新型 EOR 工艺可防止页岩油未来枯竭

Shale Ingenuity 的 SuperEOR 已经过现场测试并取得了积极的成果,有望解决产量下降的问题。

运营商正在寻找从生产井中开采更多石油和天然气的方法,但他们需要证据证明新技术可以胜过传统的 EOR 解决方案。(来源:Shutterstock)

非常规开发的目标是从油藏中开采尽可能多的页岩油和气,但即使采用最先进的 EOR 解决方案,仍有很大一部分仍留在地下。

根据美国能源部化石能源和碳管理办公室的报告,“即使在最好的情况下,初级、二级和三级(增强型)技术最终也只能回收30%到60%的原始石油”,而大量的碳氢化合物则无法生产。

运营商正在寻找从生产井中提取更多石油和天然气的方法,但他们需要证据证明新技术可以胜过传统的 EOR 解决方案。

Shale Ingenuity 的 SuperEOR 已在现场测试中取得了积极成果,可能是解决采油难题的答案之一。与吞吐式注油类似,该解决方案涉及将溶剂注入油藏,溶剂膨胀成气体,将石油从岩石中驱出。

Shale Ingenuity 首席执行官罗伯特·唐尼 (Robert Downey) 向E&P介绍了这项技术。“我们使用的是一种液态烃溶剂溶液,可将其泵入页岩地层,”唐尼说。“当您将 [溶剂] 泵入地层时,它在 7 [PSI] 或 8 PSI 左右的低压下与石油混合,地层会将其加热,但一旦打开油井让其流动,溶剂就会爆发成气体,并将石油以爆炸性的方式从岩石中推向井筒。”

唐尼表示,与主要的采油方法相比,超级EOR可提供更高的采油率,并将生产成本降低约50%。

“显然,现在有很多枯竭的页岩井,人们正在寻找方法来实现这一目标,但使用天然气或二氧化碳的效果并不好,即使没有所有的压裂问题,”唐尼说。

SuperEOR 的井底压力比天然气或二氧化碳要低,因为溶剂在低得多的压力下就能与地层油混合。由于其粘度大得多,因此也不太可能进入邻井的裂缝中。

回收的溶剂由专门的溶剂回收装置收集,可显著提高石油采收率。据 Downey 介绍,该公司的专有溶剂不仅比传统方法提高了 500% 的产量,而且还可以从岩石中回收并重新使用。

工作原理

“将天然气注入这些页岩时,最大的问题是,当压力达到一定水平时,页岩中的天然裂缝就会开始张开。然后,天然气就会进入页岩裂缝,绕过基质。它不会进入基质并与石油混合,因此最终会将天然气推向邻井,无法获得良好的石油采收率,”唐尼说。

Shale Ingenuity 的解决方案则有所不同。“我们不会遇到这个问题,因为当你注入液体时,你不必达到这么高的井底压力,你不会激活那些裂缝,”他解释道。“液体会直接进入地层的页岩油中,然后你再将其冲洗出来。”

唐尼表示,这种闭环系统最大限度地减少了对环境的影响,并有可能将石油生产产生的温室气体排放减少高达 75%。

“到达地面后,生产物进入储罐,气体进入气体收集管线,溶剂以液体形式储存在地面,然后用三缸泵重新注入。这都是闭环的;因此对环境的影响要小得多,”唐尼说。“事实上,你甚至可以使用溶剂回收装置,并在那里做一些额外的事情,以进一步减少已经有限的空气排放量。”

随着项目规模的扩大,效率也会提高。与天然气处理厂类似,大规模运营具有高度可扩展性。随着工厂规模的扩大,每 1,000 立方英尺的成本会大幅下降。

Downey 表示,在石油生产中使用 SuperEOR 的成本约为每桶 17 美元,比其他 EOR 方法便宜得多。“从历史上看,每桶的高成本以及与天然气控制相关的挑战阻碍了天然气和二氧化碳吞吐页岩油 EOR 项目的成功

Downey 告诉E&P: “如果你想做一个包含 60 口井的项目,那么其经济效益将优于包含 10 口井的项目。”运营商可能在六到七个月后就能收回 10 口井的项目,但对于使用 SuperEOR 的包含 60 口井的项目,“你将获得七到十倍的投资回报,并在六到七个月内获得回报,”他说。

