像泥浆一样清澈:技术实现钻井泥浆的重复利用

R3 Environmental Systems 工艺从钻井作业过程中产生的废物中回收钻井液和水,用作新钻井泥浆产品中原始钻井液的直接替代品。 

一家秉持“不贪图、不想要”的公司开发了一种真空辅助石油回收工艺,可以重复利用钻井泥浆。

这项技术起源于建筑行业,可回收用过的钻井液和水并生产燃料颗粒。总部位于新斯科舍省市政集团公司的子公司R3 Environmental Systems于 2017 年开始开发该工艺,并于 2022 年真空辅助纯油回收工艺获得了 OTC Spotlight 新技术认可。 

R3 的工艺在真空下加热用过的钻井液,蒸发掉油和水馏分,然后将其冷凝并分离成碳氢化合物和水产品。市政集团公司制造总监帕特里克·鲁尼 (Patrick Rooney) 表示,在加热和 20 毫米至 40 毫米汞柱的作用下循环使用过的液体可以降低沸点,从而加快蒸馏过程并减少蒸发油所需的能量。 

他说,通常情况下,回收的液体会在高达 350 摄氏度的温度下沸腾。

“我们在 170 摄氏度下将其煮沸,因此我们不会使油破裂”或降解,他说。“我们只提取初榨油。”

他说,该过程使得可以使用一部分回收的油来加热系统,同时留下两部分回收的油可用于转售或进一步再利用。 

“我们的工业加热器实际上是在燃烧油,”鲁尼说。

他补充说,回收的蒸馏水不含氯化物。 

“水可以返回新配方,因为是蒸馏水,其中不再含有氯化物。他们实际上可以再次使用它来重新配制钻井泥浆或在其他地方使用它。在许多缺水的地方,恢复水是非常有价值的,”他说。

“前面有 200 个错误”

R3 总经理杰里·斯科特 (Jerry Scott) 表示,泥浆中的水量会影响这一过程的速度。

“燃烧掉水需要大量的能量。因此,如果有大量的水,这个过程就需要更长的时间,他说。

平均而言,该系统每小时可处理约两吨废钻井液。

斯科特表示,该公司几年前就开始寻找一种从钻井泥浆中提取石油而不破裂的方法。他说,还有其他技术可以提取石油,但不是返回原始质量的石油,而是退化的石油。

鲁尼表示,公司在选择发展路径之前调查了多项技术。 

像泥浆一样清澈:技术实现钻井泥浆的重复利用
R3 的真空辅助纯油回收装置配有蒸馏塔、蒸馏塔泵和热交换器。来源:R3 环境系统

” 戴森从未发明过旋风分离器。他是第一个将其置于真空中的人,”鲁尼说。“我们研究了这些不同的技术,其中让我们着迷的技术之一就是蒸馏。”

但在真空下泵送污泥会带来一些问题。

“污泥从一开始就很难泵送。“它们很粗糙,”他说。 

斯科特表示,泵供应商不接受这个概念。

“当我们告诉他们操作条件时,很多泵供应商甚至拒绝给我们报价,”他说。

通过一系列测试项目,R3 能够测试不同类型的泵并改进系统,将蠕动泵与高热软管和凸轮泵组合起来。

“我们现在比竞争对手更好,因为我们领先他们 200 个错误,”鲁尼说。

该工艺已在纽芬兰和拉布拉多近海使用一年。

像泥浆一样清澈:技术实现钻井泥浆的重复利用
帕特里克·鲁尼(左)和杰里·斯科特在 2022 年海上技术会议期间庆祝真空辅助纯油采收新技术受到关注。(来源:海上技术会议

“水中的石油回收率很高,”鲁尼说。“这与多种不同类型的泥浆配合得很好。”

在该过程返回初榨油和可重复使用的水的同时,它还产生可用于水泥窑或工业炉的燃料颗粒。

“实际上,我们希望制造一种可供人们使用的燃料颗粒,”斯科特说。

然而,鲁尼表示,并非所有地区或业务都使用由此产生的颗粒。 

他表示,该公司目前正在努力使该过程“高度移动”,以便能够在钻井液供应更加困难且回收的石油有用的偏远地区使用。

“这些油可以一次又一次地重复使用。因此,只要它作为废物返回给我们,我们就可以一遍又一遍地重复生产相同的基础油,因为我们不会对其进行降解,”他说。

斯科特说,整个过程减少了运营的碳足迹。 

“通常钻一口井,我们可以为他们节省约 400 吨二氧化碳排放量,”他说。“这就是一个开始。”

原文链接/hartenergy

Clear as Mud: Tech Enables Reuse of Drilling Mud

R3 Environmental Systems’ process recovers drilling fluid and water from waste generated during drilling operations for use as a direct substitute for virgin drilling fluid in new drilling mud products. 

