2023 年 4 月

生产中有什么新变化

长途送货
伦纳德·卡尔法扬/特约编辑

本专栏中反复出现的主题是油井增产,因为它是提高石油和天然气产量的一个重要方面。另一个反复出现的主题是“旧”或较旧的技术可能会被遗忘或过时,但也可能再次成为“新”。  

油井增产应用的一个普遍领域是将增产技术输送到地层深处,从而可以提高新井以及现有井的产量,使其超出初始完井或补救增产处理的可能水平。水力压裂(包括非常规地层和页岩地层)以及碳酸盐岩地层完井增产中尤其存在机会。  

水力压裂当然,在适用的情况下,新井中的水力压裂和老井中的重复压裂本身是“长距离”、深入储层的增产方法。但是,是否可以通过压裂额外提供增产添加剂来改善油井生产响应呢?有两种通用方法旨在实现此目的。  

一种是使用支撑剂添加剂,例如添加到总支撑剂负载中的轻质支撑剂,旨在延长有效支撑裂缝长度,从而提高裂缝导流能力。两个例子是 Sun Specialty Products 的 SUN OMNIPROP®CARBO 的 CARBOAIR。SUN OMNIPROP 是一种先进的热固性纳米复合材料珠,具有接近中性浮力、高强度和高温稳定性。CARBOAIR 是一种高输运、超低密度陶瓷支撑剂,专为滑溜水(低摩擦减速液)压裂而开发。增强添加剂的其他例子是那些控制支撑剂回流的添加剂,例如纤维或可延展且形状奇特的固体材料,它们可以将支撑剂“包裹”在裂缝内,随着时间的推移保持更大的传导性。  

另一种具有优点但似乎兴趣已减弱的通用方法是使用支撑剂输送的增产化学品2000 年代初,前 BJ Services(现为 Baker Hughes)开发了 Sorb TM系列产品。这些产品采用支撑剂尺寸、高孔隙度硅藻土作为基质,并注入抑制剂化学物质(例如水垢、盐、石蜡或沥青质)而开发。吸附剂以低百分比添加到支撑剂阶段,以便将其输送到支撑裂缝延伸的深度,然后在生产过程中缓慢释放抑制剂,从而对不需要的沉积提供早期和长期控制。CARBO 还销售其 GUARD 系列产品,这些产品是工程陶瓷支撑剂,同样注入了化学抑制剂,例如用于盐或结垢控制。  

Hallux Talon 的 XLGUARD 是这类支撑剂化学处理的新成员。XLGUARD 利用相同的工程多孔陶瓷支撑剂在整个支撑剂填充裂缝中 提供专有的、缓慢释放的聚合物特异性酶,以加速基于凝胶的压裂液清理并提高产量。 

也许利用产生低浓度酸的酶将是对含碳酸盐非常规地层进行额外深度刺激的创造性选择。此外,结合多种支撑剂输送化学物质应该是一个更大的考虑因素,这可能是实现更高产井和甚至更小的裂缝设计的一种选择。  

碳酸盐刺激在碳酸盐岩地层中完成的井的标准增产是通过传统的支撑 水力压裂、无支撑剂的酸压裂或基质酸化。在酸压裂中,高强度酸、盐酸 (HCl) 或 HCl-有机酸混合物以高于压裂压力的高速率泵送。酸通常以一种或另一种方式稠化以减缓反应并控制注入过程中渗漏到基质地层中,从而扩展和延伸所产生的裂缝。酸蚀刻所产生的裂缝的壁,因此当裂缝闭合时,沿裂缝壁产生的粗糙体支撑连接到井眼的高传导性裂缝通道。  

通过碳酸盐的基质酸化,酸(通常也通过化学方式稠化或缓凝)被简单地泵入到破裂压力以下,从而在地层中形成几英尺或更多英尺的分支虫洞状通道。  

碳酸盐岩地层中的增产方法具有相同的目标——在尽可能深的地层中形成无限导电的小直径通道。但是建造大直径隧道又如何呢?恰好有一种现有技术可以做到这一点,并且有成功的历史——cid隧道技术,该技术于本世纪初开发出来,并在拉丁美洲流行起来,最初在委内瑞拉取得了成功,然后在东南亚和中东取得了成功,碳酸盐岩地层中大规模裸眼完井现象十分普遍。它是由前 BJ Services 开发的,作为他们的 StimTunnel 技术,该技术仍然可以通过 Baker Hughes 获得,但现在有些被遗忘了。  

