油田化学

出色的排量和井筒清理

案例研究证明选择更环保、更高效、更强大的置换系统的好处

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设备仓库

2010 年马孔多漏油事件标志着石油和天然气行业的一个重大转折点。无论人们如何看待该事件的原因,随后出台的严格安全和环境法规从根本上改变了海上作业的进行方式。但即使在事件发生之前,随着作业进入更深的水域,井更深、斜度更大、压力和温度更高,以及非水钻井液的使用不断增加,挑战已经堆积起来。所有这些因素对用于置换钻井液和清理井眼的系统具有决定性影响。

前后位移

理想情况下,驱替操作应以最小的流体界面驱替充满固体的钻井液,去除所有残留固体,并使表面保持水润湿,以实现最佳完井阶段。完井阶段固体的存在会导致金属管的缝隙腐蚀和硫化氢应力开裂,并损害地质构造的渗透性和孔隙度,这将对油藏的产能产生负面影响。

在马孔多之前,位移通常是间接的、不平衡的,而且速度相当慢,无法确保彻底清理。间接驱替需要在钻井液和完井液之间使用中间液。大多数海上作业需要使用大量海水,以低于地层静水压力(欠平衡)的压力泵入井眼,然后通常简单地排放到海洋中。该技术可以有效地提供非常干净、无固体的井眼,还可以减少与使用隔离器和过滤相关的时间和成本,但它有一些严重的缺点。首先,从环境角度来看,它并不理想。其次,中间流体的使用增加了操作时间。第三,压力不平衡可能导致油藏压力淹没井筒,导致井涌甚至井喷,这当然会带来严重的安全和环境风险。

马孔多后的法规规定,作业者必须始终保持两道屏障,必须考虑到从井中流出的每一桶液体,并且任何排放都必须比以前更加环保。因此,大多数操作员转而采用直接的平衡或超平衡位移,无需海水等中间流体,但仍然缓慢进行。然而,事实证明,这项技术远非理想,流体界面的体积大得不可持续,在某些情况下需要更换数千桶流体,而且剩余固体含量如此之高,以至于人们很难称其为该操作“井筒清理”。

大多数驱替系统由采用表面活性剂(表面活性剂)配制的垫片组成,可降低溶剂和表面活性剂的表面张力以捕获固体和润湿管道表面。含有溶剂(通常源自石油)的系统的问题在于它们不能与水基流体很好地配合。仅使用表面活性剂的系统的问题在于,它们不能很好地清除许多合成泥浆,例如那些用酯异构化烯烃配制的泥浆。

创新一种新型位移系统

面对看似无法克服的问题,该行业确实需要彻底重新思考海上排水的化学和机械原理,但这是一项艰巨的任务。任何新的解决方案都必须满足安全性、有效性、法规和经济性方面的多项严格标准,即:

  • 成本效益;
  • 环保;
  • 去除固体物能力强;
  • 有效地使表面保持水润湿;
  • 能够在井底高温下工作;
  • 密度足以取代更深井中使用的密度更大的非水钻井液。

TETRA 创新集团的科学家们始终渴望应对新的挑战,他们着手开发解决方案,并提出了 TETRA 先进驱替系统或 TADS,这是一种专为实现最佳井眼清理而设计的三相透明盐水解决方案。该系统专为直接或间接驱替水基、油基和合成基钻井泥浆而设计,在完井阶段能够非常有效地去除固体并使管表面水润湿。

但 TADS 并不是一种静态的、一刀切的技术。它不断改进并针对每个应用程序进行定制。根据井眼条件以及操作员使用的钻井和完井液类型,TADS 由低密度或高密度卤化物盐水和 TETRAClean 900 系列化学品的定制混合物组成。

TADS 案例研究 1

墨西哥湾的一家运营商打算暂时放弃一口深水井,以便稍后完成,无需额外的循环或过滤。水深约 2,000 英尺,井深 26,000 英尺,井底温度为 260°F。第一阶段是“零”置换,使用与 Q125 合金套管兼容的定制配方高密度、无固体、防腐蚀悬浮液来置换 16.5 磅/加仑的含固体合成泥浆它已经在井里五年多了。10 个月后进行第二阶段,需要应用由溴化钙和溴化锌配制的高密度、无固体 TADS。

尽管 TETRA 工程师相信位移和清理将非常令人满意,但操作实际上超出了预期,大大减少了暂停井和随后启动完井阶段的井眼清理管柱的数量。TETRA 解决方案最终为运营商节省了 540 万美元,提供了更高效的临时废弃方式,并为竣工阶段做好了理想的准备。