测试解决方案

新技术已在多个页岩气田进行了建模和测试,包括尤蒂卡页岩气田和鹰福特页岩气田以及粉河盆地。

在 Eagle Ford 进行的现场测试证明了该解决方案的有效性。据 Downey 称,使用专有溶剂使采油率提高了 44%,产量在短短 10 个月内从 13 桶/天提高到 390 桶/天。Downey 发现,使用传统采油方法取得的最接近的结果是 EOG 计划,该计划实现了 35% 的采油率,但仅用了五年时间。他说,其他 EOR 解决方案甚至无法达到这个门槛。

主题变奏

Shale Ingenuity 还开发了一项名为 UltraEOR 的技术,该技术结合了名为 Cycle Stim 的技术,利用循环水力压裂在井筒中产生大量小剪切裂缝。该过程增加了溶剂接触的表面积,Downey 表示,他预计该解决方案将使早期产品的采油率翻一番。Downey 表示,尽管尚未进行现场测试,但该技术有可能将采油率提高 1,000%。

Downey 解释道,该解决方案用途广泛,而且成本低廉:“循环增产适用于垂直井、水平井、常规井、非常规井、石油、天然气、低渗透、高渗透、旧井和新井。它的成本约为典型压裂作业成本的 20% 到 50%。”

唐尼说,该过程使用的液体和沙子更少,不需要化学品,并且需要现场部署的人员也更少。

Downey 表示,由于 Cycle Stim 的复杂性以及人们更倾向于使用传统水力压裂方法,该行业对此的采用一直进展缓慢,但他乐观地认为,该技术成本较低且对环境的影响较小,将成为在现场进行测试的有力理由。他相信,结果将导致广泛使用。

变革的驱动力

随着石油和天然气行业努力应对页岩储量减少的现实,创新技术的出现可能会对采收率和经济性产生重大影响。这些先进的开采方法不仅有望使老化油井焕发活力,而且还能提供更可持续、更经济高效的增产解决方案。尽管行业惯性可能会在短期内减缓广泛采用,但潜在好处(从显著提高石油采收率到显著改善环境)是变革的驱动力。

EOR 回收率比较
该图表显示了 Eagle Ford 的 SuperEOR 项目与德克萨斯州所有其他天然气吞吐 EOR 项目的结果比较。(来源:Shale Ingenuity)
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Novel EOR Process Could Save Shale from a Dry Future

Shale Ingenuity’s SuperEOR, which has been field tested with positive results, looks to remedy the problem of production declines.

Operators are looking for ways to extract more oil and gas from producing wells, but they need evidence that new technologies can outperform traditional EOR solutions. (Source: Shutterstock)

The objective of unconventional developments is to produce as much shale oil and gas as possible from a reservoir, but even with the most advanced EOR solutions, a large percentage remains in the ground.

According to a report by the U.S. Department of Energy’s Office of Fossil Energy and Carbon Management, “even under the best of circumstances, primary, secondary, and tertiary (enhanced) techniques can ultimately lead to recovery of 30 to 60 percent of the original oil in place,” which leaves a lot of hydrocarbons unproduced.

Operators are looking for ways to extract more oil and gas from producing wells, but they need evidence that new technologies can outperform traditional EOR solutions.

Shale Ingenuity’s SuperEOR, which has been field tested with positive results, could be one answer to the recovery conundrum. Similar to huff and puff injection, this solution involves injecting a solvent into the reservoir, which expands into a gas to drive oil out of the rock.

Robert Downey, CEO of Shale Ingenuity, explained the technology to E&P. “What we use is a liquid hydrocarbon solvent solution that you pump into a shale formation,” Downey said. “When you pump [the solvent] into the formation, it becomes miscible in the oil at low pressure of around 7 [PSI] or 8 PSI and the formation heats it up, but the minute you open that well to flow, that solvent wants to explode into a gas and push that oil very explosively out of the rock and up the wellbore.”

SuperEOR offers higher recovery rates and reduces production costs by about 50% compared to primary recovery methods, Downey said.

“Obviously, there are a lot of depleted shale wells out there now, and people are looking for a way to make this work, but using natural gas or CO2 just doesn’t work very well, even without having all the fracturing issues,” Downey said.

