2023年5月
特征

EOR/IOR技术:DJ盆地先进的页岩油EOR方法

与天然气或二氧化碳 EOR 相比,两种创新的页岩油 EOR 工艺更加简单,资本支出和运营成本更低。在作业过程中使用先进的成分油藏模拟模型,以确保最大的石油采收率。
Robert Downey / Shale Ingenuity Jim Erdle 博士 / 计算机建模小组 Kiran Venepalli / 计算机建模小组

美国水平井页岩油开发于2006年左右开始,首先在美国北部的威利斯顿盆地开发,2007年扩展到伊格尔福特盆地,此后又扩展到二叠纪盆地、DJ盆地、粉河盆地、 Uinta、圣胡安和 SCOOP/STACK。如今,页岩油水平生产井超过 94,000 口,每天为我国供应 7 MMbps。  

这些井中约有一半位于德克萨斯州的二叠纪和伊格尔福德页岩区。所有这些水平页岩油井的产量都具有初始产量高、最初几年急剧下降的特点,随后下降幅度较小,达到经济极限。经济生产可能会持续 8 年到 15 年以上,具体取决于盆地和完井特征以及商品价格。 

一家行业数据分析公司按首次产出年份和各州的油井数量计算了水平页岩油井的日产量,如图 1 所示 。在 DJ 盆地,页岩油开发始于垂直井,主要集中在 Ft. 盆地。Hays-Codell 页岩石灰岩和砂岩序列于 1990 年代开始,并于 2009 年过渡到在 Codell 和 Niobrara 页岩完成的水平井。  

图1.按首次生产年份划分的水平页岩油日产油量和按州划分的水平页岩油井数量。 (来源诺维实验室)
图1.按首次生产年份划分的水平页岩油日产油量和按州划分的水平页岩油井数量。(来源诺维实验室)

如今,约有 9,025 个 Niobrara 和 Codell 页岩井正在生产,其中约 8,625 个位于科罗拉多州东北部的瓦滕伯格油田地区,约 400 个位于怀俄明州东南部夏安附近。图 2显示了 Niobrara 和 Codell 水平页岩油井按首次生产年份划分的日产量以及按州划分的油井数量。 

图 2. Niobrara 和 Codell 页岩油水平井日产油量(按首次生产年份)和各州水平页岩油井数量。
图 2. Niobrara 和 Codell 页岩油水平井日产油量(按首次生产年份)和各州水平页岩油井数量。

Codell 是位于 J 砂上方的砂质页岩,厚度从 5 英尺到 50 多英尺不等。Niobrara 是一片厚厚的白垩层和泥灰岩层,在整个盆地中随处可见。该盆地最深的部分位于丹佛以北,开发主要集中在大型 Wattenberg 油田地区,该地区于 1970 年在 J-Sand 深处发现了天然气。EIA 列出了 Wattenberg 油田,面积约 2,000 英里图2为科罗拉多州杰佛逊县北部至韦尔德县东南部的美国第九大气田,DJ盆地产层段地层柱如图3所示。 

图3 DJ盆地地层柱。
图3 DJ盆地地层柱。

Niobrara 页岩是白垩岩和泥灰岩的叠层序列,总厚度从 300 英尺到 900 英尺以上。Niobrara 是 DJ 盆地页岩油开发的主要目标,其中一个单独完成的水平井白垩间隔。  

最初,水平井的钻完井横向长度为 4,000 至 5,000 英尺,但后来横向长度增加到 9,000 英尺以上。DJ 盆地的钻井条件简单且成本低廉,可实现单眼完井。随着操作人员尝试不同的流体类型和支撑剂,压裂增产措施随时间而变化,但最常见的压裂增产处理方法是滑溜水,支撑剂负载量为 0.5 至 1.0 ppg。同样,横向间距也有所不同,但通常为 300 至 600 英尺。Niobrara 厚的多白垩层段需要井堆积,具有不同的横向间距和不同的垂直偏移量,具体取决于岩石厚度和储层岩石特性。 

政治和流行病的挫折2018 年,科罗拉多州立法机构颁布了参议院第 181 号法案,该法案改变了科罗拉多州石油和天然气保护委员会 (COGCC) 的重点和组成,Niobrara 页岩的开发放缓。该法案通过后,科罗拉多州州长更换了 COGCC 董事会,新董事会开始制定一系列极大限制发展的新规则。  

由于 Covid-19,2020 年 3 月原油价格下跌也减缓了发展。2021年和2022年原油价格上涨改善了页岩油开发的经济效益;然而,长期的井许可时间和过多的井后退限制阻碍了持续开发。以每桶 60 美元的原油价格计算,Niobrara 页岩井的平均寿命约为 10 至 12 年。因此,预计目前正在生产的油井中一半以上可能会在未来五年内达到经济上有限的产量水平。 

EOR 限制 

提高石油采收率从未在全球范围内提供大量石油产量。根据国际能源署 2018 年的一项研究,“提高石油采收率发生了什么?”, “OR”在全球原油产量中的份额似乎一直稳定在 2% 左右。“EOR 开发不足的原因包括缺乏对石油稀缺的担忧,偏爱能产生快速回报的上游产业项目。此外,原因还包括政府政策激励、缺乏技能和技术/专业知识,以及提高采收率的高成本和风险。  

美国一些盆地(例如DJ盆地)的页岩油开发已接近成熟,并且如前所述,自2009年以来钻探的许多页岩油水平井已达到或已经枯竭。这些油井将不得不被堵塞或废弃,成本高昂,或者必须采取一些行动来增加石油产量。折射是一个考虑因素;然而,进行重复压裂的成本可能令人望而却步,即等于或大于完成后进行的裂缝增产处理。而且它们可能无法产生足够的产量来收回成本并产生有吸引力的投资回报率。  