酸隧道掘进是一种有效地将盐酸注入裸眼碳酸盐岩地层的方法,并形成从几英尺到 60 英尺或更长的隧道。用这种方法建造的最长隧道已超过 120 英尺。该技术利用一种由连续油管输送的特殊工具来启动进入,然后延伸到地层中,同时在高压下喷射高活性酸以溶解岩石实际上,“钻”出了一条巨大的、敞开的隧道。  

在操作过程中,酸也会泄漏到岩石基质中,形成次要通道或“牧场”,流入所创建的隧道中。工具串中还可以包含记忆测斜仪,以跟踪隧道轨迹和方向。创建一条隧道后,可以将连续油管和工具拉出,并在不同位置多次重新进入以创建其他隧道。酸性隧道掘进是一种清洁过程,因为水、溶解的氯化钙盐和二氧化碳是碳酸盐岩中酸性反应的唯一副产品。也不需要占用空间大的地面设备。所需要的只是连续油管装置、酸罐和酸泵装置。  

这些用于增强油井增产和生产的“长距离”输送方法并不普遍适用,但它们的适用范围超出了它们的考虑范围。在非常规井的多区压裂完井中,井清理或长期抑制结垢或盐沉积的微小改进对于提高生产率而言可能是显着的,特别是在井寿命的早期。在碳酸盐岩裸眼完井中,不应忘记酸性隧道掘进,这是一种已经行之有效的增产方法。 

关于作者
伦纳德·卡尔法延
特约编辑
Leonard Kalfayan 拥有 42 年的石油、天然气和地热经验。他曾在 Hess、BJ Services、Unocal 工作并担任顾问。他是 SPE 杰出讲师和杰出会员。他撰写了大量出版物,还拥有 13 项美国专利。
相关文章
原文链接/worldoil
April 2023
Columns

What's new in production

Long distance delivery
Leonard Kalfayan / Contributing Editor

A recurring theme in this column is well stimulation, as it is such a crucial aspect of oil and gas production enhancement. Another recurring theme is that “old” or older technology can become forgotten, or passe, but can also become “new” again.  

One such general area of well stimulation application is the delivery of stimulation technologies to distances deep in the formation, whereby production from new wells as well as existing wells can be enhanced beyond that possible with an initial completion or with a remedial stimulation treatment. There are opportunities that especially exist in hydraulic fracturing, including in unconventional and shale formations, and in stimulation of wells completed in carbonate formations.  

Hydraulic fracturing. Of course, hydraulic fracturing in new wells and refracturing in older wells, where applicable, are “long distance,” deep into the reservoir, stimulation methods themselves. But what about additionally delivering production enhancement additives via fracturing to improve well production response? There are two general methods that are designed to do so.  

One is with proppant additives, such as lightweight proppants added to the overall proppant loading that are designed to extend effective propped fracture length and thereby increase fracture conductivity. Two examples are SUN OMNIPROP ®, from Sun Specialty Products, and CARBOAIR, from CARBO. SUN OMNIPROP is an advanced thermoset nanocomposite bead with near-neutral buoyancy, high strength, and high temperature stability. CARBOAIR is a high-transport, ultra-low-density ceramic proppant developed for slickwater (low-friction reducer fluid) fracturing. Other examples of enhancement additives are those that control proppant flowback, such as fiber or malleable and oddly shaped solid materials that can keep proppant “trapped” within the fracture, maintaining greater conductivity over time.  

