能源转型

挖掘美国墨西哥湾沿岸的“盐田”用于储氢

研究人员正在建立一个包含数百个盐丘的综合数据库,以帮助扩大美国地下氢的储存。

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取自德克萨斯州盐丘的岩芯样本。
资料来源:德克萨斯大学经济地质局。

德克萨斯大学奥斯汀经济地质局的研究人员正在带头扩大美国墨西哥湾沿岸盐丘和洞穴的氢储存量。

该计划是该局德克萨斯州高级资源回收 (STARR) 计划的一部分,该计划正在为该地区陆上和海上发现的 600 多个盐丘建立一个综合数据库。

然而,并非每个站点都适合存储,因此 STARR 正在组装新工具来帮助进行早期站点表征和筛选过程。该列表包括新的建模工作流程、盐芯描述协议、地震/岩石物理特征以及估计注入/抽取方案的新方法。

地球科学家兼 STARR 项目主任 Lorena Moscardelli 强调“每个穹顶和每个洞穴都是独一无二的”,并补充道,“一个穹顶可以有 60 到 70 个洞穴,这说明了正确的地下特征描述与适当的工程方法。”

墨西哥湾沿岸的氢基础设施包括德克萨斯州世界上仅有的三个用于氢储存的盐丘,但它们几乎完全致力于为炼油厂和石化厂提供原料。

莫斯卡德利相信,最近该地区规划的一系列“绿色”和“蓝色”氢能项目可能会改变这一现状。她表示,如果生产出足够的氢气来替代大量使用的天然气,存储需求“可能是巨大的”,并且“地面储罐将成为这种规模的经济上可行的解决方案。”

有助于说明的是,该局最近的另一项研究估计,如果新的氢项目在 2019 年仅取代美国天然气消费量的 1%,则需要额外 100 Bcf 的存储容量。目前,墨西哥湾沿岸仅有 5 至 8 Bcf 的储存量。

幸运的是,STARR 相信未来氢供应有足够的空间分布在其所谓的美国“盐地产”上。除墨西哥湾沿岸外,该国的投资组合还包括墨西哥湾的近海盐丘、德克萨斯州西部二叠纪盆地的盐层以及犹他州的一些地点,其中一个政府支持的大型项目计划储存利用风能和氢气生产的氢气。两个 450 万桶盐穴的太阳能发电。

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显示德克萨斯州、路易斯安那州、密西西比州和墨西哥湾盐丘位置的交互式地图的屏幕截图。用户可以单击每个图标并查看基本信息(例如深度、直径、洞穴数量等)以及指示储氢潜力的热图。
资料来源:德克萨斯大学奥斯汀分校经济地质局/德克萨斯州高级资源回收局。

加盐还是加冰块?

虽然潜力似乎已经成熟,但盐丘和盐穴通常被描述为“受地理限制”,这换句话说,在美国许多其他地区和世界大部分地区,它们不是一种选择。这种相对稀缺性促使德克萨斯大学和其他地方的其他人对在多孔介质地层(即枯竭的气藏和盐水层)中储存氢的未经证实的概念开展了并行研究。

储层岩石比盐丘丰富得多,存储容量也更大。但由于缺乏现场经验,莫斯卡德利表示,我们可能不会看到针对储层岩石的商业规模储氢项目在这十年内实现。

她说,“与盐丘中的人造洞穴相比,多孔介质中储氢的技术不确定性要大得多”,而盐丘可以在不到 5 年的时间内规划和调试。

莫斯卡德利还指出,除了储存氢气之外,盐层还有数十年储存石油和天然气的记录,包括在美国战略石油储备中。

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拟议的 220 兆瓦电解槽设施将利用间歇性可再生能源生产氢气,并计划使用犹他州三角洲的两个盐穴进行储存。2022 年 6 月,美国能源部向项目开发商 Advance Clean Energy Storage 贷款超过 5 亿美元用于建设该设施。
资料来源:先进清洁能源存储。