页岩油提高采收率 (EOR) 尚处于起步阶段,已在 Eagle Ford 页岩的数百口井中实施。根据德克萨斯州铁路委员会(RRC)的数据,截至2022年中期,Eagle Ford地区共有36个获批的页岩油EOR项目,除1个项目外,所有项目均涉及天然气循环注入。已经或计划在二叠纪、威利斯顿盆地和 SCOP 等其他页岩盆地进行 13 次页岩油 EOR 测试,但成效有限。  

几乎所有这些 EOR 预测都涉及天然气的循环注入,通常称为吞吐 (HnP)。在其中几个 EOR 项目中,由于天然裂缝或裂缝增产处理而导致的井间连通限制了最大天然气注入压力,并导致石油采收率降低。对Niobrara页岩DJ盆地的富集天然气HnP进行了评价,预计EOR作业15年可增量采收率约13%。  

使用天然气或CO 2 的页岩EOR需要使用大型、专门设计的高压压缩机组,该压缩机组可以将大量气体或CO 2注入页岩储层,以达到超过最小混相压力(MMP)的压力。这些压缩机组成本高,交货周期长,而且在大多数情况下无法租赁。  

天然气通常从中游公司购买并运送到井场。二氧化碳普遍供应不足,需要专用的输送管道,且输送和材料成本较高。在相对较短的时间内高速注入和生产的循环性质可能难以在现场管理。天然气和CO 2 HnP的注入和生产周期可能需要数天甚至数月,具体取决于压缩能力和井眼配置。  

压缩燃料消耗约为喷射量的7%至8%。喷射周期中的所有这些成本(设备、喷射剂、燃料、维护以及由此产生的生产停机)使得许多项目不经济或仅具有边际经济性。迄今为止,这些页岩油 EOR 项目已由 16 家公司开发,其中大部分是大型独立生产商,他们拥有设计和实施这些项目所需的财务能力和技术专长。  

页岩 EOR 方法 

Shale Ingenuity发明并开发了两种创新的页岩油EOR方法,名为SuperEORUltraEOR它们涉及将特定成分的液体溶剂以高速率和短注入期(几天)注入页岩油储层,然后回流至特定的最小井眼压力。溶剂在地面设备中回收并重新注入,从而降低成本。原油产生的天然气继续流向中游设施进行液化天然气回收。溶剂回收效率高、成本低。UltraEOR 在 EOR 过程开始时增加了一个步骤,在井筒横向周围生成复杂的裂缝网络,从而增加溶剂与页岩基质的接触。 

特定成分或“调和的”液体溶剂以与天然气或CO 2显着不同的方式回收石油溶剂的溶解度或混溶压力很低;它立即降低原油和岩石基质之间的界面张力;降低油的粘度;它增加了对石油的相对渗透率;它向原油增加溶解气体压力,当压力降低时变成气体,膨胀并驱动石油通过页岩孔隙;并且还受益于其他力,例如平流和分子扩散通量。因此,它可以非常有效地从页岩油基质中采收石油,并且不需要高压注入。 

SuperEOR 和 UltraEOR 页岩油 EOR 工艺与任何其他 EOR 工艺一样,需要对页岩油储层和已完井的井有充分的了解。开发了油藏的成分油藏模拟模型以获得油藏的产量和压力历史匹配。与任何油藏模拟模型一样,可用数据越详细和准确,SuperEOR 和 UltraEOR 性能下的模型预测结果就越准确。页岩油储层的成分模拟模型表明,当调整溶剂成分时,采油率会得到优化,并且随着过程的继续,可能需要定期调整溶剂成分以获得最佳采油率。  

Shale Ingenuity拥有与天然气循环注入优化石油采收率相关的专利,并拥有与溶剂循环注入优化石油采收率相关的其他正在申请的专利。  

SuperEOR成分油藏模拟过程。为了说明DJ盆地Niobrara组SuperEOR和UltraEOR过程的页岩油提高采收率潜力,在Wattenberg油田中东北部地区选择了具有代表性的Niobrara水平页岩油生产井。  

所选井在Niobrara A层段完成,进行了4,000英尺横向和25级滑溜水压裂增产处理。在模拟时,该井已有5陆年的生产历史。完井、裸眼测井、PVT、生产和表面压力数据被用来开发成分模拟模型。PVT 数据用于开发模型所使用的调整状态方程,以跟踪油藏中的各个碳氢化合物成分以及 SuperEOR 和 UltraEOR 液体溶剂的注入和生产。该井生产历史见图4。 

图4 案例研究井的生产历史。
图4 案例研究井的生产历史。

利用来自模拟井附近一口井的 PVT 数据开发了九分量 EOS 模型。九种假组分是N 2 、CO 2 、CH 4 、C 2 H 6 、C 3 H 8 、C 4 、C 5 、C 6和C 7 + 。表 1显示了 EOS 的组成和所选参数。图 5a5b显示了恒定质量膨胀实验的实验数据与模拟数据匹配。图 6a6b显示了差异释放实验的实验数据与模拟数据匹配。 

表 1. 伪组件和选定的 EOS 参数。
表 1. 伪组件和选定的 EOS 参数。
图5a和5b。 恒定质量实验的实验数据与模拟数据匹配。
图5a和5b。恒定质量实验的实验数据与模拟数据匹配。
图6a和6b。 差异释放实验的实验数据与模拟数据匹配。
图6a和6b。差异释放实验的实验数据与模拟数据匹配。

利用组合的单孔隙度模型来匹配所选井的历史压力和产量。使用对称元素方法,模型由五个骨折阶段组成,占骨折刺激治疗阶段总数的 20%。然后将整个井的结果扩展到 25 个裂缝阶段。减少建模压裂阶段的数量可降低模型复杂性和模拟计算时间。  