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TADS 案例研究 2

墨西哥湾的一家运营商在 4,400 英尺深的海底井中使用 TADS,用 13.9 磅/加仑的氯化钙和溴化钙完井液置换 14.4 磅/加仑的异构化烯烃基泥浆。TADS 清除了井眼和立管中的所有泥浆和残留固体,将完井液返回地面,仅 75 桶受污染的流体界面。相比之下,在应用 TADS 之前,受污染的流体回流量通常为 700 至 800 桶。TADS 减少了硅藻土压滤机上的固体负载,从而实现更长的过滤周期并减少清理时间。浊度降低了 94%,达到 14 NTU,固体含量可以忽略不计,对井眼清理工具的检查表明,井眼清理和管表面水润湿非常有效。

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ESG时代的解决方案

自推出以来,TADS 已多次被证明在驱替和井眼清理方面非常有效。该系统满足所有关键标准:成本效益高、环境友好、能有效去除固体并使表面呈水润湿状态、能够承受井底升高的温度,并且可以配制足够稠密的配方以取代钻井中使用的较重的钻井液。极深的井。

关于结果,TADS 是针对每项工作量身定制的,因此它可以产生最佳结果。它的清理效果非常有效,井眼清理工具从孔中出来后看起来几乎是新的,它最大限度地减少了流体污染并减少了浪费,并减少了钻机时间和位移成本。同样重要的是,它对环境友好,这是一个主要优点,因为法规逐年变得越来越严格。最后,为了表彰 TADS 的卓越表现,TADS 荣获 2022 年 Hart Energy 工程创新特别优异奖。

应用 TADS 后清洁工具的示例
应用 TADS 后从孔中拔出的异常清洁的井眼工具显示了该系统在清理方面的有效性。

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TETRA 技术徽标

原文链接/jpt
Oilfield chemistry

Exceptional Displacement and Wellbore Cleanup

Case studies prove the benefits of choosing a greener, more efficient, and more powerful displacement system

Sponsored By TETRA Technologies Logo
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The 2010 Macondo oil spill marked a major turning point for the oil and gas industry. Whatever one thinks of the incident’s causes, the stringent safety and environmental regulations that came afterward fundamentally altered how offshore operations are conducted. But even before the incident, the challenges were already stacking up as operations moved into deeper waters with deeper, more deviated wells, higher pressures and temperatures, and the growing use of non-aqueous drilling fluids. All these factors have a determinative bearing on the system used to displace the drilling fluid and clean out the wellbore.

Displacement Before and After

Ideally, a displacement operation should displace the solids-laden drilling fluid with minimal fluid interface, remove all the residual solids, and leave the surfaces water-wet for an optimal completion phase. The presence of solids during the completion phase can cause crevice corrosion and hydrogen-sulfide stress cracking of metal tubulars, as well as damage the permeability and porosity of the geological formation, and that would negatively impact productivity from the reservoir.

Prior to Macondo, displacements were usually indirect, underbalanced, and quite slow to ensure a thorough cleanout. An indirect displacement entails the use of an intermediary fluid between the drilling and completion fluids. Most offshore operations entailed the use of enormous volumes of seawater pumped into the wellbore at pressures below the hydrostatic pressure of the formation (underbalanced) and then often simply discharged into the ocean. This technique is effective at providing a very clean, solids-free wellbore that also lessens the time and costs associated with using spacers and filtration, but it has some serious drawbacks. First, it’s not ideal from an environmental standpoint. Second, the use of an intermediary fluid adds time to the operation. Third, underbalanced pressures carry the potential for reservoir pressure to overwhelm the wellbore, leading to kicks and even a blowout, which of course pose serious safety and environmental risks.

The post-Macondo regulations said that operators had to maintain two barriers at all times, every barrel of fluid coming out of the well had to be accounted for, and any discharge had to be more environmentally benign than before. As a result, most operators switched to balanced or overbalanced displacements that were direct, without an intermediary fluid like seawater, but still conducted them slowly. This technique proved to be far from ideal, though, with unsustainably high volumes of fluid interface, in some cases upward of several thousand barrels of fluid requiring replacement, and levels of remaining solids so high that one would be hard-pressed to call the operation ‘wellbore cleanout’.

