增强恢复

2024 年 SPE 提高石油采收率的先驱

该荣誉旨在表彰获奖者在 IOR 领域做出的持久而重大的贡献。

从左至右依次为 IOR 先驱 Stephane Jouenne、Baojun Bai、Mojdeh Delshad 和 Varadarajan Dwarakanath,以及奖励委员会主席 Randy Seright。
从左至右依次为 IOR 先驱 Stephane Jouenne、Baojun Bai、Mojdeh Delshad 和 Varadarajan Dwarakanath,以及奖励委员会主席 Randy Seright。
来源:穆罕默德·阿卜杜拉(Mohammad Abdullah),德克萨斯大学奥斯汀分校石油与地球系统工程系希尔德布兰德(Hildebrand)。

油藏具有许多复杂性和神秘性。四位采油专家帮助揭开了其中的一些谜团,攻克了油藏,提高了产量。

从开发在裂缝导致严重通道时改善一致性的预成型颗粒凝胶,到模拟油藏中的提高采收率 (EOR) 过程,到确定水稳定性概念,到展示聚合物溶液在不降解的情况下可以行进的距离,2024 年提高采收率 (IOR) 先锋奖的四位获奖者做出了“持续而重要的提高采收率的贡献”,新墨西哥理工学院 2024 年先锋奖评选委员会主席、2008 年获奖者 Randy Seright 告诉JPT

Seright、另外四位此前获得该奖项的获奖者以及 2024 年 SPE IOR 大会总主席 Tom McCoy 对 16 位终身成就奖候选人进行了评估,并选出了四位在其职业生涯中“为 IOR 做出了最持久和最重大的贡献”的人,Seright 说道。“这就是为什么我们在 IOR 方面取得如今的成就的原因。”

今年 4 月,在塔尔萨举行的两年一度的 IOR 会议上,获得表彰的 2024 年 IOR 先锋奖获得者包括密苏里州罗拉密苏里科技大学 (Missouri S&T) Lester Birbeck 捐赠讲席教授白宝军 (Baojun Bai);德克萨斯大学奥斯汀分校 (UT-Austin) 希尔德布兰德石油与地球系统工程系研究教授 Mojdeh Delshad;休斯顿雪佛龙技术中心化学 EOR 团队负责人 Varadarajan Dwarakanath;以及曾领导道达尔能源公司团队致力于聚合物驱地面和地下研究课题、现任道达尔能源公司二氧化碳捕获项目协调员的 Stephane Jouenne

“这是印度洋研究学会颁发的最负盛名的奖项,”塞赖特说道。

白宝俊

预成型颗粒凝胶

Seright 表示,白先生在 IOR 领域的主要贡献是开发了预制颗粒凝胶,这种凝胶可用于在压裂液流向错误位置时堵塞压裂孔,而不是使用化学反应性凝胶,因为化学反应性凝胶由于与储层流体接触敏感而可能无法正确凝固。

“通过预先形成凝胶,你就能解决这个问题,”他说道,并指出这些凝胶还可以堵塞更宽的裂缝。

白先生告诉JPT,他在中国石油的研究小组于 1996 年开始研究预成型颗粒凝胶技术,并于 1999 年在中国成功进行了现场试验,之后开始“将该技术推广到所有油田”。该技术现已在数千口油井中使用。

他还扩展了预制颗粒凝胶技术,使其能够在高温、高盐度条件、二氧化碳和封存条件下发挥作用。

白先生拥有美国新墨西哥矿业技术学院石油工程博士学位、中国地质大学石油地质学博士学位、北京石油勘探开发研究院研究生院石油工程硕士学位以及中国黑龙江大庆石油学院油藏工程学士学位。

白先生说,他在中石油的顾问帮助他形成了对 IOR 的兴趣。在密苏里科技大学任职期间,他正在培养下一代 IOR 专家

他说:“石油和天然气是一个非常复杂的领域,你需要大量的知识”,因为这个行业比简单地钻一个洞和生产石油要复杂得多。”

“这实际上比许多其他领域更复杂。这背后有大量的科学和理解,”他说。“这是一个你可以深入的、非常非常棒的领域。”

他说,其中一个原因是,传统的石油和天然气开采方法会将大部分原始碳氢化合物留在原地。这使得 IOR 和 EOR 等学科成为热门话题,尤其是随着开发出新的经济高效的技术以从现有油藏中开采更多石油。

