简易按钮,去除 H2S


由《油田技术》编辑助理出版


石油和天然气的勘探和生产(E&P)通常涉及高风险、高投资和技术密集型活动。

如果行业活动不够复杂,出于环境考虑、产品质量和设备保护,勘探与生产公司需要在石油和天然气运输之前去除硫化氢和硫醇等杂质。

勘探与生产 (E&P) 运营商需要一个简单的按钮来简化硫化氢 (H2S )和硫醇的去除步骤。市面上有各种使用液体和固体溶液的处理系统以及服务技术公司可用于去除 H2S硫醇,每种系统都有其固有的优缺点。了解这些技术及其如何满足 E&P 需求至关重要。在考虑所有运营因素时,这些知识至关重要,尤其是那些影响产品上市速度、维护问题和成本、设备功能以及简化操作的因素,同时还要确保环境得到保护并维护安全。

E&P的H 2 S问题

硫化氢(H2S ) 是一种高腐蚀性和毒性气体,会对上游生产造成严重污染。这种污染物可能自然产生,也可能由勘探开发过程中使用的技术产生。由于含硫酸盐矿物的微生物硫酸盐还原 (MSR) 和/或热化学硫酸盐还原 (TSR),储层中可能会自然合成硫化氢。在使用蒸汽辅助重力泄油 (SAGD) 和水力压裂等勘探开发技术(用于油砂和页岩油/气生产)时,可能会处理产生的硫化氢

硫化氢( H2S ) 可出现在所有存在钻井液和相关设备的钻井区域,包括钻台、下部结构、振动筛、泥浆清洁器、泥浆池、泥浆泵房和试井设备。未设计用于缓解硫化氢 (H2S) 的钻井和井控设备可能会影响其结构完整性,从而影响其功能和运行。

上游运营商可以预见H2S

  • 固有地存在于伴生天然气(“天然气”)中。
  • 在卸钻过程中,也称为“井内钻”,当钻杆完成时,底部流体被置换到地面。
  • 如果钻杆从井中拔出得太快,液体就会进入井眼。
  • 在取回岩心或流体样本期间。
  • 在流量测试过程中,监测并记录井流量、压力和水位。

据了解,勘探与生产运营商每年要花费 1500 多万美元的运营成本来去除 H2S 但生产现场使用的一些现有技术效率低下、不经济,在某些情况下还不安全。

H2S脱除技术

有多种再生和非再生的 H2S去除方法可供选择,所有这些方法在捕获和释放 H2S 的方式上各不相同。多年来,清除剂在去除少量 H2S 方面一直发挥着关键作用。选择最合适的清除剂涉及几个因素,包括流速、H2S数量、需求、空间、资本支出、运营支出和其他考虑因素。

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Easy button for H2S removal

Published by , Editorial Assistant
Oilfield Technology,


Exploration and Production (E&P) of oil and natural gas often involves high risk, high investment, and technologically intensive activities.

If the industry’s activities aren’t complex enough, environmental concerns, product quality, and the protection of equipment require E&P companies to remove impurities such as hydrogen sulfide and mercaptans before the oil and gas is transported.

E&P operators need an easy button to simplify the hydrogen sulfide (H2S) and mercaptans removal step. A range of treating systems using liquid and solid solutions and service technology companies are available for H2S and mercaptan removal, each with inherent advantages and disadvantages. The importance of understanding these technologies and how they address E&P requirements cannot be overstated. This knowledge is paramount when considering all operational factors, especially those that contribute to speed to market, maintenance concerns and costs, functionality of the equipment, and making operations more straightforward, all while ensuring the environment is protected, and safety is maintained.

E&P’s H2S issue

H2S, a highly corrosive and poisonous gas, can be a significant nuisance to upstream production. This contaminant can be generated naturally or produced by technologies used during the E&P process. Natural synthesis of H2S can happen in the reservoir due to microbial sulfate reduction (MSR) of sulfate-containing minerals and/or thermochemical sulfate reduction (TSR). Processing derived H2S production can happen when using E&P technologies such as steam- assisted gravity drainage (SAGD) and hydraulic fracturing used in the production of oil sands and shale oil/gas.

H2S can manifest in all rig areas where drilling fluid and associated equipment are present, including the rig floor, substructure, shale shakers, mud cleaners, mud pit room, mud pump room, and well test equipment. Drilling and well control equipment not designed to mitigate H2S could be subject to structural integrity, impeding functionality and operations.

Upstream operators can anticipate H2S:

  • Inherently in associated natural gas (‘sour gas’).
  • During break out, also known as ‘run in the hole’, when the drill pipe has been completed, and bottom fluids are displaced to the surface.
  • If a drill pipe is extracted from the well too quickly and fluids enter the wellbore.
  • During the retrieval of core or fluid samples.
  • During the flow test process when the well flow rate, pressure, and water level are monitored and recorded.

E&P operators are known to pay US$15+ million a year in operating costs to remove H2S, but some existing technologies being used in production fields are inefficient, uneconomical, and in some cases, unsafe.

H2S removal technologies

A range of regenerative and non-regenerative H2S removal methods are available, all of which vary in how they capture and release H2S. Over the years, scavengers have been pivotal in the removal of lower quantities of H2S. Selecting the most appropriate scavenger involves several factors, including flow rates, H2S quantities, demand, space, CAPEX, OPEX, and other considerations.

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