建模的 Niobrara 油藏顶部深度为 6,700 英尺,产层厚度为 270 英尺。该模型有 10 层恒定网格厚度。水库温度为 190°F。初始储层压力为 4,000 psig。页岩基质绝对渗透率估计为 0.0001 md。水力压裂是简单的平面压裂,每个压裂阶段一个,半长为 225 英尺,压裂高度为 81 英尺。  

模型中使用对数间隔的局部细化网格块,以适应从低渗透性页岩基质到高渗透性支撑裂缝的大瞬态响应。使用自动化历史匹配工具完成了一次石油、天然气和水生产以及地面生产压力的历史匹配。调整参数包括基质渗透率、相对渗透率、孔隙度、水力裂缝几何形状、水力裂缝导流率和地层压缩性。  

贝叶斯概率历史匹配需要大约 500 次模拟运行才能实现可接受的历史匹配,并且历史匹配误差小于 1%。图 7a7d显示了历史匹配误差图以及石油产量、天然气产量、水产量和 BHP 的匹配。利用历史匹配模型来评估和优化通过 SuperEOR 溶剂 EOR 工艺预测的石油采收率。评估了几种方案,改变注入速率、注入压力、浸泡时间、回流速率、回流压力和溶剂注入剂成分。SuperEOR 预测运行了大约 13 年。没有对 SuperEOR 项目的 NPV 进行优化,因为这需要对此类项目进行一些其他假设,例如 SuperEOR 作业中的井数、溶剂成本和溶剂回收系统。  

图7a-7d。 历史产量和压力与历史匹配案例。
图7a-7d。历史产量和压力与历史匹配案例。

然而,提供了未优化的 SuperEOR 开发方案,假设一个八井项目由与建模井相同的完井组成。最大注入 BHP 假定为 3,900 psi。单井(五阶段)预测所选恒定成分溶剂溶液的产油量,最大注入量为 330 bpd,注入周期为 26 天,最大产量为 1,500 Mcfd,生产周期为 30 天,最小产量 BHP 750 psi,图 8。 该预测假设没有浸泡时间,因为其他模拟运行表明浸泡时间对石油采收率没有显着影响。 

图 8. SuperEOR 下的历史石油产量和原油产量提高。
图 8. SuperEOR 下的历史石油产量和原油产量提高。

五个模拟压裂阶段的累计石油产量,在没有假设经济限制的初级(压力消耗)生产下,以及经过 13 年的 SuperEOR 运行后,如图 9 中 的黑线所示。经过 5 年的 SuperEOR 运行,预计累计石油产量将达到 27,600 桶,即持续五年的初级石油生产后累计采收石油量的 146%。经过 13 年的 SuperEOR 运营,预计该井的累计石油产量将达到 47,658 桶,即 13 年持续初级石油生产后累计采收石油量的 172%。  

图 9. 累计原生油产量和 SuperEOR 提高产量。
图 9. 累计原生油产量和 SuperEOR 提高产量。

假设经济极限产量为 10 桶/日,整个油井的原生欧元预计为 78,600 桶石油。因此,SuperEOR作业开始时的油井产量在达到计算的经济极限后的一年内达到了计算的经济极限(图9)。因此,实施SuperEOR可以将油井寿命延长10年以上,并将费用从78,600欧元增加到石油产量 238,290 桶,增加 300%。 

图 10. 不同最大注入 BHP 下的累积初级油产量和 SuperEOR。
图 10. 不同最大注入 BHP 下的累积初级油产量和 SuperEOR。

对最大井底注入压力进行了敏感性分析,以评估如果 SuperEOR 工艺在较低的最大注入 BHP 下进行,对石油采收率的影响。这是一个特别重要的考虑因素,因为其他页岩油盆地的几个天然气 HnP EOR 项目已经显示,一旦 BHP 在注入期间达到一定的高水平,就会通过天然或水力增产处理裂缝实现井间连通。图 10显示了最大注入 BHP 为 3,500、3,000、2,500 和 2,000 psi 时初级和超级 EOR 下的累积石油产量。SuperEOR运行13年后,采收率分别降低8.3%、13.3%、18.9%和24.2%。模拟模型还显示了通过该过程回收石油的油藏区域。图 11显示了 SuperEOR 工艺运行 13 年之后油藏中层含油饱和度的俯视图,表明石油采收率几乎完全集中在水力裂缝之间的网格块上。  

图 11 中区块模拟网格顶视图,显示 13 年 SuperEOR 后的含油饱和度。
图 11 中区块模拟网格顶视图,显示 13 年 SuperEOR 后的含油饱和度。

增值。 与天然气或CO 2 HnP EOR 相比,该工艺具有多种优势。最值得注意的是,它可以在更短的时间内采收更多的石油。回收成本也低得多,因为溶剂注入剂比天然气或CO 2成本更低,并且只需购买一次;溶剂回收率几乎100%,回收成本低。周期时间短,因此油井停机时间短,有效日产油率更高。可以设计多井工艺来实现交错的注入和生产计划,以提供接近恒定的回流和注入速率。不需要人工举升设备,因为井的流速足以有效地将石油从井眼中举升。  

对一个八井项目进行了未经优化的 SuperEOR 项目经济分析,假设每口井的完成横向长度为 9,000 英尺。关键项目假设和结果以及该项目的预测石油产量如图12 所示。按净价 83 美元/桶计算,并且不会为可能通过 SuperEOR 生产的任何额外天然气提供经济利益,无风险,未经优化的流程应该会产生有吸引力的资本支出投资回报率。  