他说道:“如果我们拥有足够的知识,我们就可以使用 EOR 技术来生产它。”

莫杰德·德尔沙德

EOR 模拟

塞赖特说,德尔沙德是一位化学驱油专家,她职业生涯的大部分时间都致力于帮助业界理解和正确模拟各种 EOR 化学品和过程在油藏中的行为。

Delshad 拥有伊朗德黑兰沙里夫大学化学工程学士学位以及德克萨斯大学奥斯汀分校石油工程硕士和博士学位。

在寻找硕士导师的过程中,她找到了 Gary Pope,当时他是德克萨斯大学奥斯汀分校的新教授,并于 2006 年获得 IOR 先锋奖。他向她介绍了表面活性剂和 EOR。

她说:“我根本不知道他在说什么。”

她阅读了有关表面活性剂、聚合物和 EOR 的资料,觉得很有趣,于是决定与他一起工作。Delshad 开展了油水微乳液三相相对渗透率的研究工作。1986 年毕业时,油价“可观”,因此她选择在德克萨斯大学奥斯汀分校从事博士后工作。她没有从事实验室工作,而是专注于模拟和建模,并使用 UTCHEM 模拟器。

她说:“它成为了行业化学驱油模型的黄金标准。”

她表示,成本和采收率对于 EOR 项目来说很重要,但简单对于成功也很重要。

“不要让事情变得太复杂,”她说。 “这已经是一个复杂的过程了。”

如今,她回到田纳西大学担任研究教授,她提醒学生们牢记这一理念。“你需要帮助(操作员)能够快速、简单地面对挑战并找到解决方案,而无需太多模拟知识,”她说。

Delshad 还相信 IOR 和 EOR 人才大有可为,并向世界各地的工程师教授 EOR 基础知识。

“这些技术还有未来吗?当然有,但它们可能不会像过去那样被使用,”她说,“你学到的所有知识都可以应用到其他地方。”

德尔沙德目前正致力于氢气和 CCUS 存储的研究。“她发现对复杂过程进行建模和模拟非常有趣,”她说道,并补充说她目前所从事的工作“比将二氧化碳注入油藏开采石油复杂得多”。

Varadarajan“W” Dwarakanath

水性稳定性

Seright 表示,Dwarakanath 在德克萨斯大学奥斯汀分校读研究生期间开发了水稳定性概念,后来在北海的 Captain 聚合物驱项目和印度尼西亚的 Minas 化学驱项目中发挥了关键作用。

他说,水性稳定性在表面活性剂驱油中非常重要,因为它有助于确保表面活性剂配方能够流过多孔岩石。

Dwarakanath 告诉JPT,他在大学期间,表面活性剂含水层修复项目涉及胶体悬浮液,但当时大多数人并没有意识到“透明比胶体悬浮液更好”。

他说,他在还是一名年轻学生时偶然支持了水稳定性概念,但他对这一概念的普及感到自豪。

Dwarakanath 后来为他设计的水性稳定流体创建了定制的表面活性剂分子结构,这大大降低了表面活性剂的滞留率,从而提高了化学 EOR 性能。这一概念在雪佛龙运营的印度尼西亚米纳斯油田的碱-表面活性剂-聚合物试验中得到了验证。他说,注入水性稳定流体使石油产量从 40 桶/天增加到 1,250 多桶/天,累计采收率提高了 22%。

他还是海上 Captain 聚合物驱项目的负责人,该项目涉及创新的 IOR 工作,例如将液态聚合物从乳液变为分散体。这一改进使化学活性激增 50%,含水量低于 5%,堵塞趋势减少,并且由于浓缩配方的增强而降低了物流成本。

Dwarakanath 拥有印度贝拿勒斯印度大学采矿工程学士学位以及德克萨斯大学奥斯汀分校石油工程硕士和博士学位。

虽然他在大学早期的工作重点是钻井,但他说他发现 IOR 更令人兴奋。“我希望看到比钻井工作更长远的东西,”他说。“钻井一完成,油井就完工了,所以 IOR 更有意义。”

他说,这个油藏就像一本侦探小说,如果作业者足够幸运,他们就能拥有一段漫长的生产历史。“这是你能读到的最好的侦探小说”,他指出自己已经在 IOR 工作了大约 30 年。“这是我扮演油藏界的福尔摩斯先生的方式。”