The other general method that has merit, but which has seemingly diminished in interest, is the use of proppant-conveyed production enhancement chemistries. In the early 2000s, the former BJ Services (now Baker Hughes), developed their SorbTM line of products. These were developed with proppant-size, highly porous, diatomaceous earth as a substrate infused with inhibitor chemistries, such as for scale, salt, paraffin or asphaltenes. Sorbs are added to proppant stages in low percentages, so that they are delivered just as deep as the propped fracture extends, and then slowly release inhibitor during production, providing early time and longer-term control of unwanted depositions. CARBO also markets their GUARD line of products, which are engineered ceramic proppants similarly infused with chemical inhibitors, such as for salt or scale control.  

A newer addition to this category of proppant-delivered chemical treatments is XLGUARD from Hallux Talon. XLGUARD utilizes the same engineered, porous ceramic proppant, to deliver proprietary, slow-release, polymer-specific enzymes throughout the full proppant packed fracture to accelerate gel-based frac fluid cleanup and enhance production.  

Perhaps utilizing enzymes that generate acid in low concentration would be a creative option for additional, deep stimulation of carbonate-containing, unconventional formations. Also, combining multiple proppant-delivered chemistries should be a greater consideration, which could be an option to enable more productive wells and possibly even smaller fracture designs.  

Carbonate stimulation. Standard stimulation of wells completed in carbonate formations is either by conventional, propped hydraulic fracturing, acid fracturing without proppant, or matrix acidizing. With acid fracturing, high-strength acid, hydrochloric (HCl) or HCl–organic acid blends are pumped at high rates above fracturing pressure. The acid is typically viscosified one way or another, to slow reaction and control leakoff into the matrix formation during injection, thereby propagating and extending the created fracture. Acid etches the walls of the created fracture, so that when the fracture closes, asperities generated along the fracture wall support a highly conductive fracture channel connected to the wellbore.  

With matrix acidizing of carbonates, acid, also often viscosified or retarded chemically, is simply pumped below fracturing pressure, creating branched wormhole-like channels into the formation several or more feet.  

Stimulation methods in carbonate formations have the same objective – creating infinitely conductive, small-diameter channels as deep into the formation as practically possible. But what about creating large-diameter tunnels? There happens to be an existing technology that does just that and has a history of success—acid tunneling—which was developed earlier this century and gained popularity in Latin America, initially with successes in Venezuela, then in southeast Asia and the Middle East, where massive open-hole completions in carbonate formations are prevalent. It was developed by the former BJ Services, as their StimTunnel technology, which is still available through Baker Hughes, but now somewhat forgotten.  

Acid tunneling is a method for effectively targeting placement of HCl acid into open-hole carbonate formations, and creating tunnels that can vary from a few feet to perhaps 60 ft or more. The longest tunnels created with this method have been over 120 ft. The technology utilizes a special tool, conveyed by coiled tubing, to initiate entry and then extension into the formation, all the while jetting the highly reactive acid at high pressure to dissolve away rock and, in effect, “drill” a large, wide-open tunnel.  

Acid also leaks off into the rock matrix during the operation, creating secondary channels or “branches” that feed into the created tunnel. A memory inclinometer gauge also can be included in the tool string to track tunnel trajectory and orientation. After one tunnel is created, the coiled tubing and tool can be pulled out, and re-entered multiple times at different locations to create additional tunnels. Acid tunneling is a clean process, since water, dissolved calcium chloride salt, and carbon dioxide are the only byproducts of the acid reaction in carbonate rock. There is no need for large footprint surface equipment, either. A coiled tubing unit, acid tanks, and acid pumping unit are all that are needed.  

These “long distance” delivery methods for enhancing well stimulation and production are not universally applicable, but they are applicable for more than they are given consideration. In multi-zone fracture completions in unconventional wells, minor improvements in well clean-up or extended inhibition of scale or salt deposition can be significant with respect to production rate enhancement, especially early in well life. And in open-hole carbonate completions, acid tunneling should not be forgotten, as an already proven stimulation method. 

About the Authors
Leonard Kalfayan
Contributing Editor
Leonard Kalfayan has 42 years of oil, gas and geothermal experience. He has worked for Hess, BJ Services, Unocal, and as a consultant. He is an SPE Distinguished Lecturer and Distinguished Member. He has authored numerous publications, and also holds 13 U.S. patents.
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