图 12. SuperEOR 项目假设和经济结果。
图 12. SuperEOR 项目假设和经济结果。

SuperEOR 过程的建模已在美国大部分页岩区中完成,SPE 206186 和 SPE 208312 描述了 Midland 盆地 Wolfcamp D 和 Eagle Ford 页岩中的类似建模工作。SuperEOR 工艺的岩心测试已在 Eagle Ford 和 Midland 盆地 Wolfcamp B 页岩上进行,结果表明,经过 6 个注入和生产周期后,石油采收率约为 90%。SPE 209348 中介绍了这些岩心测试和结果。SuperEOR 工艺也在其他页岩油盆地进行了成功的现场测试。 

UltraEOR 过程的成分油藏模拟。使用相同的程序对UltraEOR过程进行了建模,并在主要完井平面阶段裂缝之间的区域添加了复杂的裂缝网络。CMG GEM 成分油藏模拟模型提供了能够描绘复杂裂缝网络的功能。在本例中,我们假设生成裂缝宽度为 0.001 英尺、有效渗透率为 17.5 毫达西的复杂裂缝网络。平面裂缝(SuperEOR)和复杂裂缝(UltraEOR)五阶段模型的比较如图13 所示。   

图 13 中间区块 SuperEOR 和 UltraEOR 模拟网格俯视图。
图 13 中间区块 SuperEOR 和 UltraEOR 模拟网格俯视图。

在主要完井平面裂缝阶段之间的区域中产生复杂的裂缝可以通过识别页岩应力方向改变的专有过程来实现。这种裂缝生成过程已在世界各地的许多油井中得到成功证明和演示。 

图 14. 初次 SuperEOR 和 UltraEOR 下的预测累计采油率。
图 14. 初次 SuperEOR 和 UltraEOR 下的预测累计采油率。

这种复杂的裂缝网络有效地使五个主要平面裂缝之间的区域的裂缝表面积加倍。因此,累计采油率约为 SuperEOR 采收率的两倍。图 14显示了在一次采收率、SuperEOR 采收率和 UltraEOR 采收率下建模的五个压裂阶段的累积石油与时间的关系。如图所示,经过 13 年的 EOR 运行,SuperEOR 可以将石油采收率提高到一次采收率的 1.8 倍,而 UltraEOR 可以实现的石油采收率是一次采收率的 3.7 倍。   

图 15. UltraEOR 项目假设和经济结果。
图 15. UltraEOR 项目假设和经济结果。

对一个八井项目进行了未经优化的 UltraEOR 项目经济分析,假设每口井的完成横向长度为 9,000 英尺。项目关键假设和结果以及预测石油产量如图15 所示。 

结论 

两种新型页岩油 EOR 工艺 SuperEOR 和 UltraEOR 的石油采收率应远远优于天然气或 CO 2 HnP EOR,而且成本要低得多。SuperEOR 和 UltraEOR 具有几个重要的操作优势:更简单、资本和运营成本更低。这些工艺需要严格的成分油藏模拟模型来设计,并在 SuperEOR 和 UltraEOR 操作中使用,以便在工艺投入现场操作时进行优化,以实现最大石油采收率。  

致谢 

Shale Ingenuity 感谢与计算机建模小组的合作以及其先进的成分油藏模拟软件在 SuperEOR 和 UltraEOR 页岩油 EOR 工艺开发中的应用。此外,感谢 Novi Labs 访问其油井数据库,从而能够生成 Niobrara 产量和油井图表。本文摘自 SPE 论文 213082-MS,“DJ 盆地先进、优越的页岩油 EOR 方法”,于 4 月 17 日至 19 日在俄克拉荷马城会议中心举行的 SPE 俄克拉荷马城石油和天然气研讨会上发表,2023。   

关于作者
罗伯特·唐尼
页岩的独创性
罗伯特·唐尼 (Robert Downey) 在上游石油天然气和能源技术开发领域拥有 30 多年的经验。在加入 Shale Ingenuity 之前,他曾在 Amoco、Encana、Synthetic Genomics、Ciris Energy 和 Gunnison Energy 担任过多个行政和技术专业职位。他在煤炭生物转化、油藏模拟建模、油藏工程以及钻井和完井方面获得了多项专利。唐尼先生获得了科罗拉多矿业学院石油工程学士学位。
吉姆·埃尔德尔博士
计算机建模小组
Jim Erdle 博士拥有 49 年的行业经验,主要从事上游服务和软件领域油藏和生产工程相关职位。在他的职业生涯早期,他参与了试井设计、监测和解释技术方面的一些行业领先进展,包括密闭室和表面压力读数 (SPRO)、钻杆测试以及通过 NODAL 分析提高产量。Erdle 博士还致力于增产处理设计、监测技术和生产监测软件。在工作 25 年后,他最近从计算机建模团队退休,最近担任公司美国和拉丁美洲软件销售和支持副总裁。他拥有宾夕法尼亚州立大学石油工程学士学位(1971 年)和博士学位(1974 年)
基兰·维内帕利
计算机建模小组
Kiran Venepalli 是计算机建模小组的产品经理,专门从事油藏建模和模拟。在此职位上,他在根据能源转型目标确定 CMG 解决方案的方向和发展方面发挥着关键作用。他还负责监督非常规解决方案。这需要勘探和开发非常规石油和天然气资源,例如页岩气和致密油,重点是利用技术进步来改进开采技术并尽量减少对环境的影响。Venepalli先生拥有12年的行业经验,拥有阿拉斯加大学费尔班克斯分校石油工程硕士学位和印度JNTU学士学位。
相关文章
原文链接/worldoil
May 2023
Features

EOR/IOR technology: Advanced shale oil EOR methods for the DJ basin

Two innovative shale oil EOR processes offer greater simplicity, and lower capital expenditure and operating costs, compared to natural gas or CO2 EOR. Advanced compositional reservoir simulation modeling is used during operation to ensure maximum oil recovery.
Robert Downey / Shale Ingenuity Dr. Jim Erdle / The Computer Modeling Group Kiran Venepalli / The Computer Modeling Group

Horizontal well shale oil development in the U.S. began in earnest around 2006, first in the Williston basin of the northern U.S. Development expanded to the Eagle Ford in 2007 and has since expanded to several more basins, such as the Permian, DJ, Powder River, Uinta, San Juan and SCOOP/STACK. Today, there are more than 94,000 horizontal shale oil producing wells contributing 7 MMbpd to our nation’s supply.  

