油田化学

非常规油气设施中的微生物腐蚀:定制的整体解决方案

这项关于非常规设施中微生物控制的综合研究可以整合分子微生物学、化学处理和生产工程,以制定控制微生物群落和降低影响设施完整性的腐蚀率的具体策略。

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经过 21 天的孵化后,对碳钢试样进行共聚焦显微镜检查。
来源:论文 SPE 228313

阿根廷及全球其他页岩气田非常规油藏的回流水中含有丰富的Halanaerobium菌属微生物群。这种微生物原生于这些油藏,并在地面设施中旺盛生长,主要通过硫代硫酸盐还原、有机酸生成和生物膜形成等方式促进微生物腐蚀 (MIC)。因此,Halanaerobium菌是Vaca Muerta非常规油藏地面设施中需要控制的关键目标菌属。

本研究提出了一套在实验室和现场条件下实施的定制化整体解决方案。在实验室中开发了目标菌属的浮游和固着体外培养物,并通过三磷酸腺苷 (ATP) 杀灭试验、荧光和共聚焦显微镜筛选出有效的杀菌剂配方。在现场,基于最低抑菌浓度 (MIC) 风险评估设计了处理方案,并集成了先进全面的监测技术,包括 ATP 计数、目标特异性定量聚合酶链式反应计数、用于完整微生物多样性的宏基因组分析、腐蚀产物的光谱表征以及使用碳钢试样的腐蚀速率监测。

该解决方案在阿根廷一家非常规原油处理厂的应用证明了其有效性。该方案成功实现了既定的关键性能指标——减少微生物总数、降低腐蚀速率以及消除液流中的目标菌属——彰显了该处理方案的有效性以及极具竞争力的应用成本。值得一提的是,该处理方案还引发了微生物群落的变化,这表明持续定制缓解工具可能大有裨益。


本摘要摘自 YPF Tecnologia 的 M. Pagliaricci、G. Rojas、FL Massello 和 J. Dos Santos 的论文 SPE 228313; E. Bortoli 和 S. Navarrete,YPF Qumica,布宜诺斯艾利斯自治城; W. Morris,YPF Tecnologia; W. Vargas,YPF,布宜诺斯艾利斯自治市;和 I. Vega,YPF Tecnologia。该论文已经过同行评审,并可在 OnePetro 的 SPE 期刊上以开放获取方式获取。

原文链接/JPT
Oilfield chemistry

Microbiologically Influenced Corrosion in Unconventional Oil and Gas Facilities: A Tailored Integral Solution

This comprehensive study on microbial control in unconventional facilities allows for the integration of molecular microbiology, chemical treatments, and production engineering to develop specific strategies to control microbial communities and reduce corrosion rates that affect the integrity of the facilities.

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Confocal microscopy of carbon steel coupons after 21 days of incubation.
Source: Paper SPE 228313

Flowback water from unconventionalreservoirs in Argentina and other shale plays worldwide contains a microbiome rich in the bacterial genus Halanaerobium. This microorganism is native to these reservoirs and thrives in surface facilities, where it contributes to microbiologically influenced corrosion (MIC), primarily through thiosulfate reduction, organic acid production, and biofilm formation. Consequently, Halanaerobium is the key target genus to control in the surface facilities of Vaca Muerta’s unconventional production.

This study presents a tailored integral solution implemented at laboratory and field conditions. Both planktonic and sessile in-vitro cultures of the target genus were developed in the laboratory, and effective biocidal formulations were selected through adenosine triphosphate (ATP) kill tests, fluorescence, and confocal microscopy. In the field, treatment applications were designed based on MIC risk assessments and integrated with advanced and comprehensive monitoring techniques, including ATP counts, target-specific quantitative polymerase chain reaction counts, metagenomic analysis for complete microbial diversity, spectroscopic characterization of corrosion products, and corrosion rate monitoring using carbon steel coupons.

The application of this solution in an unconventional crude-oil treatment plant in Argentina demonstrated its effectiveness. The defined key performance indicators were successfully achieved—a reduction in total microorganism counts, a decrease in corrosion rate, and the elimination of the target genus in liquid streams—underscoring the treatment’s effectiveness at a competitive application cost. It is worth mentioning the treatment also induced changes in the microbiome, suggesting that ongoing customization of mitigation tools may be beneficial.


This abstract is taken from paper SPE 228313 by M. Pagliaricci, G. Rojas, F.L. Massello, and J. Dos Santos, YPF Tecnologia; E. Bortoli and S. Navarrete, YPF Química, Ciudad Autónoma de Buenos Aires; W. Morris, YPF Tecnologia; W. Vargas, YPF, Ciudad Autónoma de Buenos Aires; and I. Vega, YPF Tecnologia.The paper has been peer reviewed and is available as Open Access in SPE Journal on OnePetro.