1996 年,Varadarajan Dwarakanath 在犹他州希尔空军基地进行三氯乙烯含水层修复工作。
1996 年,Varadarajan Dwarakanath 在犹他州希尔空军基地进行三氯乙烯含水层修复工作。
来源:Varadarajan Dwarakanath。

史蒂芬·朱安

映射 HPAM 传输

Jouenne 完成了“令人难以置信的实验室工作,解答了许多疑问”,Seright 说道。“他是第一个公开展示何时何地可以运输水解聚丙烯酰胺 (HPAM) 溶液的人。”

Jouenne 在推动实施 TotalEnergies 的 Dalia 和 Camelia 聚合物驱项目(安哥拉近海)方面发挥了关键作用。他告诉JPT ,在准备 Dalia 聚合物试点项目时,他最初负责整个聚合物链的质量控制。

“这很有教育意义,因为你必须详细了解聚合物溶解过程和注入设施,”他说。“很快,一系列有关这种回收方法效率的问题就出现了。”

他说,这些问题包括:注入过程的可靠性;地面和油藏的氧化和热降解;管道、节流阀和注入井的机械降解;注入性;采油效率;聚合物对油水分离的影响;等等。这些问题是他未来工作的基础,包括开发 EOR 聚合物的流动和粘性行为模型。

“研究聚合物溶液非常有趣,因为这些流体的行为方式令人难以置信。溶液像蜂蜜一样粘稠,像口香糖一样有弹性。试图理解这种“复杂流体”的行为可能要花上好几辈子的时间,”他说。

这种复杂性还与地面设施设计和油藏采油的复杂性相结合。

Jouenne 表示,“开展 EOR 工作就像是在不断加深你的理解,每当你进步的时候,一系列新的世界就会向你敞开。”

由于他参与了从注入设施到油井、到地下和石油生产的整个 EOR 链,他对 EOR 有着独特的见解和知识。

他说道:“各个学科的专家都会找你,因为你是最了解这种奇怪且不寻常液体的人。”

他将自己对聚合物的最初认识归功于法国科学家 Guy Chauveteau,以及 TotalEnergies EOR 专家 Danielle Morel 和 Maurice Bourrel 对他职业生涯的指导。

Jouenne 拥有法国 ENSIC 化学工程学院化学与过程工程硕士学位以及法国巴黎第六大学材料物理化学博士学位。

2012 年聚合物采样活动期间,Stephane Jouenne 与同事 Guillaume Heurteux 在 Dalia FPSO 质量控制实验室。
2012 年聚合物采样活动期间,Stephane Jouenne 与同事 Guillaume Heurteux 在 Dalia FPSO 质量控制实验室。
来源:Stephane Jouenne。

原文链接/JPT
Enhanced recovery

2024 SPE Pioneers of Improved Oil Recovery

The honor recognizes recipients for their lasting and significant contributions in the field of IOR.

From left, IOR Pioneers Stephane Jouenne, Baojun Bai, Mojdeh Delshad, and Varadarajan Dwarakanath, and Awards Committee Chairman Randy Seright.
From left, IOR Pioneers Stephane Jouenne, Baojun Bai, Mojdeh Delshad, and Varadarajan Dwarakanath, and Awards Committee Chairman Randy Seright.
Source: Mohammad Abdullah, Hildebrand Department of Petroleum and Geosystems Engineering, The University of Texas at Austin.

Reservoirs present plenty of complexity and mystery. Four oil recovery experts have helped remove some of those mysteries, taming the complex to boost production.

From developing preformed particle gels that improve conformance when fractures cause severe channeling to simulating enhanced oil recovery (EOR) processes in the reservoir to identifying the aqueous stability concept to demonstrating the distance polymer solutions can travel without degradation, the four 2024 recipients of the 2024 Improved Oil Recovery (IOR) Pioneer Award have made a “sustained and important contribution to increased oil recovery,” Randy Seright, New Mexico Tech, 2024 Pioneer selection committee chairman and 2008 honoree, told JPT.

Seright, four other previous recipients of the recognition, and 2024 SPE IOR Conference General Chairman Tom McCoy evaluated a field of 16 nominees for the lifetime achievement honor and selected four who have throughout their careers “made the most lasting and significant contributions to IOR,” Seright said. “It’s why we are where we are today with respect to IOR.”