About half of these wells are located in the Permian and Eagle Ford shale plays of Texas. Production from all these horizontal shale oil wells is characterized by high initial rates and steep declines over the first few years, followed by shallower declines to economic limit. Economic production may continue from eight to more than 15 years, depending upon the basin and well completion characteristics and commodity prices. 

An industry data analytics firm has calculated the horizontal shale oil well daily production by year of first output and the number of wells by state, Fig. 1. In the DJ basin, shale oil development began with vertical wells focused on the Ft. Hays-Codell shaley limestone and sandstone sequence in the 1990s and transitioned to horizontal wells completed in the Codell and Niobrara shale in 2009.  

Fig. 1. Horizontal shale oil daily oil production by year of first production and number of horizontal shale oil wells by state. (Source Novi Labs)
Fig. 1. Horizontal shale oil daily oil production by year of first production and number of horizontal shale oil wells by state. (Source Novi Labs)

Today, there are approximately 9,025 Niobrara and Codell shale wells producing, with about 8,625 in the Wattenberg field area of northeastern Colorado and about 400 in southeastern Wyoming near Cheyenne. Figure 2 shows the Niobrara and Codell horizontal shale oil well daily production by year of first production and the number of wells by state. 

Fig. 2.  Horizontal Niobrara and Codell shale oil well daily oil production by year of first production and number of horizontal shale oil wells by state.
Fig. 2. Horizontal Niobrara and Codell shale oil well daily oil production by year of first production and number of horizontal shale oil wells by state.

The Codell is a sandy shale situated above the J sand, with a thickness ranging from 5 ft to more than 50 ft. The Niobrara is a thick interval of chalks and marlstones that is ubiquitous across the entire basin. The deepest portion of the basin is north of Denver, and development has been predominantly in the area of the large Wattenberg field, where natural gas in the deeper J-Sand was discovered in 1970. EIA lists the Wattenberg—which covers about 2,000 mi2, from northern Jefferson County to southeastern Weld County, Colorado—as the ninth-largest gas field in the U.S. A stratigraphic column of the productive intervals in the DJ basin is shown in Fig. 3. 

Fig. 3. DJ basin stratigraphic column.
Fig. 3. DJ basin stratigraphic column.

The Niobrara shale is a stacked sequence of chalkstones and marlstones, with a gross thickness ranging from 300 ft to more than 900 ft. The Niobrara is the primary target of shale oil development in the DJ basin, with horizontal wells completed individually in one of the chalky intervals.  

Initially, horizontal wells were drilled and completed with lateral lengths of 4,000 to 5,000 ft, but lateral lengths have since increased to more than 9,000 ft. Drilling conditions in the DJ basin are simple and low-cost, enabling monobore completions. Fracture stimulations have varied over time, as operators experimented with varying fluid types and proppants, but the most common fracture stimulation treatment method is slickwater with proppant loading of 0.5 to 1.0 ppg. Lateral spacing, likewise, varies but is generally 300 to 600 ft. The thick, multi-chalk intervals of the Niobrara require well stacking, with varying lateral spacing and varying vertical offsets, as dictated by rock thickness and reservoir rock properties. 

Political and pandemic setbacks. Development of the Niobrara shale slowed after 2018, when the Colorado legislature enacted Senate Bill 181, which changed the Colorado Oil and Gas Conservation Commission’s (COGCC) focus and makeup. Following its passage, the Colorado governor replaced the COGCC board of directors, and the new board began enacting a series of new rules that greatly restricted development.  

The drop in crude prices in March 2020, due to Covid-19, also slowed development. Higher crude prices in 2021 and 2022 have improved economics for shale oil development; however, continued development is hampered by long well permitting times and excessive well setback restrictions. Niobrara shale wells have an average life of about 10 to 12 years at a $60/bbl crude price. Therefore, it is anticipated that more than half of the wells now on production will likely reach their economically limited production level within the next five years. 

EOR LIMITATIONS 

Enhanced oil recovery has never provided a significant amount of oil production worldwide. According to an International Energy Agency 2018 study, Whatever happened to enhanced oil recovery?, “EOR’s share of global crude oil production seems to have remained broadly stable over time at around 2%.” Reasons for lack of EOR development include lack of concerns over oil scarcity and preference for upstream industry projects that can generate fast returns. Also, reasons include governmental policy incentives, lack of skills and technologies/expertise, in addition to high costs and risks of EOR.  

Shale oil development in some U.S. basins, such as the DJ basin, is reaching maturity and as mentioned earlier, many horizontal shale oil wells drilled since 2009 are reaching or have reached depletion. These wells will have to be plugged or abandoned at significant cost, or some action must be taken to increase oil production. Refracs are a consideration; however, the costs of conducting refracs can be prohibitive, i.e., equal to or greater than the fracture stimulation treatment conducted upon completion. And they may not yield sufficient production to recover costs and generate an attractive ROI.  