Most displacement systems consist of spacers formulated with surfactants—surface-active agents that reduce surface tension to captures solids and wet tubing surfaces—or both solvents and surfactants. The problem with systems containing solvents, which are usually petroleum-derived, is that they don’t work well with water-based fluids. The problem with surfactant-only systems is that they aren’t so good at cleaning away many synthetic-based muds, like those formulated with ester-isomerized olefin.

Innovating a New Kind of Displacement System

Confronted with a seemingly insurmountable problem, the industry really needed to totally rethink the chemistry and mechanics of offshore displacement, but it was a tall order. Any new solution would have to meet several demanding criteria with regard to safety, efficacy, regulations, and economics—namely, it would have to be:

  • cost-efficient;
  • environmentally friendly;
  • powerful in removing solids;
  • effective at leaving surfaces water-wet;
  • capable of performing at high bottomhole temperatures; and
  • dense enough to displace the denser non-aqueous drilling fluids used in ever-deeper wells.

Always eager to tackle a new challenge, scientists of the TETRA Innovation Group set about developing a solution and came up with the TETRA Advanced Displacement System or TADS, a 3-phase clear-brine solution designed for optimal wellbore cleanout. Engineered for use in the direct or indirect displacement of water-based, oil-based, and synthetic-based drilling muds, the system is highly effective at removing solids and rendering tubular surfaces water-wet for the completion phase.

But TADS is not a static, one-size-fits-all technology. It undergoes continuous improvement and is customized for each application. Based on wellbore conditions as well as the types of drilling and completion fluids the operator is using, TADS is composed of a tailored blend of low- or high-density halide brines and TETRAClean 900-series chemicals.

TADS Case Study No. 1

An operator in the Gulf of Mexico set out to temporarily abandon a deepwater well for later completion without the need for additional circulation or filtration. Water depth was about 2,000 feet and well depth 26,000 feet, with bottomhole temperature at 260°F. The first phase was a ‘dirty’ displacement using a custom-formulated high-density, solids-free, corrosion-inhibiting suspension fluid compatible with the Q125-alloy casing to displace the 16.5 lb/gal solids-laden synthetic-based mud that had been in the well for more than five years. The second phase was undertaken 10 months later and entailed the application of a high-density, solids-free TADS formulated with calcium bromide and zinc bromide.

Although TETRA engineers were confident the displacement and cleanout would be more than satisfactory, the operation actually exceeded expectations, greatly reducing the number of wellbore cleanout strings both to suspend the well and later to initiate the completion phase. The TETRA solutions ultimately saved the operator $5.4 million, provided a more efficient temporary abandonment, and yielded an ideal preparation for the completion phase.

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TADS Case Study No. 2

An operator in the Gulf of Mexico used TADS in a subsea well in 4,400 feet of water to displace a 14.4 lb/gal isomerized olefin-based mud with a 13.9 lb/gal calcium chloride and calcium bromide completion fluid. TADS removed all the mud and residual solids from the wellbore and riser, returning the completion fluid to the surface with only 75 barrels of contaminated fluid interface. By contrast, before TADS was applied, contaminated fluid returns typically ranged from 700 to 800 barrels. TADS reduced solids loading on the diatomaceous-earth filter press, enabling longer filtration cycles and lessening cleanup time. Turbidity was reduced 94% to 14 NTUs with negligible solids, and examination of the wellbore cleanup tools showed very effective hole-cleaning and water-wetting of tubular surfaces.

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A Solution for the ESG Era

Since its introduction, TADS has repeatedly proved to be exceptionally effective at displacement and wellbore cleanout. The system meets all the key criteria: it’s cost-efficient, environmentally friendly, effective at removing solids and rendering surfaces water-wet, capable of withstanding elevated bottomhole temperatures, and can be formulated dense enough to displace the weightier drilling fluids used in extremely deep wells.

Regarding outcomes, TADS is tailored to each job so it produces the best results possible. It’s so effective at cleanout that wellbore cleanout tools come out of the hole looking practically new, it minimizes fluid contamination and reduces waste, and it cuts rig time and displacement costs. Crucially, too, is that it’s environmentally friendly, a major benefit as regulations continue to grow more and more restrictive with each passing year. Finally, in recognition of its excellence, TADS is a 2022 winner of a Hart Energy Special Meritorious Award for Engineering Innovation.

Examples of clean tools after applying TADS
Exceptionally clean wellbore tools pulled out of the hole after the application of TADS show just how effective at cleanout the system is.

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