Occidental:部分 DAC 已做好扩展准备

西方石油公司和其他直接空气捕获企业面临的主要挑战是该过程是否具有成本竞争力。

Wood Mackenzie 全球 CCUS 经济总监 Peter Findlay 告诉 Hart Energy,存储是一个主要因素,包括规模、技术风险和与碳排放者的距离。(来源:Shutterstock)

该行业几十年来一直在捕获碳,但其中大部分是更容易捕获的燃烧前碳。 

Wood Mackenzie北美分析师 Rohan Dighe 告诉 Hart Energy,直接空气捕获 (DAC) 正在挑战“更难的东西”,即燃烧后碳。 

“这里”有许多不同的捕获技术。目前更被接受的行业标准是使用胺作为溶剂,但也有新的提议溶剂,”他说。“这里有新的吸收剂,有膜,还有正在提议的其他技术,并且处于不同的技术准备度和商业适应性水平。”

碳捕获技术只是碳捕获、利用和封存 (CCUS) 难题的一部分。Wood Mackenzie 全球 CCUS 经济总监 Peter Findlay 告诉 Hart Energy,存储是一个主要因素,包括规模、技术风险和与碳排放者的距离。

他说,存储的一个挑战是确保有足够的规模来处理二到四十年的排放量。 

“通过真正了解地质情况和羽流的走向,你可以降低技术风险,”他说。

他补充说,迄今为止,存储在小规模运营中大多取得了成功,但挪威近海的斯莱普纳项目是一个明显的例外。

他说,一旦排放者相信一个项目能够可靠地处理排放规模,运输问题仍然存在。

“你希望有足够多的排放者相信整个CCS(碳捕获和封存)商业模式对他们有利,这样他们就可以在合理的风险下真正赚钱,”他说。

芬德利表示,目前,每个人都在试图了解如何在不带来不可预见的未来风险的情况下使 CCS 和存储项目变得可行。

“在某种程度上,页岩气生产的早期阶段存在一些相似之处,即风险似乎是可控的,但人们正在确定风险的水平和大小顺序,”他说。

他说,在某种程度上,碳有可能储存在页岩气中,尽管它很可能会储存在枯竭的油气井中。

“在美国,我们看到一些地区存在临时或接近储存的情况,通常不是在页岩中,而是在页岩附近的枯竭的石油和天然气井中,”他说。

需要更多 CCS 项目

碳捕获项目对于到 2050 年实现净零排放目标至关重要。据 Wood Mackenzie 称,要实现这些目标,每年需要70 亿吨 (btpa) CO 2产能。然而,到 2050 年,世界只能实现 2 btpa 的基本情景,这将导致全球变暖 2.5 摄氏度,远高于将气温上升限制在 1.5 摄氏度的目标。

10 月份,Wood Mackenzie 表示,全球计划的 CCUS 产能为每年 1.4 btpa 的 CO 2捕集、运输和封存项目。美国在计划活动方面处于领先地位,占所有项目的 33%。

2020年,西方石油公司的风险投资部门Oxy Low Carbon Ventures与Rusheen Capital Management联手成立了1PointFive新公司授权 Carbon Engineering 的 DAC 技术在二叠纪盆地建造一座 DAC 工厂。从那时起,西方石油公司对 DAC 的关注已将该技术推上了头条新闻。西方石油公司随后以 11 亿美元收购了 Carbon Engineering 。

“xy 将全力投入 DAC,以此作为抵消其上游产品组合碳排放的一种方式,”Dighe 表示。“我认为 DAC 的最大问题(或者说最大的障碍)是成本,并确保其具有成本竞争力,特别是与其他点源减排相比。”

虽然存在一些压力,要求不要仅仅为了证明持续的石油和天然气排放而使用 DAC,但他表示,主要问题是,与其他碳捕获方法相比,DAC“从根本上来说是昂贵的”。

西方石油公司负责运营、美国陆上资源和碳管理的总裁理查德·杰克逊在公司第三季度财报电话会议上表示,DAC 是一项必要且有价值的技术。 

“短期内,我们相信我们的 DAC 技术能够以比其他产品解决方案更低的成本和更大的规模为 CDR(二氧化碳去除)提供二氧化碳去除信用,”他说。

DAC技术

1PointFive 计划的 DAC 设施将使用Carbon Engineering 的除碳技术。第一步使用风扇将大量空气吸入空气承包商,这是一个以工业冷却塔为模型的大型结构。一旦风扇将空气吸入承包商,空气就会流过表面,氢氧化钾溶液流过该表面。氢氧化钾溶液与CO 2分子发生化学结合,将它们以碳酸盐的形式捕获在液体中。 