Shale oil enhanced oil recovery (EOR) is in its infancy and has been implemented in a few hundred wells in the Eagle Ford shale. According to Railroad Commission of Texas (RRC) data, as of mid-2022, there are 36 permitted shale oil EOR projects in the Eagle Ford, all of which, except for one, involve the cyclic injection of natural gas. Thirteen shale oil EOR tests have been conducted, or are planned, in other shale basins, such as the Permian, the Williston basin and the SCOOP, with limited success.  

Nearly all of these EOR projections have involved the cyclic injection of natural gas, often referred to as huff-and-puff (HnP). In several of these EOR projects, interwell communication, due to natural fractures or fracture stimulation treatments, has limited maximum natural gas injection pressures and resulted in reduced oil recoveries. Enriched natural gas HnP in the DJ basin of the Niobrara shale was evaluated, and an incremental oil recovery of about 13% in 15 years of EOR operation was predicted.  

Shale EOR, using natural gas or CO2, requires the use of large, specially designed high-pressure compressor sets that can inject very large volumes of gas or CO2 into the shale reservoir to reach pressures exceeding the minimum miscibility pressure (MMP). These compressor sets are hig- cost, and they require long delivery lead times and, in most cases, cannot be rented.  

Natural gas is usually purchased from a midstream company and delivered to the wellsite. Carbon dioxide is generally in short supply and requires a dedicated delivery pipeline and higher costs for transmission and materials. The cyclic nature of injection and production at high rates, and for relatively short periods of time, can be difficult to manage in the field. Injection and production cycles for natural gas and CO2 HnP may be many days or even months, depending upon the compression capacity and wellbore configurations.  

Compression fuel consumption is about 7% to 8% of the injected volumes. All of these costs—equipment, injectant, fuel, maintenance, and resulting production downtimes—during the injection cycles make many of these projects uneconomic or only marginally economic. To date, these shale oil EOR projects have been developed by 16 companies, mostly majors and large independent producers, who have the financial capacity and technical expertise required to design and implement them.  

SHALE EOR METHODS 

Shale Ingenuity has invented and developed two innovative shale oil EOR methods, named SuperEOR and UltraEOR. They involve the injection of a liquid solvent of a specified composition into the shale oil reservoir, at a high rate and for a short injection period (a few days), followed by flowback to a specific minimum wellbore pressure. The solvent is recovered in equipment at the surface and reinjected, thereby reducing costs. Gas produced with the crude oil continues to flow to the midstream facility for NGL recovery. Solvent recovery is highly efficient and low-cost. UltraEOR adds a step at the start of the EOR process that generates a complex fracture network around the wellbore lateral, thereby increasing the contact of the solvent with the shale rock matrix. 

Specific composition, or “tuned” liquid solvents recover oil in a manner significantly different from natural gas or CO2. The solvent has a very low solubility or miscibility pressure; it immediately reduces the interfacial tension between the crude oil and rock matrix; it reduces the oil viscosity; it increases the relative permeability to oil; it adds solution gas pressure to the crude oil and becomes a gas when the pressure is reduced, expanding and driving the oil through the shale pores; and also benefits from other forces, such as advective and molecular-diffusion flux. As a result, it is very effective at recovering oil from the shale oil matrix, and high-pressure injection is not required. 

The SuperEOR and UltraEOR shale oil EOR processes, like any other EOR process, require a sound understanding of the shale oil reservoir and the wells completed into it. A compositional reservoir simulation model of the reservoir was developed to obtain a production and pressure history match of the reservoir. As with any reservoir simulation model, the more detailed and accurate data available, the more accurate the model forecast results under SuperEOR and UltraEOR performance. Compositional simulation modeling of shale oil reservoirs shows that oil recovery is optimized when the solvent composition is tuned, and the solvent composition may require periodic adjustment for optimum oil recovery as the process continues.  

Shale Ingenuity owns patents related to the optimization of oil recovery under cyclic injection of natural gas and has additional patents in application relating to the optimization of oil recovery under cyclic injection of solvents.  

SuperEOR compositional reservoir simulation process. To illustrate the shale oil EOR potential of the SuperEOR and UltraEOR processes in the Niobrara formation of the DJ basin, a representative Niobrara horizontal shale oil producing well was selected in the central-northeastern area of Wattenberg field.  

The selected well was completed in the Niobrara A interval, with a 4,000-ft lateral and a 25-stage slickwater fracture stimulation treatment. At the time of the simulation, the well had a 5½-year production history. Well completion, open-hole logs, PVT, production and surface pressure data were used to develop a compositional simulation model. The PVT data were used to develop a tuned equation of state used by the model to track the individual hydrocarbon components in the reservoir and the injection and production of the SuperEOR and UltraEOR liquid solvent. The production history of the well is shown in Fig. 4. 

Fig. 4. Production history of case study well.
Fig. 4. Production history of case study well.

A nine-component EOS model was developed with the PVT data from a well in the immediate vicinity of the modeled well. The nine pseudo components were N2, CO2, CH4, C2H6, C3H8, C4, C5, C6, and C7+. Table 1 shows the composition and selected EOS parameters. Figures 5a and 5b show experimental data versus simulation data match for constant mass expansion experiment. Figures 6a and 6b show experimental data versus simulation data match for differential liberation experiment. 

Table 1. Pseudo components and selected EOS parameters.
Table 1. Pseudo components and selected EOS parameters.
Fig. 5a and 5b. Experimental data versus simulation data match for constant mass experiment.
Fig. 5a and 5b. Experimental data versus simulation data match for constant mass experiment.
Fig. 6a and 6b. Experimental versus simulation data match for differential liberation experiment.
Fig. 6a and 6b. Experimental versus simulation data match for differential liberation experiment.