A company taking “waste not, want not” to heart has developed a vacuum-assisted oil recovery process that makes it possible to reuse drilling mud.

The technology, which emerged from the construction industry, recovers used drilling fluid and water and generates fuel pellets. Nova Scotia-based R3 Environmental Systems, a subsidiary of Municipal Group of Companies, started developing the process in 2017, and in 2022 the Vacuum Assisted Pure Oil Recovery process received OTC Spotlight on New Technology recognition. 

R3’s process heats used drilling fluid under a vacuum to evaporate out the oil and water fractions before condensing them and separating them into hydrocarbon and water products. Circulating the used fluid under heat and 20 mm to 40 mm of mercury lowers the boiling point—speeding up the distillation process and reducing the energy required to boil off the oil, said Patrick Rooney, director of manufacturing for Municipal Group of Companies. 

Normally, he said, the recovered fluids would boil off at temperatures as high as 350 C.

“We’re boiling it off at 170 degrees Celsius, so therefore we’re not cracking” or degrading the oil, he said. “We’re pulling off just the virgin oil.”

He said the process makes it possible to use one part of recovered oil to heat the system while leaving two parts of recovered oil available for resale or further reuse. 

“We're actually burning the oil in our industrial heaters,” Rooney said.

The recovered distilled water contains no chlorides, he added. 

“The water could go back for a new formulation because being distilled water, there's no more chlorides in it. They could actually use that again to reformulate drill mud or use it in the process somewhere else. And in lots of places where water is scarce, it's very valuable to get the water back,” he said.

'200 mistakes ahead'

Jerry Scott, general manager for R3 said the amount of water in the mud affects the speed of the process.

“It takes a lot of energy to burn off the water. So if there's a lot of water,” the process takes longer, he said.

On average, the system can treat about two tons of used drilling fluid per hour.

Scott said the company started looking for a way to extract oil from drilling mud without cracking some years back. There are, he said, other technologies that can extract the oil, but rather than returning virgin quality oil, it’s degraded.

Rooney said the company investigated a number of technologies before choosing a path to pursue. 

Clear as Mud: Tech Enables Reuse of Drilling Mud
R3’s Vacuum Assisted Pure Oil Recovery plant features a distillation tower, distillation tower pumps and heat exchangers. (Source: R3 Environmental Systems)

“Dyson never invented the cyclone. He's just the first one to put it in a vacuum,” Rooney said. “We looked at these different technologies and one of the ones that fascinated us was distillation.”

But pumping sludges under a vacuum posed some problems.

“Sludges are hard to pump in the first place. They’re abrasive,” he said. 

Scott said pump vendors were not receptive to the concept.

“We had a lot of pump vendors even refusing to quote us once we told them the operating conditions,” he said.

Through a series of test projects, R3 was able to test different types of pumps and refine the system to include a combination of peristaltic pumps with high heat hoses and lobe pumps.

“We're better than the competition right now because we're 200 mistakes ahead of them,” Rooney said.

The process has been used offshore Newfoundland and Labrador for a year.

Clear as Mud: Tech Enables Reuse of Drilling Mud
Patrick Rooney, left, and Jerry Scott celebrate Spotlight on New Technology recognition for Vacuum Assisted Pure Oil Recovery during Offshore Technology Conference 2022. (Source: Offshore Technology Conference)

“We have good recovery rates for the oil in the water,” Rooney said. “That’s gone very well with multiple different types of mud.”

And while the process returns virgin oil and reusable water, it also creates fuel pellets, which can be used in cement kilns or industrial furnaces.

“Ideally, we'd like to make a fuel pellet that someone can use,” Scott said.

However, Rooney said, not all regions or operations are set up to use the resulting pellets. 

He said the company is now working to make the process “highly mobile” to allow it to be used in remote locations where supply of drilling fluids is more difficult and recovered oil would be useful.

“The oil could be reused over and over and over again. So as long as it comes back to us as waste, we could reproduce the same base oil that could be over and over because we're not degrading it,” he said.

The whole process, Scott said, reduces the carbon footprint of operations. 

“Typically to drill one well, we can save them about 400 tons of CO2 emissions,” he said. “It’s a start.”