碳酸盐经过浓缩、纯化和压缩,因此可以以气体形式输送以供储存或使用。该过程将盐从溶液中分离出来,将盐形成小颗粒,并加热颗粒以释放纯气体形式的CO 2 。

“Arbon Engineering 创造了一种独特且创新的大规模除碳工艺,与我们的 OxyChem 能力非常契合。这个过程使用了可以大规模部署的设备和材料,”杰克逊说。

斯特拉托斯正在进行中

1PointFive 于 2023 年 4 月在德克萨斯州埃克托县的第一个 DAC 设施(名为 Stratos)破土动工。施工已完成30%以上。计划于 2025 年中期启动,该设施预计每年 捕获高达 500,000 公吨 CO 2 。

1PointFive 总裁兼总经理 Mike Avery 在财报电话会议上表示,到 2030 年,Stratos 的净产能将售出 65% 至 70%。在此之后,一系列早期谈判将使 Stratos 的净产能达到约 85%他说,到 2030 年产能都会售罄。

“我认为,人们也越来越认识到直接空中捕获技术在未来不会被淘汰。” 他说,这项技术现在已经准备好在商业规模上投入使用,而且当与其他一些替代方案放在一起时,它实际上比人们想象的更便宜。

西方石油公司表示,Carbon Engineering 正在将 Stratos 的 FEED 研究应用于将在德克萨斯州克莱伯格县 King Ranch 建造的 DAC 工厂。美国能源部清洁能源示范办公室 8 月宣布,克莱伯格县设施将获得高达 6 亿美元的拨款,作为南德克萨斯 DAC 中心的一部分。

Jackson 表示:“收购 Carbon Engineering 之际,加速 DAC 创新的需求至关重要。”他补充说,Oxy 将致力于将 Carbon Engineering 的创新快速整合到 DAC 工厂中。 

Jackson 表示,公司下一阶段的 DAC 战略将侧重于加速降低成本和扩大合作伙伴关系。他说,对空气接触器设计的一些改进可能会减少每个设施所需的空气接触器的数量。功耗更低的空气接触器风扇电机正在开发中。

1PointFive 表示,根据当前的合规性和市场情况,预计到 2035 年在全球部署 100 多个 DAC 设施,但在季度财报电话会议上,Jackson 表示,市场需求和降低成本的能力将影响该公司开发未来 DAC 设施的速度。 

“如果CDR市场发展慢于预期,我们将可以灵活地重新将精力集中在研发上,目标是更快地降低成本,”他说。“如果 CDR 市场的发展符合我们所规划的中或高水平,那么我们打算继续执行我们的成本降低计划,并为此做好准备以确保开发合作伙伴。”

WoodMac 碳项目
规划和运营项目所在地。(来源:伍德麦肯齐)
原文链接/hartenergy

Occidental: Parts of DAC Ready to Scale

A major challenge facing Occidental and other direct air capture ventures is whether the process can be made cost-competitive.

Storage is a major factor that includes scale, technical risk and proximity to carbon emitters, Peter Findlay, Wood Mackenzie’s director of CCUS economics globally, told Hart Energy. (Source: Shutterstock)

The industry has been capturing carbon for decades, but most of that has been the easier-to-capture pre-combustion carbon. 

Direct air capture (DAC) is taking on “the harder stuff,” or the post-combustion carbon, Rohan Dighe, North American analyst at Wood Mackenzie, told Hart Energy. 

“There’s lots of different capture technologies for that. The more accepted industry standard right now is using amines as a solvent, but there’s new proposed solvents,” he said. “There’s new absorbents, there’s membranes, there’s other technologies that are being proposed and are at different levels of technology readiness and commercial adaptability.”

The technology to capture carbon is only part of the puzzle when it comes to carbon capture, utilization and sequestration (CCUS). Storage is a major factor that includes scale, technical risk and proximity to carbon emitters, Peter Findlay, Wood Mackenzie’s director of CCUS economics globally, told Hart Energy.

He said a challenge of storage is ensuring there’s enough scale to deal with two to four decades of emissions. 

“You can decrease your technical risk by really understanding the geology and where the plume is going,” he said.

To date, storage has mostly been successful in small-scale operations, with the notable exception of the Sleipner project offshore Norway, he added.

And once emitters believe a project can handle the scale of emissions reliably, there’s still the transport issue, he said.

“You want enough emitters that can be convinced that the whole CCS (carbon capture and sequestration) business model is favorable for them, so they can actually make money on this with a reasonable amount of risk,” he said.

Right now, Findlay said, everyone is trying to understand how to make CCS and storage projects feasible without opening up unforeseen future risks.

“To some extent, there’s some similarities there in the early days of shale production in that the risks seemed manageable, but people were determining the level and order of magnitude of risks as they level,” he said.

At some point, there is the potential that carbon may be stored in shale plays, he said, although it’s most likely it will be stored in depleted oil and gas wells.