A compositional, single-porosity model was utilized to match the historical pressure and production of the selected well. An element of symmetry approach was used, with a model comprised of five fracture stages, or 20% of the total number of fracture stimulation treatment stages. Results were then scaled up to 25 fracture stages for the entire well. Reducing the number of modeled frac stages reduces model complexity and simulation computation time.  

The modeled Niobrara reservoir has a top at 6,700-ft depth, with a pay thickness of 270 ft. The model has 10 layers of constant grid thickness. Reservoir temperature is 190°F. Initial reservoir pressure is 4,000 psig. Absolute shale matrix permeability was estimated to be .0001 md. Hydraulic fractures are simple planar fracs, one per frac stage, having a half-length of 225 ft and frac height of 81 ft.  

Logarithmically spaced, locally refined grid blocks were used in the model to accommodate the large transient response from the low-permeability shale matrix to the high-permeability propped fractures. The history match of primary oil, gas and water production, and surface production pressure, was completed, using an automated history matching tool. The tuning parameters included matrix permeability, relative permeability, porosity, hydraulic fracture geometry, hydraulic fracture conductivity, and formation compressibility.  

Bayesian probabilistic history matching required approximately 500 simulation runs to achieve an acceptable history match with less than 1% history match error. Figures 7a through 7d show the history match error plot and matches on oil production rate, gas production rate, water production rate and BHP. The history-matched model was utilized to evaluate and optimize the forecast oil recovery via the SuperEOR solvent EOR process. Several scenarios were evaluated, varying injection rate, injection pressure, soak time, flowback rate, flowback pressure, and solvent injectant composition. The SuperEOR forecast was run for a period of approximately 13 years. Optimization of the NPV for a SuperEOR project was not conducted, as this would require several other assumptions for such a project, such as the number of wells in SuperEOR operation, the cost of solvent and the solvent recovery system.  

Fig. 7a-7d. Historical production and pressure versus history match case.
Fig. 7a-7d. Historical production and pressure versus history match case.

However, an unoptimized SuperEOR development scenario is offered, assuming an eight-well project consisting of wells completed identical to the modeled well.  Maximum injection BHP was assumed to be 3,900 psi. The single-well (five stages) forecast oil production for the selected constant composition solvent solution, with a maximum injection rate of 330 bpd, injection period of 26 days, maximum production rate of 1,500 Mcfd, production period of 30 days and minimum production BHP of 750 psi, Fig. 8. This projection assumes no soak time, as other simulation runs show that soak time has no significant impact on oil recovery. 

Fig. 8. Historical oil production and improved crude output under SuperEOR.
Fig. 8. Historical oil production and improved crude output under SuperEOR.

Cumulative oil production, for the five modeled frac stages, under primary (pressure depletion) production with no assumed economic limit, and after 13 years of SuperEOR operation, is shown as the black line, Fig. 9. After five years of SuperEOR operation, cumulative oil is forecast to be 27,600 bbl or 146% of the cumulative oil recovered after five years of continued primary oil production.  After 13 years of SuperEOR operation, cumulative oil from the well is forecast to be 47,658 bbl or 172% of the cumulative oil recovered after 13 years of continued primary oil production.  

Fig. 9. Cumulative primary oil production and increase output with SuperEOR.
Fig. 9. Cumulative primary oil production and increase output with SuperEOR.

Primary EUR for the entire well was forecast to be 78,600 bbl of oil, assuming an economic limit rate of production of 10 bopd. Therefore, the well production at the start of SuperEOR operation was within one year of reaching the calculated economic limit, Fig. 9. Thus, implementation of SuperEOR could extend the life of the well by more than 10 years and increase the EUR from 78,600 to 238,290 bbl of oil, a 300% increase. 

Fig. 10. Cumulative primary oil production and with SuperEOR at varying maximum injection BHP.
Fig. 10. Cumulative primary oil production and with SuperEOR at varying maximum injection BHP.

A sensitivity analysis to maximum bottomhole injection pressure was run, to assess the impact on oil recovery, if the SuperEOR process were to be conducted at lower maximum injection BHP. This is an especially important consideration, as several natural gas HnP EOR projects in other shale oil basins have shown inter-well communication via natural or hydraulic stimulation treatment fractures once the BHP reaches a certain high level during injection. Figure 10 shows the cumulative oil production under primary and SuperEOR at maximum injection BHP of 3,500, 3,000, 2,500 and 2,000 psi. The oil recovery after 13 years of SuperEOR operation is reduced by 8.3%, 13.3%, 18.9% and 24.2%, respectively. The simulation model also shows the areas of the reservoir where oil is being recovered by the process. Figure 11 shows a top view of the oil saturation of the middle layer of the reservoir after 13 years of SuperEOR process operation, indicating that oil recovery is localized almost entirely to those grid blocks between the hydraulic fractures.  

Fig. 11. Top view of middle block sim grid showing oil saturation after 13 years SuperEOR.
Fig. 11. Top view of middle block sim grid showing oil saturation after 13 years SuperEOR.

Value added. The process has multiple advantages over natural gas or CO2 HnP EOR. Most notably, it recovers far more oil in less time. The cost of recovery is also much lower, as the solvent injectant is lower-cost than natural gas or CO2 and is purchased only once; recovery of the solvent is almost 100%, and the cost of recovery is low. Cycle times are short, and as a result, wells experience little downtime and higher effective daily oil production rates. A multi-well process can be designed to enable staggered injection and production schedules to afford near constant flowback and injection rates. Artificial lift equipment is not needed, as the wells flow at rates sufficient to efficiently lift oil out of the wellbores.  