The 2024 IOR Pioneer recipients who were honored during the biannual IOR conference in Tulsa in April are Baojun Bai, professor of petroleum engineering, who sits in the Lester Birbeck Endowed Chair at Missouri University of Science and Technology (Missouri S&T) in Rolla, Missouri; Mojdeh Delshad, research professor in the Hildebrand Department of Petroleum and Geosystems Engineering at The University of Texas at Austin (UT-Austin); Varadarajan Dwarakanath, team lead for chemical EOR at the Chevron Technology Center in Houston; and Stephane Jouenne, who previously led a TotalEnergies team dedicated to surface and subsurface research topics for polymer flooding and is currently CO2 capture project coordinator at TotalEnergies.

“It’s the most prestigious award given out in IOR,” Seright said.

Baojun Bai

Preformed Particle Gels

Bai’s major contribution to the field of IOR was developing preformed particle gels that can be used to plug fracs when fracture fluids are channeling to the wrong location instead of using chemical-reactive gels that may not set properly because of their sensitivity to contact with reservoir fluids, Seright said.

“By preforming the gel, you take care of that problem,” he said, noting that these gels also have potential for plugging wider fractures.

Bai told JPT his research group in PetroChina initiated work on the preformed particle gel technology in 1996 and successfully field tested it in 1999 in China before starting to “use this technology for all the fields.” The technology has since been used in thousands of wells.

He has also expanded the preformed particle gel technology to function in high-temperature, high-salinity conditions, CO2 floods, and sequestration efforts.

Bai holds a PhD in petroleum engineering from New Mexico Institute of Mining and Technology, a PhD in petroleum geology from China University of Geoscience in Beijing, a master’s degree in petroleum engineering from the Graduate School of Research Institute of Petroleum Exploration and Development in Beijing, and a bachelor’s degree in reservoir engineering from Daqing Petroleum Institute in Heilongjiang, China.

Bai said his advisors in PetroChina helped frame his interest in IOR. In his role at Missouri S&T, he is now shaping the next generation of IOR specialists

“Oil and gas is a really complex area, and you need a lot of knowledge” because the industry is more complex than simply drilling a hole and producing oil, he said.

“It is actually more complex than many other areas. There’s a lot of science and understanding behind it,” he said. “It’s a really, really fantastic area that you can go into.”

One reason, he said, is that conventional oil and gas recovery methods leave a great portion of the original hydrocarbons in place. This makes disciplines like IOR and EOR a hot topic, especially as new cost-efficient technologies are developed to produce more oil from current reservoirs.

“If we have good knowledge, we can produce it using EOR technology,” he said.

Mojdeh Delshad

EOR Simulations

Seright said Delshad, an expert in chemical flooding, has devoted a major part of her career to helping the industry understand and correctly simulate how various EOR chemicals and processes behave in the reservoir.

Delshad holds a BS degree in chemical engineering from Sharif University in Tehran, Iran, and MS and PhD degrees in petroleum engineering from UT-Austin.

Her search for a supervisor for her master’s led her to Gary Pope, who was then a new professor at UT-Austin and in 2006 became an IOR Pioneer honoree. He introduced her to surfactants and EOR.

“I had no clue what he was talking about,” she said.

She read up on surfactants, polymers, and EOR, found it interesting, and decided to work with him. Delshad carried out research work on three‑phase relative permeability for microemulsion in oil and water. When she graduated in 1986, oil prices were “miserable,” so she opted for postdoctoral work at UT-Austin. Rather than lab work, she focused on simulation and modeling and worked with the UTCHEM Simulator.

“It became the gold standard of chemical flooding modeling for the industry,” she said.

Costs and recovery factor are important for EOR projects, she said, but simple is also important for success.

“Don’t make it too complicated,” she said. “It’s already a complex process.”

Now back with UT as a research professor, she reminds her students of that concept. “You need to help (operators) be able to quickly and simply, without too much knowledge about simulation, face the challenges and find solutions for it,” she said.

Delshad also believes there is a future for IOR and EOR talents and has taught EOR fundamentals to engineers around the world.

“Is there any future for these technologies? Absolutely, there are, but they may not be used in the way they used to be in the past,” she said. “All the knowledge you learned can be applied elsewhere.”

Delshad is now working on hydrogen and CCUS storage. “I find it fascinating, the modeling and simulation of complicated processes,” she said, adding that what she’s working on now is “much more complex than injecting CO2 into reservoirs to produce oil.”

Varadarajan “DW” Dwarakanath

Aqueous Stability

Dwarakanath developed the aqueous stability concept while he was a graduate student at UT‑Austin and later played a key role in the Captain polymerflood project in the North Sea and the Minas chemical flood project in Indonesia, Seright said.