“In the U.S., we see some areas where there’s contingent or close to storage, not usually in the shale, but in depleted oil and gas wells that are near the shale,” he said.

More CCS projects needed

Carbon capture projects are critical to meet net-zero emissions goals by 2050. According to Wood Mackenzie, 7 billion tonnes per annum (btpa) of CO2 capacity is required to meet those goals. However, the world is only on track to meet a base case scenario of 2 btpa by 2050, which would result in global warming of 2.5 C, well above the goal of limiting the temperature increase to 1.5 C.

In October, Wood Mackenzie said globally planned CCUS capacity was at 1.4 btpa of CO2 across capture, transport and storage projects. The U.S. leads in planned activity with 33% of all projects.

In 2020, Occidental Petroleum’s venture capital arm, Oxy Low Carbon Ventures, joined with Rusheen Capital Management to form 1PointFive. The new company licensed Carbon Engineering’s DAC technology to build a DAC plant in the Permian Basin. Since then, Occidental’s DAC focus has thrust that technology into headlines. Occidental later acquired Carbon Engineering for $1.1 billion.

“Oxy is going all in on DAC as a way of offsetting the carbon from its upstream portfolio,” Dighe said. “I think the big issue—or the big hurdle—for DAC is cost and making sure that it’s cost competitive, especially compared to other point source emission abatement.”

While there has been some pressure not to use DAC merely to justify continuing oil and gas emissions, he said the main issue is that DAC is “just fundamentally expensive” compared to other carbon capture methods.

Richard Jackson, Occidental’s president for operations, U.S. onshore resources and carbon management, said during the company’s third-quarter earnings call that DAC is both a necessary and valuable technology. 

“Near term, we believe our DAC technology can provide carbon dioxide removal credits for CDRs (carbon dioxide removal) at a lower cost and a larger scale than other product solutions,” he said.

DAC technology

1PointFive’s planned DAC facilities will use Carbon Engineering’s carbon removal technology. The first step uses fans to pull large volumes of air into an air contractor, which is a large structure modeled on industrial cooling towers. Once the fan pulls air into the contractor, it passes over a surface with a potassium hydroxide solution flowing over it. The potassium hydroxide solution chemically binds with the CO2 molecules, trapping them in the liquid as a carbonate salt. 

The carbonate salt is concentrated, purified and compressed so it can be delivered in gas form for storage or use. This process separates the salt out of the solution, forms the salt into small pellets and heats the pellets to release the CO2 in pure gas form.

“Carbon Engineering created a unique and innovative large-scale carbon removal process that has a strong fit to our OxyChem capabilities. This process uses equipment and materials that are ready to deploy at scale,” Jackson said.

Stratos underway

1PointFive broke ground in April 2023 on its first DAC facility, known as Stratos, in Ector County, Texas. Construction is more than 30% complete. Start-up is planned for mid-2025, and that facility is expected to capture up to 500,000 metric tonnes of CO2 per year. 

Mike Avery, president and general manager of 1PointFive, said during the earnings call that Stratos’s net capacity is 65% to 70% sold out through 2030. Behind that, a pipeline of earlier stage negotiations will take Stratos up to about 85% net capacity sold out through 2030, he said.

“I think there’s also growing recognition that direct air capture is not sitting out in the future. It’s a technology that’s ready to go now at commercial scales and that it’s actually more affordable than people think when placed next to some of the other alternatives out there,” he said.

Occidental said Carbon Engineering is adapting Stratos’s FEED study for a DAC plant to be built at King Ranch in Kleberg County, Texas. The U.S. Department of Energy’s Office of Clean Energy Demonstrations in August announced the Kleberg County facility would receive a grant of as much as $600 million as part of the South Texas DAC Hub.

“The acquisition of Carbon Engineering comes at a time where the need to accelerate DAC innovation is critical,” Jackson said, adding Oxy will work to rapidly integrate Carbon Engineering’s innovations into the DAC plants. 

Jackson said the next phase of the company’s DAC strategy will focus on accelerating cost reduction and expanding partnerships. Some improvements to air contactor design might reduce the number of air contactors required per facility, he said. Air contactor fan motors that consume less power are under development.

1PointFive has said it envisions deploying more than 100 DAC facilities worldwide by 2035 under current compliance and market scenarios, but during the quarterly earnings call, Jackson said market demand and the ability to reduce costs will influence the pace at which the company develops future DAC facilities. 

“If the CDR market develops slower than expected, we will have the flexibility to refocus our efforts on R&D, with the goal of bringing costs down faster,” he said. “If the CDR market develops in line with the medium or high cases we’ve laid out, then we intend to continue executing on our cost-down plan and to be positioned to secure development partners for this.”

WoodMac Carbon Projects
Where planned and operating projects are located. (Source: Wood Mackenzie)