与此同时,将氢气注入正在研究的多孔介质中所面临的挑战包括微小分子如何在储层系统内快速迁移及其引起化学和微生物反应的潜力。每个问题都可能导致产品损失,但后者可能同时产生不需要的副产品,例如有毒的硫化氢气体。

Leopoldo Ruiz Maraggi 是一名油藏工程师,与 STARR 合作帮助开发新的流动模型,他指出,盐丘的性质消除或大大减轻了这些风险因素。他将盐穴描述为“本质上是地表下的储罐”,这意味着注入氢气的回收率接近 100%(减去用于维持足够压力的缓冲气体体积)。

与储层岩石相比的另一个优点是,更容易在盐层中储存近乎纯净的氢,这应该避免表面分离或脱水的需要。进一步支持商业案例的是,盐穴使天然气能够按需流动,一些人认为这对于满足发电厂的及时需求至关重要。

正如鲁伊斯·马拉吉(Ruiz Maraggi)解释的那样,“在盐洞中,只有一个空隙,因此与多孔介质相比,流体流动的阻力更小。” 这意味着我们可以实现更大的注入和提取率。”

但盐的形成还存在一些未知因素。

例如,虽然盐丘通常被认为对氢呈惰性,但这只是部分正确。它们可能含有矿物异质性,可能与氢发生负面反应并影响储存潜力,莫斯卡德利说,这强调了“需要追求详细的地下特征”。

此外,目前储存氢气的少量圆顶通常被认为是炼油厂关闭时的备用,因此每年可能仅使用一到两次。

在假设的绿色氢场景中,盐穴可能需要每年多次填充和抽水才能为发电厂供电。由此引入的压力和温度动态将影响洞穴的整体容量,这也是 STARR 表示需要在建模方面取得进展的原因之一。

该小组计划在一系列即将发表的同行评审论文中分享更多有关其正在进行的研究的信息,这些论文涵盖了人造盐洞储氢的各个方面。

原文链接/jpt
Energy transition

Digging Into the US Gulf Coast's 'Salt Real Estate' for Hydrogen Storage

Researchers are building a comprehensive database of hundreds of salt domes to help expand subsurface hydrogen storage in the US.

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Core sample taken from a salt dome in Texas.
Source: University of Texas Bureau of Economic Geology.

Researchers from The University of Texas (UT) at Austin’s Bureau of Economic Geology are spearheading efforts to expand hydrogen storage in salt domes and caverns along the US Gulf Coast.

The initiative is part of the bureau’s State of Texas Advanced Resource Recovery (STARR) program that is building a comprehensive database of the region’s more than 600 salt domes found both onshore and offshore.

However, not every site is ideal for storage, so STARR is assembling new tools to help with the early site characterization and screening process. The list includes new modeling workflows, protocols for salt-core descriptions, seismic/petrophysical characterizations, and new ways to estimate injection/withdrawal schemes.

Lorena Moscardelli, a geoscientist and the director of the STARR program, emphasized that "each dome and each cavern is unique" and added, "a single dome can have 60 to 70 caverns, which speaks to the importance of proper subsurface characterization in conjunction with appropriate engineering approach."

The Gulf Coast's hydrogen infrastructure includes in Texas the world's only three salt domes used for hydrogen storage, but they are almost entirely dedicated to supplying refineries and petrochemical plants with the feedstock.

Moscardelli believes the recent raft of "green" and "blue" hydrogen projects being planned across the region could change that. If enough hydrogen is produced to replace a meaningful share of natural gas used, she said the storage requirements “would be overwhelming” and that “surface tanks won’t be an economically feasible solution at this scale.”

Helping to illustrate, separate research from the bureau recently estimated that if new hydrogen projects displaced the equivalent of just 1% of US natural gas consumption in 2019, an additional 100 Bcf of storage capacity would be needed. Currently, just 5 to 8 Bcf of storage exists along the Gulf Coast.