Aqueous stability is important in surfactant flooding because it helps ensure a surfactant formulation will flow through porous rock, he said.

Dwarakanath told JPT that while he was in university, surfactant aquifer remediation projects involved colloidal suspensions but that at the time, most didn’t realize “clear was better than colloidal suspension.”

He backed the aqueous stability concept as a young student by accident, he said, but is proud that the concept took off.

Dwarakanath later created customized surfactant molecular structures for the aqueous stable fluids he designed, which significantly reduced surfactant retention to enhance chemical EOR performance. That concept was validated in an alkali-surfactant-polymer pilot at the Chevron-operated Minas field in Indonesia. Injection of aqueous stable fluids there increased oil production from 40 to more than 1,250 BOPD and cumulative recovery by 22% of original oil in place, he said.

He was also a lead in the offshore Captain polymerflood project, which involved innovative IOR work like altering liquid polymer from an emulsion into a dispersion. This modification led to a 50% surge in chemical activity, a water content of under 5%, reduced plugging tendencies, and lowered logistical costs due to the enhanced concentration formula.

Dwarakanath holds a BS degree in mining engineering from the Banaras Hindu University in India and MS and PhD degrees in petroleum engineering from UT-Austin.

While his early university work focused on drilling, he said he finds IOR to be more exciting. “I wanted to see something more long-term than a drilling effort,” he said. “You’re done with the well as soon as you’re done drilling, so IOR makes more sense.”

The reservoir is akin to a mystery novel, he said, and if an operator is lucky, they get a long history of production. “It’s the best mystery novel you can have,” noting he has been working in IOR for about 3 decades. “It’s my way of being Mr. (Sherlock) Holmes for a reservoir.”

Varadarajan Dwarakanath at the Hill Air Force Base in Utah in 1996 while doing aquifer remediation of trichloroethylene.
Varadarajan Dwarakanath at the Hill Air Force Base in Utah in 1996 while doing aquifer remediation of trichloroethylene.
Source: Varadarajan Dwarakanath.

Stephane Jouenne

Mapping HPAM Transport

Jouenne has done “incredible lab work that’s answered a bunch of questions,” Seright said. “He’s the first to publicly demonstrate when and where you could transport” hydrolyzed polyacrylamide (HPAM) solutions.

Jouenne was key in driving the implementation of TotalEnergies’ Dalia and Camelia polymerflood projects offshore Angola. While preparing for the Dalia polymer pilot, he told JPT, he initially worked on quality control of the entire polymer chain.

“It was very educative because you have to know in detail the polymer dissolution process and the injection facilities,” he said. “Rapidly, a number of questions concerning the efficiency of this recovery method emerged.”

Those included: reliability of the injection process; oxidative and thermal degradation at the surface and in the reservoir; mechanical degradation in pipes, in chokes, and in injection wells; injectivity; oil recovery efficiency; impact of polymer on oil and water separation; and more, he said. These questions were the basis for his future work, which included developing a model for flow and viscous behavior of EOR polymers.

“Working on polymer solutions is fascinating because these fluids behave in an incredible way. Solutions are viscous like honey and elastic like a chewing gum. Trying to understand the behavior of such ‘complex fluid’ can occupy you for several lives,” he said.

That complexity also combines with the complexities of surface facility design and oil recovery in the reservoir.

“Working on EOR is a sequence of new worlds which open to you each time you progress in your comprehension,” Jouenne said.

Because of his involvement along the EOR chain from injection facilities to the well, to subsurface and oil production, he has a unique perspective and knowledge of EOR.

“Experts of each discipline call on you because you are the guy who understands this strange and unusual fluid,” he said.

He credits French scientist Guy Chauveteau for his initial learnings on polymers along with guidance from TotalEnergies EOR experts Danielle Morel and Maurice Bourrel for shaping his career.

Jouenne holds an MS degree in chemical and process engineering from ENSIC Chemical Engineering School in France and a PhD in physical chemistry of materials from Paris VI University in France.

Stephane Jouenne with colleague Guillaume Heurteux in the quality control lab of Dalia FPSO during the polymer-sampling campaign in 2012.
Stephane Jouenne with colleague Guillaume Heurteux in the quality control lab of Dalia FPSO during the polymer-sampling campaign in 2012.
Source: Stephane Jouenne.