油田化学

保护钢铁:研究人员在抗腐蚀方面取得进展

随着操作员对腐蚀威胁筛选过程进行微调并开发出一种跟踪抑制剂有效性的新方法,保护金属基础设施的新策略应运而生。

行业研究人员正在利用先进技术,持续对抗油气基础设施的腐蚀。来源:Ziggy1/Getty Images。
在对抗石油和天然气基础设施腐蚀的持续斗争中,行业研究人员正在采用先进技术。
资料来源:Ziggy1/Getty Images。

在整个行业中,一个无声的敌人正在瞄准石油基础设施:腐蚀。

为了保护重要设备,研究人员一直在努力工作。在雪佛龙技术中心,研究人员开发了一种针对特别棘手的微生物腐蚀 (MIC) 的筛选方法,而西方石油公司的化学品管理团队则开发了一种量化金属损失的方法,用于衡量腐蚀抑制剂 (CI) 化学品的有效性。

两家公司的专家在四月份于加尔维斯顿举行的SPE 国际油田化学会议上详细介绍了他们的方法。

微生物腐蚀威胁着油气作业,但准确识别风险资产历来颇为困难。雪佛龙技术中心的研究人员旨在开发一种更有效的微生物腐蚀威胁筛查方法,以帮助预防腐蚀,减少杀菌剂过度处理,并确保资产保持良好的运行状态。

雪佛龙技术中心生产化学研究科学家戴维·利奇说: “油田里有生命。”

他说,谈到非常规作业中的微生物,有些是可能引发问题的“主要有害因素”,而有些则“始终存在,但不是真正的问题”。

Leach 在SPE 224254 的报告中指出,硫酸盐还原菌 (SRB)、产酸菌 (APB)、产甲烷菌以及生物膜形成菌或黏液等有害因素可能会造成问题。该报告详细介绍了他的团队如何识别水库或设施中潜在的 MIC 威胁,将这些潜在威胁缩小到可控的测试数量,并深入了解如何最好地识别实际的 MIC 相关威胁。

SRB 可促进 H2S生成,生成硫化铁固体并导致腐蚀。APB 可导致钢材表面发生化学腐蚀,而产甲烷菌则可通过电化学机制导致铁点蚀。

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Oilfield chemistry

Protecting Steel: Researchers Advance Fight Against Corrosion

New strategies for protecting metal infrastructure emerge as operators fine-tune a corrosion threat screening process and develop a new method for tracking inhibitor effectiveness.

Industry researchers are turning to advanced technology in the ongoing battle against corrosion in oil and gas infrastructure. 
Source: Ziggy1/Getty Images.
Industry researchers are turning to advanced technology in the ongoing battle against corrosion in oil and gas infrastructure.
Source: Ziggy1/Getty Images.

All around the industry, a silent enemy targets oil infrastructure: corrosion.

In a bid to protect vital equipment, researchers have been hard at work. At Chevron Technical Center, researchers have developed a screening method for particularly problematic microbiologically influenced corrosion (MIC) while Occidental Petroleum’s Chemical Management Team has developed a means to quantify metal loss as a way to measure effectiveness of corrosion inhibitor (CI) chemicals.

Experts from both companies detailed their approaches during the SPE International Conference on Oilfield Chemistry in Galveston in April.

Microbial corrosion threatens oil and gas operations, but properly identifying at-risk assets has traditionally been difficult. Researchers at Chevron Technical Center aimed to develop a method for more effective MIC threat screening—helping prevent corrosion, reduce biocide overtreatment, and keep assets online and in good working order.

“There’s life in the oil field,” David Leach, production chemistry research scientist at Chevron Technical Center, said.

When it comes to microbes in unconventional operations, some are “major bad actors” that can cause problems while others are “always present but not a real problem,” he said.

It’s the bad actors, like sulfate-reducing bacteria (SRB), acid-producing bacteria (APB), methanogens, and biofilm formers or slime, that can cause problems, Leach said while presenting SPE 224254. The paper details the process his team followed to identify potential MIC threats in a reservoir or facilities, narrow those contenders to a manageable number for testing, and gain insight into how to best identify actual MIC-related threat.

SRB can contribute to H2S production, generate iron sulfide solids, and lead to corrosion. APBs can cause chemical corrosion on steel surfaces, while methanogens can cause iron pitting through electrochemical mechanisms.

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