SuperEOR works at lower bottomhole pressures than natural gas or CO2 because the solvent is miscible in the formation oil at much lower pressure. Because it has much greater viscosity, it is also much less likely to move into fractures in offset wells.

The recovered solvent, which is gathered by a special solvent recovery unit, significantly improves oil recovery. According to Downey, the company’s proprietary solvent not only improves production up to 500% more than traditional methods, but also can be recovered from the rock and reused.

How it works

“The big problem when injecting natural gas into these shales is that you get to a certain bottom of pressure and the natural fractures that are in the shale start opening up. Then the gas wants to move into the shale fractures and bypass the matrix. It doesn’t go into the matrix and become miscible in the oil, so you end up pushing the gas to an offset well, and you don’t get good oil recovery,” Downey said.

Shale Ingenuity’s solution works differently. “We don’t have that problem because when you inject the liquid and you don’t have to go to this high bottomhole pressure, you don’t activate those fractures,” he explained. “The liquid goes right into the shale oil in the formation and then you flush it back out.”

This closed-loop system minimizes environmental impact and has the potential to cut greenhouse-gas emissions from oil production by up to 75%, Downey said.

“At the surface, your production goes to the tanks, your gas goes to your gas gathering line, the solvent gets stored as a liquid on the surface, and then you reinject it with a triplex pump. It’s all closed loop; so the environmental impact is much lower,” Downey said. “In fact, you could even take your solvent recovery unit and do some additional things on there to further reduce the already limited air emissions.”

As project size increases, efficiency improves. Similar to a gas processing plant, a large-scale operation is highly scalable. The cost per 1,000 cf decreases substantially as plant size grows.

The cost of using SuperEOR in oil production is approximately $17/bbl, making it much less expensive than other EOR methods, Downey said. “Historically, the high cost per barrel and challenges related to gas containment have hindered the success of natural gas and CO2 huff and puff shale oil EOR projects.”

“If you wanted to do a project of 60 wells, the economics for that are going to be better than a project with 10 wells,” Downey told E&P. Operators might break even on a 10-well project after six or seven months, but with a 60-well project using SuperEOR, “you’re looking at a return on investment of seven to 10 times your money and payouts in six to seven months,” he said.

Putting the solution to the test

The new technology has been modeled and tested across various shale plays, including the Utica and Eagle Ford shales, and the Powder River Basin.

A field test in the Eagle Ford demonstrated the efficacy of the solution. According to Downey, using the proprietary solvent enabled a 44% increase in oil recovery and a rise in production from 13 bbl/d to 390 bbl/d in only 10 months. The closest results achieved using traditional recovery methods Downey found was a program for EOG that achieved 35% recovery, but only after five years. Other EOR solutions were unable to reach even that threshold, he said.

Variations on a theme

Shale Ingenuity also developed a technology called UltraEOR that incorporates a technique called Cycle Stim, which uses cyclic hydraulic fracturing to create numerous small shear fractures in the wellbore. This process increases the surface area available for solvent contact, and Downey said he expects this solution to double the oil recovery rates achieved by the earlier product. Although not yet field-tested, the technique has the potential to increase oil recovery by 1,000%, Downey said.

The solution is both versatile and cost effective, Downey explained: “Cyclic stimulation will work on vertical wells, horizontal wells, conventional wells, unconventional wells, oil, gas, low perm, high perm, old wells and new wells. It’s about 20% to 50% of the cost of a typical frack job.”

The process uses less fluid and sand, requires no chemicals, and needs fewer people on location to deploy it, Downey said.

The industry has been slow to adopt Cycle Stim due to its complexity and the preference for traditional fracking methods, Downey said, but he is optimistic that the technique’s lower cost and reduced environmental footprint will be compelling reasons to test it in the field. He believes the results will lead to widespread use.

Drivers for change

As the oil and gas industry grapples with the realities of diminishing shale reserves, the emergence of innovative technologies could significantly impact recovery and economics. Advanced extraction methods like these not only promise to rejuvenate aging wells but also offer a more sustainable and cost-effective solution for enhancing production. Although industry inertia may slow widespread adoption in the near term, the potential benefits—ranging from significant increases in oil recovery to substantial environmental improvements—are drivers for change.

EOR recovery comparison
This graph shows a comparison between the results of a SuperEOR project in the Eagle Ford and all other natural gas huff and puff EOR projects in Texas. (Source: Shale Ingenuity)
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