Fortunately, STARR believes there is more than enough room for future hydrogen supplies spread across what it calls the "salt real estate" of the US. Aside from the Gulf Coast, the nation’s portfolio includes offshore salt domes in the Gulf of Mexico, salt beds in the Permian Basin of west Texas, and locations in Utah where a major government-backed project plans to store hydrogen produced using wind and solar power in two 4.5-million bbl salt caverns.

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Screenshot showing an interactive map of salt dome locations in Texas, Louisiana, Mississippi, and in the Gulf of Mexico. Users can click each icon and see basic information (e.g., depth, diameter, number of caverns, etc.) and a heat map indicating hydrogen storage potential.
Source: The University of Texas at Austin Bureau of Economic Geology/State of Texas Advanced Resource Recovery.

With Salt or On the Rocks?

While the potential seems ripe, salt domes and caverns are often described as “geographically constrained,” which is another way of saying they are not an option in many other parts of the US and for much of the world. This relative scarcity has prompted others at UT and elsewhere to launch parallel research into the unproven concept of storing hydrogen in porous media formations, i.e., depleted gas reservoirs and saline aquifers.

Reservoir rocks are far more abundant and have larger storage capacities than salt domes. But given the lack of field experience, Moscardelli said we will likely not see a commercial-scale hydrogen storage project targeting reservoir rock materialize in this decade.

“There are a whole lot more technical uncertainties with hydrogen storage within porous media than within manmade caverns in salt domes,” which can be planned and commissioned in less than 5 years, she said.

Moscardelli also pointed out that in addition to storing hydrogen, salt formations have a decades-long track record of storing oil and gas, including at the US Strategic Petroleum Reserve.

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A proposed 220-MW electrolyzer facility that will run on intermittent renewable power to produce hydrogen plans to use two salt caverns for storage in Delta, Utah. In June 2022, the US Department of Energy loaned project developer Advance Clean Energy Storage more than half a billion dollars to construct the facility.
Source: Advanced Clean Energy Storage.

Meanwhile, the challenges involved with injecting hydrogen into porous media being studied include how the tiny molecule rapidly migrates within a reservoir system along with its potential to cause chemical and microbial reactions. Each issue may lead to product loss, but the latter may simultaneously generate unwanted byproducts such as toxic hydrogen sulfide gas.

Leopoldo Ruiz Maraggi, a reservoir engineer working with STARR to help develop new flow models, noted that the nature of salt domes negates or substantially mitigates these risk factors. He describes salt caverns as “essentially tanks under the surface,” which means recovery rates of the injected hydrogen is nearly 100% (minus the cushion gas volumes used to maintain adequate pressure).

Another advantage over reservoir rocks is that it is much easier to store nearly pure hydrogen inside salt formations, which should avoid the need for surface separation or dehydration. Further bolstering the business case is that salt caverns enable gas to flow on demand, which some consider to be critical in meeting the timely needs of power plants.

As Ruiz Maraggi explained, “In a salt cavern, you simply have a void and thus less resistance for fluid flow compared to porous media. This means that we can achieve larger injection and withdrawal rates.”

But there are some unknowns involved with salt formations.

For instance, while salt domes are commonly thought to be inert to hydrogen, this is only partly true. They can contain mineralogical heterogeneities that could negatively react with hydrogen and impact storage potential which Moscardelli said underscores the "need to pursue detailed subsurface characterizations.”

Additionally, the small number of domes storing hydrogen today are generally considered backup for refinery shutdowns and as such may be used only once or twice annually.

In a hypothetical green hydrogen scenario, a salt cavern may need to be filled up and drawn down several times a year to feed a power plant. The pressure and temperature dynamics this introduces will impact the overall capacity of a cavern, which is one reason STARR says its advancements on modeling are needed.

The group plans to share more about its ongoing research in a series of soon-to-be-published peer-reviewed papers covering various aspects of hydrogen storage in manmade salt caverns.