An unoptimized SuperEOR project economic analysis for an eight-well project was conducted, assuming 9,000-ft completed lateral lengths in each well. The key project assumptions and results and the forecast oil production for the project are shown in Fig. 12. As shown at a net $83/bbl price, and providing no economic benefit for any additional natural gas that may be produced via SuperEOR, the unrisked, unoptimized process should generate an attractive ROI on capital expenditure.  

Fig. 12. SuperEOR project assumptions and economic results.
Fig. 12. SuperEOR project assumptions and economic results.

Modeling of the SuperEOR process has been completed in most of the U.S. shale plays, and SPE 206186 and SPE 208312 describe similar modeling work in the Midland basin Wolfcamp D and Eagle Ford shales. Core tests of the SuperEOR process have been conducted on Eagle Ford and Midland basin Wolfcamp B shale, demonstrating about 90% oil recovery after six injection and production cycles. These core tests and results are presented in SPE 209348.  The SuperEOR process has also been field-tested successfully in other shale oil basins. 

Compositional reservoir simulation of the UltraEOR process. The UltraEOR  process was modeled, using the same procedure, with the addition of a complex fracture network situated in the areas between the primary completion planar stage fractures. The CMG GEM compositional reservoir simulation model provides a feature enabling the delineation of a complex fracture network. In this case, we assumed the generation of a complex fracture network having fracture widths of .001 feet and an effective permeability of 17.5 millidarcies. A comparison of the five-stage model with planar (SuperEOR) and complex (UltraEOR) fractures are shown in Fig. 13. 

Fig. 13. Top view of middle block SuperEOR and UltraEOR simulation grids.
Fig. 13. Top view of middle block SuperEOR and UltraEOR simulation grids.

Complex fracture generation in the areas between the primary completion planar fracture stages may be achieved with a proprietary process that recognizes the altered stress orientations of the shale. This fracture generation process has been proven and demonstrated successfully in many wells worldwide. 

Fig. 14. Forecasted cumulative oil recovery under primary SuperEOR and UltraEOR.
Fig. 14. Forecasted cumulative oil recovery under primary SuperEOR and UltraEOR.

This complex fracture network effectively doubles the fracture surface area in the region between the five primary planar fractures. As a result, the cumulative oil recovery is about double the oil recovery from SuperEOR. Figure 14 shows the cumulative oil versus time for the five fracture stages modeled, under primary recovery, SuperEOR recovery and UltraEOR recovery. As shown, after 13 years of EOR operation, SuperEOR may increase oil recovery by 1.8 times versus primary and UltraEOR may achieve 3.7 times as much oil as primary recovery.   

Fig. 15. UltraEOR  project assumptions and economic results.
Fig. 15. UltraEOR project assumptions and economic results.

An unoptimized UltraEOR project economic analysis for an eight-well project was conducted, assuming 9,000-ft completed lateral lengths in each well. The key project assumptions and results and the forecast oil production for the project are shown in Fig. 15. 

CONCLUSIONS 

The two novel shale oil EOR processes, SuperEOR and UltraEOR, should enable oil recovery that is far superior to natural gas or CO2 HnP EOR, and at much lower cost. SuperEOR and UltraEOR have several important operational advantages of greater simplicity and lower capital and operating cost. These processes require rigorous compositional reservoir simulation modeling to design, and its use during SuperEOR and UltraEOR operation for optimized for maximum oil recovery as the process is placed into field operation.  

ACKNOWLEDGEMENTS 

Shale Ingenuity is grateful for the collaboration with the Computer Modeling Group and the application of its advanced compositional reservoir simulation software in the development of the SuperEOR and UltraEOR shale oil EOR processes. Also, thanks to Novi Labs for access to their well database , enabling the generation of the Niobrara production and well graphs. This article contains excerpts from SPE paper 213082-MS, “Advanced, superior shale oil EOR methods for the DJ basin,” presented at the SPE Oklahoma City Oil and Gas Symposium, held at the Oklahoma City Convention Center, April 17-19, 2023.   

About the Authors
Robert Downey
Shale Ingenuity
Robert Downey has over 30 years of experience in upstream oil and gas and energy technology development. Prior to Shale Ingenuity, he held numerous executive and technical professional positions at Amoco, Encana, Synthetic Genomics, Ciris Energy and Gunnison Energy. He has been awarded several patents in coal bioconversion, reservoir simulation modeling, reservoir engineering and well drilling and completions. Mr. Downey earned a BS degree in petroleum engineering from the Colorado School of Mines.
Dr. Jim Erdle
The Computer Modeling Group
Dr. Jim Erdle has 49 years of industry experience primarily in reservoir and production engineering-related positions in the upstream services and software segments. Early in his career, he was involved with some of the industry’s leading advances in well testing design, monitoring and interpretation technology including closed chamber and surface pressure readout (SPRO), drill stem testing and production enhancement via NODAL analysis. Dr. Erdle also worked on stimulation treatment design, monitoring techniques and production surveillance software. He recently retired from the Computer Modeling Group after 25 years, most recently as the company’s V.P. of software sales and support for the U.S. and Latin America. He holds a BS degree (1971) and a PhD (1974) in Petroleum Engineering from Penn State University
Kiran Venepalli
The Computer Modeling Group
Kiran Venepalli is a product manager at the Computer Modeling Group specializing in reservoir modelling and simulation. In this role, he plays a pivotal role in shaping the direction and development of CMG's solutions in line with the goals of energy transition. He is also responsible for supervising unconventional solutions. This entails exploring and developing unconventional oil and gas resources, such as shale gas and tight oil, with an emphasis on leveraging technological advancements to improve extraction techniques and minimize environmental impact. Mr. Venepalli has 12 years of industry experience and holds a master’s degree in petroleum engineering from the University of Alaska Fairbanks and a bachelor’s degree from JNTU, India.
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