with stimulation treatments; and reservoir conditions.

RockwaterA review of well fluids can help determine reasons for a well production decline. Oil, water and gas analysis should be performed. The oil analysis may determine if paraffin, asphaltenes or emulsion are blocking conductive paths. A review of the water could determine the potential for mineral scaling based on fluid chemistry, temperature and pressure. The operator also can provide a history and perhaps samples of solids and deposits from past remediation work such as workovers, swabbing jobs, or rod and tubing pulls.

Well remediation technology methods build upon a long history of production chemistry advances and expertise. Treatments can be designed to target production robbing flow assurance issues or provide treatments to maintain asset integrity.

Acidizing
Well acidizing is a stimulation technique designed to remove mineral scales and/or remove nearwellbore skin damage. A variety of acids are used including hydrochloric acid, hydrofluoric acid, acetic acid and formic acid. Acid selection can be made based on the type of deposit to be removed and downhole temperature.

In many stimulation jobs, the target is typically near-wellbore pore plugging due to mineral scale or formation fines. For both deposit removal and well stimulation, 15% hydrochloric acid is a common acid used. That amount is typically used because it provides significant acid strength while minimizing the pressure needed to flow the spent acid and dissolved solids back out of the well. Spent acid will increase in viscosity as it becomes saturated with dissolved material.

Rockwater Energy

Mineral scales dissolved with hydrochloric acid include calcium carbonate, iron sulfide and other iron scales such as iron carbonate and iron hydroxide. Hydrochloric acid is not effective against halite blockages and barium sulfate. Hydrochloric acid is only marginally effective against calcium sulfate scales. Water is an effective solvent for halite deposits.

Barium scales and calcium sulfate scales are particularly difficult to remove but can be treated with the appropriate scale inhibitor to prevent deposition. Mechanical removal such as milling or drilling out the scale may be the only recourse for removing tubing blockages that prevent a chemical treatment from contacting the solid. Often equipment replacement is required for severe scaling deposition. Prevention with a chemical scale inhibitor is often the most cost-effective remedy when dealing with sulfate scales.

Organics removal
Experience shows that there is often a dominant damage mechanism by organic deposits in the near-wellbore of producing wells. Examples of organic deposits are paraffin and asphaltenes. These deposits can create a secondary problem of stabilized emulsions. There are products designed to remove organic deposits from the near-wellbore area. This product range consists of blends of surface-active agents formulated in a solvent. These products will remove organic deposits and dissolve and disperse asphaltenes. They also contain demulsifiers that will resolve stabilized, near-wellbore emulsions without adversely impacting crude dehydration in surface facilities.

Case history
Newly drilled wells in Canadian County, Okla., in the Woodford Formation experienced a severe iron sulfide tubing deposition problem. Untreated wells that experienced tubing plugging would require mechanical and chemical intervention every few weeks. Initially, injection of tetrakis hydroxymethyl phosphonium sulfate (THPS), an iron sulfide chelator, into the annulus was used to control the iron sulfide. The corrosive nature of THPS prevented its use as a long-term solution. The producer sought a nonacid iron sulfide control solution.

Chemical additives were tested on samples of the solids. Laboratory testing indicated dispersing and antiagglomeration of the iron sulfide to prevent deposition, rather than dissolving it, was a viable option. A blend of readily available surfactants was prepared. Stability tests were run on the blend to make sure it was suitable for the 76.6 C (170 F) bottomhole temperature. In addition to the stability tests run, corrosion tests were run to ensure the blend would not corrode bottomhole tubulars. The iron sulfide blend exhibited 98% reduction in the corrosion rate versus a blank in sparged beaker corrosion tests using a synthetic field brine at 76.6 C.

Rockwell Energy

The test data on the new blend met customer specs and were approved for a field trial. Fieldwide use of the nonacid iron sulfide dispersant proved it was successful at keeping the production tubing free of iron sulfide deposits. Iron and manganese readings were reduced and total dissolvable solids at saltwater disposal locations improved with the use of the new product. Fieldwide application of the new iron sulfide control product proved it was an effective nonacid solution for the control of iron sulfide.

Conclusion
Economics should be considered when developing a well maintenance or stimulation project so the cost of a treatment program does not exceed the market price of oil and gas. If well intervention is required, the expected breakeven point on the total cost of treatment would include shut-in time, rental equipment costs, chemical costs and time required to recover the treatment fluid. If large volumes of displacement fluid are required to displace the tubing and casing, there may be a significant time period before this fluid is recovered and hydrocarbon production is reestablished.

A proper understanding of well problems is required for an effective well maintenance program. Effective design and application at the proper time can reduce field expenses and lower the time between well failures. Operators depend on their production chemistry partners to deploy an effective maintenance and stimulation program to improve field economics and improve asset valuation.